tert-Butyl (Mesitylsulfonyl)oxycarbaMate
- CAS No.
- 36016-39-4
- Chemical Name:
- tert-Butyl (Mesitylsulfonyl)oxycarbaMate
- Synonyms
- tert-Butyl (Mesitylsulfonyl)oxycarbaMate;N-Boc-O-(mesitylsulfonyl)hydroxyamine;N-BOC-O-(MESITYLSULFONYL)HYDROXYLAMINE;N-Mesitylsulfonyloxy-tert-butylcarbaMat;BOC-Azanyl 2,4,6-trimethylbenzenesulfonate;_x000D_N-Boc-O-(mesitylsulfonyl)hydroxylamine;t-Butoxycarbonyl-O-mesitylenesulfonylhydroxylamine;N-Tert-butoxycarbonyl-O-(mesitylsulfonyl)hydroxylamine;tert-butyl N-[(2,4,6-trimethylbenzenesulfonyl)oxy]carbamate;1,1-dimethylethyl [[(2,4,6-trimethylphenyl)sulphonyl]oxy]car...
- CBNumber:
- CB8909691
- Molecular Formula:
- C14H21NO5S
- Molecular Weight:
- 315.39
- MDL Number:
- MFCD00044463
- MOL File:
- 36016-39-4.mol
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|---|---|
| Signal word | Danger |
| Hazard statements | H301-H311-H331 |
| Precautionary statements | P261-P264-P270-P271-P280-P302+P352-P304+P340-P310-P330-P361-P403+P233-P405-P501 |
| HS Code | 2930909899 |
tert-Butyl (Mesitylsulfonyl)oxycarbaMate price More Price(19)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| AK Scientific | W5748 | tert-Butyl(mesitylsulfonyl)oxycarbamate | 36016-39-4 | 250mg | $19 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB154038 | tert-Butyl (mesitylsulfonyl)oxycarbamate | 36016-39-4 | 250mg | $50 | 2021-12-16 | Buy |
| AK Scientific | J92785 | tert-Butyl(mesitylsulfonyl)oxycarbamate | 36016-39-4 | 5g | $75 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB154038 | tert-Butyl (mesitylsulfonyl)oxycarbamate | 36016-39-4 | 500g | $80 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB154038 | tert-Butyl (mesitylsulfonyl)oxycarbamate | 36016-39-4 | 1g | $125 | 2021-12-16 | Buy |
tert-Butyl (Mesitylsulfonyl)oxycarbaMate Chemical Properties,Uses,Production
Uses
Tert-Butyl (Mesitylsulfonyl)oxycarbaMate is a useful reagent for the enantioselective aziridination of α,β-unsaturated aldehydes.
Synthesis
2-Mesitylenesufonylchloride (2.00 g, 9.17 mmol) was added to a flame dried and argon purged round-bottom flask and dissolved in ether (18 mL), followed by the addition of N-Boc-hydroxylamine (1.47 g, 1100 mmol) The flask was cooled to 0° C and then TEA was added dropwise (1.3 mL). The reaction stirred for 2 hours at 0° C, at which all starting material had been converted as seen by TLC. The TEA-Cl, white solid, was filtered, and washed with ether. The filtrate was concentrated in vacuo, and purified via flash chromatography in 25/75 EtOAc/hexane gradient. Yield was quantitative, 2.16 g, white solid.
Purification Methods
Separation of 1,1-Dimethylethyl (((2,4,6-trimethylphenyl)sulphonyl)oxy)carbamate on Newcrom R1 HPLC column:1,1-Dimethylethyl (((2,4,6-trimethylphenyl)sulphonyl)oxy)carbamate can be analyzed by this reverse phase (RP) HPLC method with simple conditions. The mobile phase contains an acetonitrile (MeCN), water, and phosphoric acid. For Mass-Spec (MS) compatible applications the phosphoric acid needs to be replaced with formic acid. Smaller 3 μm particles columns available for fast UPLC applications. This liquid chromatography method is scalable and can be used for isolation impurities in preparative separation. It also suitable for pharmacokinetics.
tert-Butyl (Mesitylsulfonyl)oxycarbaMate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Gubang New Materail Technology Co. LTD | 21-51317962 +8618721305404 | 16728589@qq.com | CHINA | 272 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12840 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18153 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20287 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 17322 | 58 |
| BOC Sciences | +1-631-485-4226 | inquiry@bocsci.com | United States | 19553 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29811 | 58 |
| Jinan Liheng Biotechnology Co., Ltd. | 15865262812 | info@lihengpharm.com | CHINA | 938 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34553 | 58 |
View Lastest Price from tert-Butyl (Mesitylsulfonyl)oxycarbaMate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
![tert-Butyl [(mesitylsulfonyl)oxy]carbamate pictures](/ProductImageEN/2023-03/Small/5d1f719d-3b9d-4733-8b36-74f12b843d51.jpg) |
2024-11-04 | tert-Butyl [(mesitylsulfonyl)oxy]carbamate
36016-39-4
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Weibang Biotechnology Co., Ltd | |
 |
2024-04-09 | tert-Butyl (Mesitylsulfonyl)oxycarbaMate
36016-39-4
|
US $5.00-0.10 / KG | 1KG | 98% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
![tert-Butyl [(mesitylsulfonyl)oxy]carbamate pictures](/ProductImageEN/2023-10/Small/a1430f4b-853b-46d8-b262-6e402b29765f.jpg) |
2023-10-16 | tert-Butyl [(mesitylsulfonyl)oxy]carbamate
36016-39-4
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd |
-
- tert-Butyl [(mesitylsulfonyl)oxy]carbamate
36016-39-4
- US $0.00-0.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
-
- tert-Butyl (Mesitylsulfonyl)oxycarbaMate
36016-39-4
- US $5.00-0.10 / KG
- 98%
- Henan Fengda Chemical Co., Ltd
-
- tert-Butyl [(mesitylsulfonyl)oxy]carbamate
36016-39-4
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd