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ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic iridium >(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

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(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Suppliers list
Company Name: Hubei Jusheng Technology Co.,Ltd.
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Products Intro: Product Name:(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
CAS:38465-86-0
Purity:0.99 Package:5KG;1KG
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Products Intro: Product Name:(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
CAS:38465-86-0
Purity:98% Package:1g;1.3USD
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Products Intro: Product Name:1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...
CAS:38465-86-0
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Products Intro: Product Name:(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
CAS:38465-86-0
Purity:99.00% Package:25kgs/Drum;200kgs/Drum Remarks:ISO 9001：2015 REACH Approved Manufacturer
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Products Intro: Product Name:(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
CAS:38465-86-0
Purity:98% Min. Package:1G;1KG;100KG Remarks:SC10643
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Basic information
Product Name:(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
Synonyms:(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%;Iridium(1+), (1,2,5,6-.eta.)-1,5-cyclooctadienebis(methyldiphenylphosphine)-, hexafluorophosphate(1-);(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i);(bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97%;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(Ⅰ) hexafluorophosphate
CAS:38465-86-0
MF:C34H38F6IrP3
MW:845.79
EINECS:
Product Categories:Ir;Catalysis and Inorganic Chemistry;Chemical Synthesis;Iridium
Mol File:38465-86-0.mol
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Structure
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Chemical Properties
Melting point 224 °C (dec.) (lit.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Crystalline Powder
color Red
Water Solubility Soluble in acetone. Insoluble in water.
Sensitive Air & Moisture Sensitive
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Usage And Synthesis
Chemical Propertiesred crystalline powder
Uses(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh2Me)2]PF6, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH2(solv)2(PPh2Me)2]PF6 which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials
Tag:(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE(38465-86-0) Related Product Information
METHYLDIPHENYLPHOSPHINE 1,3-CYCLOOCTADIENE (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE 1,5-Cyclooctadiene