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TRIPHENYLPHOSPHINE RESIN

TRIPHENYLPHOSPHINE RESIN structure

CAS No.: 39319-11-4

Chemical Name:: TRIPHENYLPHOSPHINE RESIN

Synonyms: POLYMER-BOUND TRIPHENYLPHOSPHINE;POLYMER SUPPORTED TRIPHENYLPHOSPHINE;TRIPHENYLPHOSPHINE POLYMER BOUND;PL-TPP RESIN;-C6H4P(C6H5)2;PL-TPP MP-RESIN;POLYSTYRENE-PPH2;diphenylphosphinated;TRIPHENYLPHOSPHINE PS;TRIPHENYLPHOSPHINE RESIN

CBNumber:: CB9181407

Molecular Formula:: C18H15P

Molecular Weight:: 262.285461

MDL Number:: MFCD20489348

MOL File:: 39319-11-4.mol

MSDS File:: SDS

Last updated:2025-01-27 09:38:02

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TRIPHENYLPHOSPHINE RESIN Properties

storage temp.	2-8°C
form	Beads
color	White to yellow
Sensitive	Air Sensitive
UNSPSC Code	12352200
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H312-H315-H319-H332-H335-H302+H312+H332
Precautionary statements	P261-P280-P305+P351+P338
Hazard Codes	Xn,Xi
Risk Statements	22-43-20/21/22-36/37/38
Safety Statements	36/37-36-26
WGK Germany	3
F	10-23
HS Code	29310099

TRIPHENYLPHOSPHINE RESIN price More Price(25)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	14664	Triphenylphosphine, polymer-bound 100-200?mesh, extent of labeling: ~3.2?mmol/g loading	39319-11-4	25g	$304	2024-03-01	Buy
Alfa Aesar	L19478	Triphenylphosphine, polymer-supported 1.4-2.0 mmol/g on polystyrene	39319-11-4	1g	$31.1	2023-06-20	Buy
Alfa Aesar	L19478	Triphenylphosphine, polymer-supported 1.4-2.0 mmol/g on polystyrene	39319-11-4	5g	$96.3	2021-12-16	Buy
Strem Chemicals	15-6730	Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked)	39319-11-4	1g	$48	2021-12-16	Buy
Strem Chemicals	15-6730	Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked)	39319-11-4	5g	$143	2021-12-16	Buy

Product number	Packaging	Price	Buy
14664	25g	$304	Buy
L19478	1g	$31.1	Buy
L19478	5g	$96.3	Buy
15-6730	1g	$48	Buy
15-6730	5g	$143	Buy

TRIPHENYLPHOSPHINE RESIN Chemical Properties,Uses,Production

Chemical Properties

white to yellow beads

Uses

Polymer-bound triphenylphosphine is a solid-supported reagent that can be used as a better alternative to triphenylphosphine in the Mitsunobu reaction.
It can also be used:

For the esterification of alkylphosphonic acids using primary alcohols in the presence of iodine and imidazole.
To catalyze the conversion of 3-[3-(1,3-dioxolan-2-yl)-1-hydroxypropyl]pyridine to 3-[1-bromo-3-(1,3-dioxolan-2-yl)propyl]pyridine using carbon tetrabromide.
To isomerize (Z)-nitro olefins to the (E)-isomers.
To prepare polymer-bound ylides which are useful in Wittig reactions.
To convert alcohols or carboxylic acids to the corresponding chlorides.
In combination with carbon tetrachloride for the coupling N-alkoxycarbonyl α-amino acids and primary amines to form the corresponding amides.

Uses

Triphenylphosphine resin is used for the preparation of polymer bound ylids which are useful for Wittig reactions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reaction type: solution phase peptide synthesis
reagent type: ligand

TRIPHENYLPHOSPHINE RESIN Preparation Products And Raw materials

Raw materials

Preparation Products

TRIPHENYLPHOSPHINE RESIN Suppliers

Global( 78)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
BOC Sciences	+1-631-485-4226	inquiry@bocsci.com	United States	19552	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49732	58
Antai Fine Chemical Technology Co.,Limited	18503026267	info@antaichem.com	CHINA	9636	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	12186	58
Hebei Chuanghai Biotechnology Co., Ltd	+8615531151365	mina@chuanghaibio.com	China	18137	58
SUZHOU SENFEIDA CHEMICAL CO.,LTD	+86-0512-83500002 +8618501500038	3899766280@qq.com	China	26362	58
LEAPCHEM CO., LTD.	+86-852-30606658	market18@leapchem.com	China	43340	58
Shanghai Acmec Biochemical Technology Co., Ltd.	+86-18621343501; +undefined18621343501	product@acmec-e.com	China	33338	58
SHANGHAI KEAN TECHNOLOGY CO., LTD.	+8613817748580	cooperation@kean-chem.com	China	40066	58
DAYANG CHEM (HANGZHOU) CO.,LTD	+8617705817739	info@dycnchem.com	China	53881	58

Supplier	Advantage
BOC Sciences	58
CONIER CHEM AND PHARMA LIMITED	58
Antai Fine Chemical Technology Co.,Limited	58
Zhengzhou Alfa Chemical Co.,Ltd	58
Hebei Chuanghai Biotechnology Co., Ltd	58
SUZHOU SENFEIDA CHEMICAL CO.,LTD	58
LEAPCHEM CO., LTD.	58
Shanghai Acmec Biochemical Technology Co., Ltd.	58
SHANGHAI KEAN TECHNOLOGY CO., LTD.	58
DAYANG CHEM (HANGZHOU) CO.,LTD	58

TRIPHENYLPHOSPHINE RESIN Spectrum

TRIPHENYLPHOSPHINE RESIN(39319-11-4)IR

39319-11-4(TRIPHENYLPHOSPHINE RESIN)Related Search:

METHYL ISOCYANOACETATE Tris(2,4-pentanedionato)chroMiuM(III) Tosylmethyl isocyanide TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III) N-BUTYLISOCYANIDE

DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) TERT-BUTYL ISOCYANIDE TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)DYSPROSIUM(III) PHENYLSELENOL 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE

2,4-PENTANEDIONE, SILVER DERIVATIVE COBALT(II) ACETYLACETONATE Benzyl isocyanide SALCOMINE Ferric acetylacetonate

Ethyl isocyanoacetate Cupric acetylacetonate TRIPHENYLPHOSPHINE RESIN, 1% DVB; 100-200 MESH; 1-1.5 MMOL/G

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TRIPHENYLPHOSPHINE POL. BOUND, 100-200 M ESH, ~1.6 MMOL/G TRIPHENYLPHOSPHINE POL. BOUND, 200-400 M ESH, ~3 MMOL/G TriphenylphosphineResin1%DvbMesh,1-1.5Mmol/G Triphenylphosphine resin, Crosslinked with 1% DVB, 1.2-1.5 mmol/g, 100-200 mesh Triphenylphosphine resin, 1% crosslinked with DVB 4-DIPHENYLPHOSPHINO POLYSTYRENE RESIN COPOLYMER OF STYRENE AND DIVINYLBENZENE, DIPHENYLPHOSPHINATED DIPHENYLPHOSPHINOBENZOYL NOVAGEL(TM) AM RESIN DIPHENYLPHOSPHINO-POLYSTYRENE MACROPOROUS POLYMER SUPPORTED TRIPHENYLPHOSPHINE PL-TPP RESIN PL-TPP MP-RESIN POLYSTYRENE CROSSLINKED WITH DIVINYL-BENZENE, DIPHENYLPHOSPHINATED POLYSTYRENE-PPH2 TRIPHENYLPHOSPHINE, POLYMER-SUPPORTED TRIPHENYLPHOSPHINE POLYSTYRENE TRIPHENYLPHOSPHINE PS TRIPHENYLPHOSPHINE PS RESIN TRIPHENYLPHOSPHINE RESIN TRIPHENYLPHOSPHINE NOVAGEL TRIPHENYLPHOSPHINE NOVAGEL(TM) 4-DIPHENYLPHOSPHINO POLYSTYRENE RESIN, CROSS-LINKED WITH 2% DVB: (1.0-2.0MMOLP/G), 200-400MESH Triphenylphosphine polystyrene (100-200 mesh, 0.8-1.6 mmol Triphenylphosphine polystyrene (200-400 mesh, 1.0-1.5 mmol 4-Diphenylphosphino Polystyrene Resin cross-linked with 2% DVB (200-400mesh) (1.0-2.0mmol/g) diphenylphosphinated Copolymer of styrene and divinylbenzene, diphenylphosphinated, Diphenylphosphino-polystyrene, Polystyrene crosslinked with divinylbenzene, diphenylphosphinated TRIPHENYLPHOSPHINE RESIN, 1% CROSSL.WITH DVB, 1.2-1.5 MMOL/G, 200-400 MESH Triphenylphosphine resin, 1% crossl. with DVB, 1.2-1.5 mmol/g, 100-200 mesh 4-Diphenylphosphino polystyrene resin, cross-linked with 2% DVB Diphenyl(4-vinylphenyl)phosphine-divinylbenzene-styrene copolymer Triphenylphosphine, polyMer-bound 100-200 Mesh, extent of labeling: ~3.0 MMol/g loading, 2 % cross-linked with divinylbenzene Triphenylphosphine resin(1.0-1.5 meq/g, 100-200 mesh) Triphenylphosphine, polymer-supported, 1.4 to 2.0mmol/g on polystyrene Triphenylphosphine resin, 1% crosslinked with DVB, 1.0-1.5mmol/g -C6H4P(C6H5)2 Triphenylphosphine, polymer supported1.4-2.0mmol/g on polystyrene 200-400 mesh2% DVB loading Triphenylphosphine, polymer-bound 100-200 mesh, extent of labeling: ~1.6 mmol/g loading Triphenylphosphine, polymer-bound 100-200 mesh, extent of labeling: ~3 mmol/g triphenylphosphine loading POLYMER SUPPORTED TRIPHENYLPHOSPHINE POLYMER-BOUND TRIPHENYLPHOSPHINE TRIPHENYLPHOSPHINE POLYMER BOUND 39319-11-4 C20H17PmC10H10nC8H8x -C6H4PC6H52 Supported Reagents Supported Synthesis Specialty Synthesis Ligands Combinatrial Chemistry Resins Mitsunobu Reaction Polymer-Supported Reagents Phosphines (Mitsunobu Reaction) Combinatorial Chemistry Mitsunobu Reaction Phosphines (Mitsunobu Reaction) Polymer-Supported Reagents