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Polyisobutylene

CAS No.
9003-27-4
Chemical Name:
Polyisobutylene
Synonyms
usb;POLYISOBUTENE;p20;p118;p200;POLY(ISOBUTYLENE) 24'000;kp5;oktol;pb150;pib100
CBNumber:
CB8147859
Molecular Formula:
C4H8
Molecular Weight:
56.10632
MDL Number:
MFCD00084436
MOL File:
9003-27-4.mol
MSDS File:
SDS
Last updated:2024-08-02 15:22:07

Polyisobutylene Properties

Melting point 54-56 °C
Boiling point 300 °C
Density 0.92 g/mL at 25 °C (lit.)
Tg -61
Tg -62
Tg -64
Tg -75
refractive index n20/D 1.51
Flash point >212
Flash point >482
form slab/chunk
Viscosity 1.08 - 1.43(Intrinsic viscosity)
Viscosity 2.42 - 3.00(Intrinsic viscosity)
Viscosity 250cp (20C)
Viscosity 3.90 - 5.05(Intrinsic viscosity)
Stability Stability Combustible. Incompatible with strong oxidizing agents.
InChI InChI=1S/C4H8/c1-4(2)3/h1H2,2-3H3
InChIKey VQTUBCCKSQIDNK-UHFFFAOYSA-N
SMILES C=C(C)C
Substances Added to Food (formerly EAFUS) POLYISOBUTYLENE (MIN M W 37,000)
FDA 21 CFR 172.615; 175.125; 175.300
EWG's Food Scores 1
FDA UNII POLYISOBUTYLENE (1300 MW) (241BN7J12Y)
POLYISOBUTYLENE (2600000 MW) (4GAS6381TX)
POLYISOBUTYLENE (85000 MW) (7X53O5S2ZY)
POLYISOBUTYLENE (1000 MW) (5XB3A63Y52)
POLYISOBUTYLENE (75000 MW) (596C33NS2J)
EPA Substance Registry System Polyisobutylene (9003-27-4)

SAFETY

Risk and Safety Statements

Safety Statements  24/25
WGK Germany  3
RTECS  UD1010000
TSCA  TSCA listed
HS Code  39022000

Polyisobutylene price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 181455 Polyisobutylene average Mw ~500,000, average Mn ~200,000 by GPC/MALLS, average Mv ~420,000 9003-27-4 100g $194 2024-03-01 Buy
Sigma-Aldrich 1546966 Polyisobutylene United States Pharmacopeia (USP) Reference Standard 9003-27-4 1g $312 2024-03-01 Buy
scipoly 684 Polyisobutylene 9003-27-4 100g $25 2024-07-03 Buy
scipoly 684 Polyisobutylene 9003-27-4 250g $50 2024-07-03 Buy
scipoly 682 Polyisobutylene 9003-27-4 100g $25 2024-07-03 Buy
Product number Packaging Price Buy
181455 100g $194 Buy
1546966 1g $312 Buy
684 100g $25 Buy
684 250g $50 Buy
682 100g $25 Buy

Polyisobutylene Chemical Properties,Uses,Production

Chemical Properties

Polyisobutylene is composed of long-chain hydrocarbon formed by polymerization of isobutene, and is extremely stable under normal conditions. It is transparent non-noxious high-consistency semi-solid polymer free of impurities.

Chemical Properties

The physical properties of polyisobutene are very dependent on molecular weight. Polymers with average molecular weight (Mw) of about 15 000 are sticky viscous liquids whilst those with molecular weight of 100000-200000 are rubber-like, resembling unmilled crepe rubber.
Polyisobutene is non-crystalline when unstretched and is therefore soluble at room temperature in hydrocarbons and halogenated hydrocarbons. The material is resistant to most acids, alkalis and aqueous solutions, as would be expected from its saturated hydrocarbon structure and absence of tertiary hydrogen atoms. The lack of tertiary hydrogen atoms renders polyisobutene more resistant to oxidation than polypropylene; also, the less numerous and partially shielded methylene groups in polyisobutene are less reactive than those in polyethylene. However, polyisobutene is rather susceptible to thermal degradation since chain scission is favoured by the greater stability of the resultant tertiary free radical:
free radical of PolyisobutylenePolyisobutene may be chlorinated but the reaction is accompanied by severe degradation.
A limitation of polyisobutene is its tendency to cold flow and, as a result, the polymer finds little use in self-supporting form. Applications are restricted mainly to adhesives, fabric and paper coatings, and blends with other polymers. Low molecular weight polyisobutene is also used in caulking compounds.

Uses

polyisobutene (hydrogenated) is an emollient.
Polyisobutylene, sometimes called butyl rubber, and other times PIB, is a vinyl polymer. It's very similar to polyethylene and polypropylene in structure, except that every other carbon is substituted with two methyl groups. It is made from the monomer isobutylene, by cationic vinyl polymerization.
Polyisobutylene is a synthetic rubber, or elastomer. It's special because it's the only rubber that's gas impermeable. That is, it's the only rubber that can hold air for long periods of time. You may have noticed that balloons will go flat after a few days. This is because they are made of polyisoprene, which is not gas impermeable. Because polyisobutylene will hold air, it is used to make things like the inner tubes, liner layers of tires, and the inner liners of basketballs.

Definition

ChEBI: A polymer composed of repeating 1,1-dimethylethylene units.

Preparation

Silicone rubbers are prepared as follows:
Preparation of Silicone rubbers
Other groups may replace the methyl groups. Silicone rubbers have excellent ozone and weathering resistance, good electrical properties, and good adhesion to metal.

Solubility in organics

non-polar organic solvents (i.e. aliphatic, aromatic, cyclic and halogenated hydrocarbons), THF

Solubility in organics

non-polar organic solvents (i.e. aliphatic, aromatic, cyclic, and halogenated hydrocarbons), THF

Solubility in organics

Non-polar organic solvents (i.e., aliphatic, aromatic, cyclic, and halogenated hydrocarbons), THF

Polyisobutylene Preparation Products And Raw materials

Global( 251)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8822 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651 admin@zlchemi.com China 3002 58
Hebei Guanlang Biotechnology Co,.LTD
+86-19930503253; +8619930503252 daisy@crovellbio.com China 5832 58
Anhui Ruihan Technology Co., Ltd
+8617756083858 daisy@anhuiruihan.com China 994 58
Hebei Jingbo New Material Technology Co., Ltd
+8619931165850 hbjbtech@163.com China 1000 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20296 58
Hebei Saisier Technology Co., LTD
+86-18400010335 +86-18034520335 admin@hbsaisier.cn China 996 58
Yujiang Chemical (Shandong) Co.,Ltd.
+86-17736087130 +86-18633844644 catherine@yjchem.com.cn China 975 58
Hebei Longbang Technology Co., LTD
+86-18032476855 +86-18032476855 admin@hblongbang.com China 943 58
HebeiShuoshengImportandExportco.,Ltd
+86-18732180219 +86-18732180219 862878185@qq.com China 925 58

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View Lastest Price from Polyisobutylene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
POLYISOBUTYLENE pictures 2024-08-08 POLYISOBUTYLENE
9003-27-4
US $6.00 / KG 1KG More than 99% 2000KG/Month Hebei Saisier Technology Co., LTD
POLYISOBUTYLENE pictures 2024-08-05 POLYISOBUTYLENE
9003-27-4
US $6.00 / kg 1kg 99% 2000KG/Month HebeiShuoshengImportandExportco.,Ltd
Polyisobutene pictures 2024-07-24 Polyisobutene
9003-27-4
US $1.00 / KG 1KG 99% 10 ton Hebei Guanlang Biotechnology Co,.LTD
  • POLYISOBUTYLENE pictures
  • POLYISOBUTYLENE
    9003-27-4
  • US $6.00 / KG
  • More than 99%
  • Hebei Saisier Technology Co., LTD
  • POLYISOBUTYLENE pictures
  • POLYISOBUTYLENE
    9003-27-4
  • US $6.00 / kg
  • 99%
  • HebeiShuoshengImportandExportco.,Ltd
  • Polyisobutene pictures
  • Polyisobutene
    9003-27-4
  • US $1.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co,.LTD
isobutenehomopolymer isobutenepolymer isobutylenehomopolymer POLYISOBUTYLENE(C12-C20) maxvis2000 napvis30 oktol oppanolb oppanolb100 oppanolb15 oppanolb150 oppanolb200 oppanolb3 paratac paxon3204 pb150 pib100 poly(2-methylpropene) polyisobutylenepsg polyvis06sh polyvis150sh polyvis200sh POLY(ISOBUTYLENE) 390 POLY(ISOBUTYLENE) 4'400 POLY(ISOBUTYLENE) 583'000 POLY(ISOBUTYLENE) 680 POLY(ISOBUTYLENE) 73'000 POLY(ISOBUTYLENE) 856'000 POLY(ISOBUTYLENE) 86'000 1-Propene,2-methyl-,homopolymer 2-methyl-1-propenhomopolymer 2-methylpropenepolymer 2-methyl-propenpolymers amoco600 hyvis200 kp5 polyvis30sh psb(aliphaticpolymer) Vistanex (b-100) POLY(ISOBUTYLENE), CA. M.W.400.000 POLY(ISOBUTYLENE), CA. M.W. 840.000 100G Poly(isobutylene), ca. MW. 4.700.000 Poly(isobutylene), ca. MW. 2.800 Poly(isobutylene), ca. MW. 1.700.000 Poly(isobutylene)ca. M.W. 840.000 Poly(isobutylene),ca. M.W. 700.000 Poly(isobutylene),ca. M.W. 85.000 Polyisobutylene (1 g) Polyisobutylene (PIB) Polyisobutylene high viscosity Polyisobutylene medium viscosity Polyisobutylene low viscosity ISO-BUTYLENE RESIN POLYISOBUTYLENE POLY(ISOBUTYLENE) 10'000 POLY(ISOBUTYLENE) 134'000 POLY(ISOBUTYLENE) 2'500 POLY(ISOBUTYLENE) 302'000