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1-Pentene

CAS No.
109-67-1
Chemical Name:
1-Pentene
Synonyms
1-C5H10;AMYLENE;PENTENE;1-Penten;petene-1;1-PENTENE;1-AMYLENE;Pentene-1;N-AMYLENE;l-pentene
CBNumber:
CB8852784
Molecular Formula:
C5H10
Molecular Weight:
70.13
MDL Number:
MFCD00003567
MOL File:
109-67-1.mol
Last updated:2023-12-25 17:47:29

1-Pentene Properties

Melting point -165 °C
Boiling point 29.9-30.1 °C (lit.)
Density 0.641 g/mL at 25 °C (lit.)
vapor density 2.4 (vs air)
vapor pressure 10.27 psi ( 20 °C)
refractive index n20/D 1.371(lit.)
Flash point −20 °F
storage temp. 2-8°C
solubility alcohol: miscible(lit.)
form Liquid
pka >14 (Schwarzenbach et al., 1993)
Specific Gravity 0.64
color Clear colorless
Odor Like gasoline.
explosive limit 8.7%
Viscosity 0.202mm2/s
Odor Threshold 0.1ppm
Water Solubility 0.15 g/L (20 ºC)
Merck 14,7122
BRN 1731629
Henry's Law Constant 0.406 at 25 °C (Hine and Mookerjee, 1975)
Dielectric constant 2.1(20℃)
Stability Stable. Incompatible with strong oxidizing agents. Highly flammable - readily forms explosive mixtures with air.
LogP 2.4-2.66 at 25℃
Indirect Additives used in Food Contact Substances 1-PENTENE
CAS DataBase Reference 109-67-1(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII ALP8M0LU81
NIST Chemistry Reference 1-Pentene(109-67-1)
EPA Substance Registry System 1-Pentene (109-67-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07,GHS08
Signal word  Danger
Hazard statements  H224-H304-H315-H319
Precautionary statements  P210-P301+P310+P331-P302+P352-P305+P351+P338-P403+P233
Hazard Codes  F+,Xn,F,Xi
Risk Statements  12-52/53-65
Safety Statements  61-62-16
RIDADR  UN 1108 3/PG 1
WGK Germany  3
RTECS  SB2179000
Autoignition Temperature 522 °F
Hazard Note  Irritant/Extremely Flammable/Keep Cold
TSCA  Yes
HazardClass  3
PackingGroup  I
HS Code  29321900
NFPA 704
4
1 1

1-Pentene price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 76969 1-Pentene analytical standard 109-67-1 5ml $139 2024-03-01 Buy
Sigma-Aldrich 241997 1-Pentene 98% 109-67-1 25g $84.5 2024-03-01 Buy
TCI Chemical P0316 1-Pentene >98.0%(GC) 109-67-1 25mL $38 2024-03-01 Buy
TCI Chemical P0316 1-Pentene >98.0%(GC) 109-67-1 500mL $374 2024-03-01 Buy
Alfa Aesar A16723 1-Pentene, 97% 109-67-1 25g $56.65 2024-03-01 Buy
Product number Packaging Price Buy
76969 5ml $139 Buy
241997 25g $84.5 Buy
P0316 25mL $38 Buy
P0316 500mL $374 Buy
A16723 25g $56.65 Buy

1-Pentene Chemical Properties,Uses,Production

Chemical Properties

1-Pentene, C5H10, is a flammable liquid with specific gravity 0.641. It occurs in coal tar and in petroleum cracking mixtures, and polymerizes on extended periods of storage (15, 320).

Physical properties

Clear, colorless, volatile, very flammable liquid with a disagreeable odor. An odor threshold concentration of 10 ppbv was determined by a triangular odor bag method (Nagata and Takeuchi, 1990).

Uses

Blending agent for high octane motor fuel; organic synthesis.

Uses

1-Pentene is used in the preparation of d-xylitol, l-arabinitol and hydrazones of substituted salicylaldehydes. It is also used as a blending agent for of high-octane gasoline. It reacts with p-toluenesulfinate to yield 1-(2-iodo-pentane-1-sulfonyl)-4-methyl-benzene. It is also involved in Gas Chromatography and Liquid Chromatography analysis.

Production Methods

1-Pentene is prepared from allyl bromide and ethyl magnesium bromide in ether or in dipropyl ether.

General Description

Colorless liquid with an odor of gasoline. Flash point -20°F(Aldrich). Insoluble in water and less dense than water. Hence floats on water. Flammable vapor is produced. Boiling point 86°F.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

1-Pentene may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. May undergo exothermic polymerization reactions in the presence of various catalysts (such as acids) or initiators.

Health Hazard

Acts as a simple asphyxiant or weak anesthetic in high vapor concentrations. Similar to effects caused by gasoline vapors.

Fire Hazard

Behavior in Fire: Containers may explode in fire.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Potential Exposure

Workers in petroleum refineries and petrochemical plants.

Source

Schauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The gas-phase emission rate of 1-pentene was 8.6 mg/kg of pine burned. Emission rates of 1-pentene were not measured during the combustion of oak and eucalyptus.
California Phase II reformulated gasoline contained 1-pentene at a concentration of 1.48 g/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were 0.40 and 51.8 mg/km, respectively (Schauer et al., 2002).

Environmental Fate

Biological. Biooxidation of 1-pentene may occur yielding 4-penten-1-ol, which may oxidize to give 4-pentenoic acid (Dugan, 1972). Washed cell suspensions of bacteria belonging to the genera Mycobacterium, Nocardia, Xanthobacter, and Pseudomonas and growing on selected alkenes metabolized 1-pentene to 1,2-epoxypentane. Mycobacterium sp., growing on ethene, hydrolyzed 1,2-epoxypropane to 1,2-propanediol (Van Ginkel et al., 1987).
Photolytic. The following rate constants were reported for the reaction of 1-pentene and OH radicals in the atmosphere: 1.8 x 10-13 cm3/molecule?sec at 300 K (Hendry and Kenley, 1979); 3.14 x 10-11 cm3/molecule?sec (Atkinson, 1990). Atkinson (1990) also reported a photooxidation rate constant of 1.10 x 10-17 cm3/molecule?sec for the reaction of 1-pentene and ozone.
Chemical/Physical. Complete combustion in air yields carbon dioxide and water.

Shipping

UN1108 1-Pentene, Hazard Class: 3; Labels: 3-Flammable liquid

Incompatibilities

Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Excessive heat may cause polymerization. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, heat. Incompatible with strong reducing agents such as hydrides; oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

627-19-0
109-67-1
Synthesis of 1-Pentene from 1-PENTYNE
Global( 195)Suppliers
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BEYOND INDUSTRIES (CHINA) LIMITED
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Shandong Zhishang New Material Co., Ltd.
+8617653113209 sales002@sdzschem.com China 3049 58

View Lastest Price from 1-Pentene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-Pentene pictures 2023-12-26 1-Pentene
109-67-1
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
1-Pentene pictures 2023-07-27 1-Pentene
109-67-1
US $1.10 / g 1g 99.0% Min 100 Tons Shaanxi Didu New Materials Co. Ltd
1-Pentene 98% pictures 2021-07-02 1-Pentene 98%
109-67-1
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
  • 1-Pentene pictures
  • 1-Pentene
    109-67-1
  • US $100.00-1.00 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd
  • 1-Pentene pictures
  • 1-Pentene
    109-67-1
  • US $1.10 / g
  • 99.0% Min
  • Shaanxi Didu New Materials Co. Ltd
  • 1-Pentene 98% pictures
  • 1-Pentene 98%
    109-67-1
  • US $15.00-10.00 / KG
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd
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