1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE
- CAS No.
- 10000-20-1
- Chemical Name:
- 1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE
- Synonyms
- 1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE;Hydrazine, 1,2-bis[(1,1-dimethylethyl)dimethylsilyl]-
- CBNumber:
- CB8206617
- Molecular Formula:
- C12H32N2Si2
- Molecular Weight:
- 260.57
- MDL Number:
- MFCD07369154
- MOL File:
- Mol file
1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE price More Price(9)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
TRC | B415375 | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 10000-20-1 | 1g | $215 | 2021-12-16 | Buy |
Biosynth Carbosynth | FB18753 | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 10000-20-1 | 500mg | $250 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | ORS0003707 | 1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE 95.00% | 10000-20-1 | 250MG | $284.55 | 2021-12-16 | Buy |
Biosynth Carbosynth | FB18753 | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 10000-20-1 | 1g | $380 | 2021-12-16 | Buy |
AK Scientific | 0239CT | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 10000-20-1 | 500mg | $455 | 2021-12-16 | Buy |
1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE Chemical Properties,Uses,Production
Chemical Properties
Colourless Oil
Physical properties
bp 118–119°C/9 Torr;55–65°C/0.05 Torr; n25 D 1.4456.
Uses
1,2-Bis(t-butyldimethylsilyl)hydrazine is a source of latent hydrazine used in the preparation of stable alkyl
and aryl N-silyl hydrazones, gem-dihalides, vinyl halides, and
room temperature Wolff–Kishner reductions.
Wolff–Kishner Reduction.
A particularly useful reaction of
the N-silyl hydrazones is their use as substrates in the Wolff–
Kishner reaction, where reduction of the corresponding carbonyl
compound can be accomplished at relatively modest temperatures.
This is in marked contrast to the more traditional Wolff–
Kishner reaction, and its Huang–Minlon modification, which
require high temperatures and the use of potassium hydroxide.Room temperature conditions for the Wolff–Kishner reaction,
previously reported by Cram and co-workers, were adapted by
Myers and Furrow to the current N-silyl hydrazone methodology
(eq 4).
Preparation
prepared by reacting t-butyldimethylchlorosilane with anhydrous hydrazine at 70??C (eq 1), with or without solvent.
1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE Preparation Products And Raw materials
Raw materials
Preparation Products
1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Alfa Chemistry | Info@alfa-chemistry.com | United States | 24072 | 58 | |
J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
3B Pharmachem (Wuhan) International Co.,Ltd. | 821-50328103-801 18930552037 | 3bsc@sina.com | China | 15848 | 69 |
Chemsky(shanghai)International Co.,Ltd. | 021-50135380 | shchemsky@sina.com | China | 32344 | 50 |
S.Z. PhyStandard Bio-Tech. Co., Ltd. | 0755-83725681-603 | China | 4505 | 50 | |
Shenzhen Polymeri Biochemical Technology Co., Ltd. | +86-400-002-6226 13028896684 | sales@rrkchem.com | China | 56070 | 58 |
Energy Chemical | 021-58432009 400-005-6266 | marketing1@energy-chemical.com | China | 44843 | 58 |
Carbosynth | -- | sales@carbosynth.com | United Kingdom | 6018 | 58 |