ChemicalBook >> CAS DataBase List >>Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos]

Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos]

Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] structure

CAS No.: 1025477-38-6

Chemical Name:: Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos]

Synonyms: e}ruthenium(II);Ru(OAc)2[(R)-dtbm-segphos];Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyL;Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II);Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II);Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos];Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos(R)]

CBNumber:: CB82528669

Molecular Formula:: C78H108O12P2Ru

Molecular Weight:: 1400.73

MDL Number:: MFCD17018804

MOL File:: 1025477-38-6.mol

Last updated:2023-04-23 13:52:06

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Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] Properties

form	solid
color	yellow to brownish-red to dark green
Sensitive	air sensitive

Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] price More Price(3)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Strem Chemicals	44-0180	Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos(R)]	1025477-38-6	250mg	$53	2024-03-01	Buy
Strem Chemicals	44-0180	Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos(R)]	1025477-38-6	1g	$158	2024-03-01	Buy
Strem Chemicals	44-0180	Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos(R)]	1025477-38-6	5g	$379	2024-03-01	Buy

Product number	Packaging	Price	Buy
44-0180	250mg	$53	Buy
44-0180	1g	$158	Buy
44-0180	5g	$379	Buy

Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] Chemical Properties,Uses,Production

Reactions

Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone.

Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] Preparation Products And Raw materials

Raw materials

Preparation Products

Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] Suppliers

Global( 14)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.	0371-0371-65511006 18625597674	sales@kingorgchem.com	China	953	55
LaaJoo	021-60702684 18516024827	huang.jiayi@sinocompound.com	China	2654	58
Shenzhen Polymeri Biochemical Technology Co., Ltd.	+86-400-002-6226 13028896684	sales@rrkchem.com	China	56057	58
Shaoxing Zejun Pharmaceuticals Co.,Ltd	0575-82126188 15395856318	service@zejunpharma.com	China	438	58
Energy Chemical	021-58432009 400-005-6266	marketing1@energy-chemical.com	China	44843	58
Shanghai Haohong Pharmaceutical Co., Ltd.	400-8210725 4008210725	malulu@leyan.com	China	39997	58
Bide Pharmatech Ltd.	400-1647117 15221909166	product02@bidepharm.com	China	63720	58
Bide Pharmatech Ltd.	400-6005915	sales@picasso-e.com	China	39661	58
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd	15229059051	1027@dideu.com	China	9974	58

Supplier	Advantage
J & K SCIENTIFIC LTD.	76
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.	55
LaaJoo	58
Shenzhen Polymeri Biochemical Technology Co., Ltd.	58
Shaoxing Zejun Pharmaceuticals Co.,Ltd	58
Energy Chemical	58
Shanghai Haohong Pharmaceutical Co., Ltd.	58
Bide Pharmatech Ltd.	58
Bide Pharmatech Ltd.	58
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd	58

Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos(R)] Ru(OAc)2[(R)-dtbm-segphos] Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyL e}ruthenium(II) Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) 1025477-38-6 C78H106O12P2Ru