ChemicalBook >> CAS DataBase List >>(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
- CAS No.
- 38465-86-0
- Chemical Name:
- (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
- Synonyms
- methyl(diphenyl)phosphane;(bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i);1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%;1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate;1,5-CYCLOOCTADIENE BIS(METHYLDIPHENYLPHOSPHANE) HEXAFLUOROPHOSPHATE IRIDIUM;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(Ⅰ) hexafluorophosphate;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97%
- CBNumber:
- CB8242424
- Molecular Formula:
- C34H38F6IrP3
- Molecular Weight:
- 845.79
- MDL Number:
- MFCD00064800
- MOL File:
- 38465-86-0.mol
Last updated:2023-04-23 13:52:06
| Melting point | 224 °C (dec.) (lit.) |
|---|---|
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | Crystalline Powder |
| color | Red |
| Water Solubility | Soluble in acetone. Insoluble in water. |
| Sensitive | Air & Moisture Sensitive |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22-36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 28439000 | |||||||||
| NFPA 704 |
|
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE price More Price(26)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 337455 | (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate 97% | 38465-86-0 | 50mg | $30.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | 337455 | (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate 97% | 38465-86-0 | 500mg | $176 | 2024-03-01 | Buy |
| Alfa Aesar | 018809 | 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate | 38465-86-0 | 0.5g | $150 | 2023-06-20 | Buy |
| Alfa Aesar | 018809 | 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate | 38465-86-0 | 2g | $457 | 2023-06-20 | Buy |
| TRC | C984583 | 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate | 38465-86-0 | 25mg | $45 | 2021-12-16 | Buy |
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Chemical Properties,Uses,Production
Chemical Properties
red crystalline powder
Uses
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh2Me)2]PF6, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH2(solv)2(PPh2Me)2]PF6 which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials
Raw materials
Preparation Products
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Suppliers
Global( 62)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30239 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 7724 | 58 |
| Shaoxin Catsyn Co., Ltd. | +undefined-0575-82040869 +86-0575-82040869; | sales@catsyn.com | China | 6114 | 58 |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43340 | 58 |
| Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57505 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 021-61259108 18621169109 | market03@meryer.com | China | 40228 | 62 |
38465-86-0((1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE)Related Search:
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
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1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...
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38465-86-0
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