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TRIPHENYLPHOSPHINE RESIN

CAS No.
39319-11-4
Chemical Name:
TRIPHENYLPHOSPHINE RESIN
Synonyms
POLYMER-BOUND TRIPHENYLPHOSPHINE;POLYMER SUPPORTED TRIPHENYLPHOSPHINE;TRIPHENYLPHOSPHINE POLYMER BOUND;PL-TPP RESIN;-C6H4P(C6H5)2;PL-TPP MP-RESIN;POLYSTYRENE-PPH2;diphenylphosphinated;TRIPHENYLPHOSPHINE PS;TRIPHENYLPHOSPHINE RESIN
CBNumber:
CB9181407
Molecular Formula:
C18H15P
Molecular Weight:
262.285461
MDL Number:
MFCD20489348
MOL File:
39319-11-4.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

TRIPHENYLPHOSPHINE RESIN Properties

storage temp. 2-8°C
form Beads
color White to yellow
Sensitive Air Sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H312-H315-H319-H332-H335-H302+H312+H332
Precautionary statements  P261-P280-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  22-43-20/21/22-36/37/38
Safety Statements  36/37-36-26
WGK Germany  3
10-23
HS Code  29310099

TRIPHENYLPHOSPHINE RESIN price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 14664 Triphenylphosphine, polymer-bound 100-200?mesh, extent of labeling: ~3.2?mmol/g loading 39319-11-4 25g $304 2024-03-01 Buy
Alfa Aesar L19478 Triphenylphosphine, polymer-supported 1.4-2.0 mmol/g on polystyrene 39319-11-4 1g $31.1 2023-06-20 Buy
Alfa Aesar L19478 Triphenylphosphine, polymer-supported 1.4-2.0 mmol/g on polystyrene 39319-11-4 5g $96.3 2021-12-16 Buy
Strem Chemicals 15-6730 Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked) 39319-11-4 1g $48 2021-12-16 Buy
Strem Chemicals 15-6730 Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked) 39319-11-4 5g $143 2021-12-16 Buy
Product number Packaging Price Buy
14664 25g $304 Buy
L19478 1g $31.1 Buy
L19478 5g $96.3 Buy
15-6730 1g $48 Buy
15-6730 5g $143 Buy

TRIPHENYLPHOSPHINE RESIN Chemical Properties,Uses,Production

Chemical Properties

white to yellow beads

Uses

Polymer-bound triphenylphosphine is a solid-supported reagent that can be used as a better alternative to triphenylphosphine in the Mitsunobu reaction.
It can also be used:

  • For the esterification of alkylphosphonic acids using primary alcohols in the presence of iodine and imidazole.
  • To catalyze the conversion of 3-[3-(1,3-dioxolan-2-yl)-1-hydroxypropyl]pyridine to 3-[1-bromo-3-(1,3-dioxolan-2-yl)propyl]pyridine using carbon tetrabromide.
  • To isomerize (Z)-nitro olefins to the (E)-isomers.
  • To prepare polymer-bound ylides which are useful in Wittig reactions.
  • To convert alcohols or carboxylic acids to the corresponding chlorides.
  • In combination with carbon tetrachloride for the coupling N-alkoxycarbonyl α-amino acids and primary amines to form the corresponding amides.

Uses

Triphenylphosphine resin is used for the preparation of polymer bound ylids which are useful for Wittig reactions.

TRIPHENYLPHOSPHINE RESIN Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 72)Suppliers
Supplier Tel Email Country ProdList Advantage
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9636 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 13417 58
BOC Sciences
16314854226; +16314854226 inquiry@bocsci.com United States 19741 58
Hebei Weibang Biotechnology Co., Ltd
+8617732866630 bess@weibangbio.com China 18153 58
SUZHOU SENFEIDA CHEMICAL CO.,LTD
+86-0512-83500002 +8615195660023 sales@senfeida.com China 23046 58
LEAPCHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 43340 58
Shanghai Acmec Biochemical Technology Co., Ltd.
+undefined18621343501 product@acmec-e.com China 33338 58
SHANGHAI KEAN TECHNOLOGY CO., LTD.
+8613817748580 cooperation@kean-chem.com China 40066 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76

TRIPHENYLPHOSPHINE RESIN Spectrum

TRIPHENYLPHOSPHINE POL. BOUND, 100-200 M ESH, ~1.6 MMOL/G TRIPHENYLPHOSPHINE POL. BOUND, 200-400 M ESH, ~3 MMOL/G TriphenylphosphineResin1%DvbMesh,1-1.5Mmol/G Triphenylphosphine resin, Crosslinked with 1% DVB, 1.2-1.5 mmol/g, 100-200 mesh Triphenylphosphine resin, 1% crosslinked with DVB 4-DIPHENYLPHOSPHINO POLYSTYRENE RESIN COPOLYMER OF STYRENE AND DIVINYLBENZENE, DIPHENYLPHOSPHINATED DIPHENYLPHOSPHINOBENZOYL NOVAGEL(TM) AM RESIN DIPHENYLPHOSPHINO-POLYSTYRENE MACROPOROUS POLYMER SUPPORTED TRIPHENYLPHOSPHINE PL-TPP RESIN PL-TPP MP-RESIN POLYSTYRENE CROSSLINKED WITH DIVINYL-BENZENE, DIPHENYLPHOSPHINATED POLYSTYRENE-PPH2 TRIPHENYLPHOSPHINE, POLYMER-SUPPORTED TRIPHENYLPHOSPHINE POLYSTYRENE TRIPHENYLPHOSPHINE PS TRIPHENYLPHOSPHINE PS RESIN TRIPHENYLPHOSPHINE RESIN TRIPHENYLPHOSPHINE NOVAGEL TRIPHENYLPHOSPHINE NOVAGEL(TM) 4-DIPHENYLPHOSPHINO POLYSTYRENE RESIN, CROSS-LINKED WITH 2% DVB: (1.0-2.0MMOLP/G), 200-400MESH Triphenylphosphine polystyrene (100-200 mesh, 0.8-1.6 mmol Triphenylphosphine polystyrene (200-400 mesh, 1.0-1.5 mmol 4-Diphenylphosphino Polystyrene Resin cross-linked with 2% DVB (200-400mesh) (1.0-2.0mmol/g) diphenylphosphinated Copolymer of styrene and divinylbenzene, diphenylphosphinated, Diphenylphosphino-polystyrene, Polystyrene crosslinked with divinylbenzene, diphenylphosphinated TRIPHENYLPHOSPHINE RESIN, 1% CROSSL.WITH DVB, 1.2-1.5 MMOL/G, 200-400 MESH Triphenylphosphine resin, 1% crossl. with DVB, 1.2-1.5 mmol/g, 100-200 mesh 4-Diphenylphosphino polystyrene resin, cross-linked with 2% DVB Diphenyl(4-vinylphenyl)phosphine-divinylbenzene-styrene copolymer Triphenylphosphine, polyMer-bound 100-200 Mesh, extent of labeling: ~3.0 MMol/g loading, 2 % cross-linked with divinylbenzene Triphenylphosphine resin(1.0-1.5 meq/g, 100-200 mesh) Triphenylphosphine, polymer-supported, 1.4 to 2.0mmol/g on polystyrene Triphenylphosphine resin, 1% crosslinked with DVB, 1.0-1.5mmol/g -C6H4P(C6H5)2 Triphenylphosphine, polymer supported1.4-2.0mmol/g on polystyrene 200-400 mesh2% DVB loading Triphenylphosphine, polymer-bound 100-200 mesh, extent of labeling: ~1.6 mmol/g loading Triphenylphosphine, polymer-bound 100-200 mesh, extent of labeling: ~3 mmol/g triphenylphosphine loading POLYMER SUPPORTED TRIPHENYLPHOSPHINE POLYMER-BOUND TRIPHENYLPHOSPHINE TRIPHENYLPHOSPHINE POLYMER BOUND 39319-11-4 C20H17PmC10H10nC8H8x -C6H4PC6H52 Supported Reagents Supported Synthesis Specialty Synthesis Ligands Combinatrial Chemistry Resins Mitsunobu Reaction Polymer-Supported Reagents Phosphines (Mitsunobu Reaction) Combinatorial Chemistry Mitsunobu Reaction Phosphines (Mitsunobu Reaction) Polymer-Supported Reagents