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TUNGSTEN SULFIDE

CAS No.
12138-09-9
Chemical Name:
TUNGSTEN SULFIDE
Synonyms
TUNGSTEN DISULFIDE;Tungsten Disulfide Nanopowder;EASCHEM;Tungsten Sulde;powder, 2 Tungsten sulfid;Wolframdisulfid;TUNGSTEN SULFIDE;ungstendisulfide;WS2 powder 0.88μm
CBNumber:
CB9239043
Molecular Formula:
S2W
Molecular Weight:
247.97
MDL Number:
MFCD00011467
MOL File:
12138-09-9.mol
MSDS File:
SDS
Last updated:2023-10-17 17:11:57

TUNGSTEN SULFIDE Properties

Melting point 1480 °C
Density 7.5 g/mL at 25 °C(lit.)
RTECS YO7716000
solubility insoluble in H2O, HCl, alkaline solutions
form powder
color Dark gray
Specific Gravity 7.5
Water Solubility Slightly soluble in water.
Exposure limits ACGIH: TWA 3 mg/m3
NIOSH: TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference 12138-09-9(CAS DataBase Reference)
EWG's Food Scores 1
EPA Substance Registry System Tungsten sulfide (WS2) (12138-09-9)
Bandgap 1.4 - 2.01 eV
Electronic properties 2D semiconductor

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  -
TSCA  Yes
HS Code  28291900
NFPA 704
0
1 0

TUNGSTEN SULFIDE price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 914290 Tungsten disulfide quantum dots 12138-09-9 20ML $197 2024-03-01 Buy
Sigma-Aldrich 914290 Tungsten disulfide quantum dots 12138-09-9 50ML $386 2024-03-01 Buy
Sigma-Aldrich 790583 Tungsten(IV) sulfide nanopowder, 90 nm avg. part. size (SEM), 99% trace metals basis 12138-09-9 5g $102 2024-03-01 Buy
Sigma-Aldrich 243639 Tungsten(IV) sulfide powder, 2 μm, 99% 12138-09-9 50g $95.5 2024-03-01 Buy
Sigma-Aldrich 901474 Tungsten sulfide single crystalline monolayer flakes on sapphire 12138-09-9 1EA $391 2023-06-20 Buy
Product number Packaging Price Buy
914290 20ML $197 Buy
914290 50ML $386 Buy
790583 5g $102 Buy
243639 50g $95.5 Buy
901474 1EA $391 Buy

TUNGSTEN SULFIDE Chemical Properties,Uses,Production

Description

Tungsten sulfide (S2W) is a chemical compound that exists naturally in the form of a rare mineral called tungstenite. It is used as a principal component of catalysts in processes such as hydrogenation of crude oil, hydrodesulfurization and hydrodenitrification reactions. It is widely employed as additives in solid lubricants to improve lubricants and extreme pressure properties and antiwear properties especially in environments of high temperature, high pressure, high vacuum, high load and with radiation and corrosive media. Due to the above property, the nanoscale of tungsten sulfide can be also added in the casting process which helps make cast metal have a certain self-lubricating properties and have an excellent adsorption capacity on the metal surface. It can also be used as solid-state secondary lithium battery cathodes and other electrochemical devices. Besides, it is found that the friction coefficient of tungsten sulfide is relatively small, which makes it an additive in other metal powder for a stable friction coefficient. It also finds application in semiconductor materials, inorganic nanotubes, etc.

Uses

Tungsten disulfide (WS2) in bulk has been used for many years as a dry lubricant due to how it exhibits properties of a low coefficient of friction, high chemical stability, and thermal stability. In 1992, it was discovered that the structure of WS2 made it capable of forming nanotube structures. These nanotubes were the first examples of WS2 being used as a low-dimensional material.
After the discovery of simple mechanical exfoliation techniques to isolate single layers of 2-D materials, it was possible to study the properties of WS2 flakes. It was shown that, just like MoS2, the band-gap of WS2 change from an indirect band-gap of 1.4eV to a direct band-gap of 2eV when changing from a bulk material to a 2-D material. Due to its band-gap, WS2 is seen as a significantly interesting material for many areas of application.
WS2 possesses a high on/off ratio in field-effect transistors, controllable spin and valley polarisation, strong geometrical confinement of excitons, and tunable photoluminescence. Additionally, WS2 could lead to increased interest in areas such as photodetectors and multi-junction photovoltaics.
Besides, WS2 is used, in conjunction with other materials, as catalyst for hydrotreating of crude oil.
Lamellar tungsten disulfide is used as a dry lubricant for fasteners, bearings, and molds under the brand name Dicronite.

References

https://en.wikipedia.org/wiki/Tungsten_disulfide
https://www.alfa.com/zh-cn/catalog/011829/
http://www.us-nano.com/inc/sdetail/1030
http://www.azonano.com/article.aspx?ArticleID=3360

Description

Few-layer?tungsten disulfide (WS2) film has a 2D-layered structure with a narrow indirect bandgap of of 1.35 eV. In contrast, the monolayer film possesses a direct bandgap of 2.1 eV.

Preparation

Synthetic?- Chemical Vapour Transport (CVT)

Application

Due to its distinctive electron configuration and high specific surface area, few-layer tungsten disulfide nanosheets have potential applications in electrodes and energy storage devices, supercapacitors, and photoelectrochemical cells as a catalyst for hydrogen evolution reactions (HERs). With?tunable electromagnetic absorption, it has practical applications?against electromagnetic pollution. WS2?is also a great potential candidate in photothermal therapy for the ablation of cancer cells, when NIR light is absorbed and converted into heat.

Synthesis

High-quality tungsten disulfide monolayer?films?are grown directly on the substrates (sapphire) by? the chemical vapour deposition (CVD) method.

Chemical Properties

Grayish-black solid. Mp above 1480C, can lubricate at temperatures above 2400F (1316C). Attacked by fluorine and hot sulfuric and hydrogen fluoride.

Uses

Tungsten sulfide is used as a component of catalysts for hydrotreating of crude oil, hydrodesulfurization and hydrodenitrification reactions. It finds application as solid-state secondary lithium battery cathodes and other electrochemical devices. It is found that it forms inorganic nanotubes, which is better reinforcing agents than carbon nanotubes. Tungsten sulfide addition to epoxy resin improves adhesion, fracture toughness and strain energy release rate.

Uses

Tungsten disulfide (WS2) is used as a solid lubricant that can withstand high temperatures. It is also used as a spray lubricant.

Uses

Tungsten sulfide possesses a pseudo 2 dimensional structure with applications in the Petrochemical industry as a desulfurization catalyst. Tungsten Sulfide nanoparticles have drawn research interest due to their potential in solid-state lubricants; coatings and photocatalysts.

Definition

ChEBI: Tungsten disulfide is a sulfide salt.

Flammability and Explosibility

Not classified

TUNGSTEN SULFIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 214)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21689 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Fuxin Pharmaceutical
+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 10297 58
SINOPRO.CO.LTD
0082-42-721-7177 michael@sinopro.co.kr South Korea 298 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
Connect Chemicals GmbH
2102-207739 inquiries@connectchemicals.com Germany 265 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23556 58

View Lastest Price from TUNGSTEN SULFIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TUNGSTEN SULFIDE pictures 2023-09-06 TUNGSTEN SULFIDE
12138-09-9
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
 EASCHEM pictures 2021-07-09 EASCHEM
12138-09-9
US $100.00 / KG 1KG 99.9% 100 Ton/Tons per Month Tungsten Disulfide Hebei Xibaijie Biotechnology Co., Ltd.
TUNGSTEN SULFIDE pictures 2019-07-06 TUNGSTEN SULFIDE
12138-09-9
US $1.00 / kg 1kg 99% Customized Career Henan Chemical Co
  • TUNGSTEN SULFIDE pictures
  • TUNGSTEN SULFIDE
    12138-09-9
  • US $0.00-0.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
  •  EASCHEM pictures
  • EASCHEM
    12138-09-9
  • US $100.00 / KG
  • 99.9%
  • Hebei Xibaijie Biotechnology Co., Ltd.

TUNGSTEN SULFIDE Spectrum

Tungsten Disulfide dispersion Tungsten sulfide (metals basis) Tungsten(IV) sulfide powder Tungsten disulfide, particle size 0.7-1.1 micrometer Wolfram(IV)disulfide tungsten disuIlfide Tungsten Disulfide Micro powder Tungsten Disulfide Nanoparticles Tungsten sulfid Tungsten(IV) sulfide powder, 2 MuM, 99% Tungsten(IV) sulfide nanopowder, 90 nm avg. part. size (SEM), 99% trace metals basis Tungsten disulfide Crystal, 99.995% Tungsten sulfide, 99.5% trace metals basis TUNGSTEN(IV) SULFIDE TUNGSTEN SULFIDE tungstensulfide(ws2) TUNGSTEN DISULFIDE, POWDER, <2 MICRON, 9 9% TUNGSTEN SULFIDE, 99.8% (METALS BASIS) TUNGSTEN DISULFIDE 99%,PARTICLE SIZE 0.7-1.1 MICROMETER Tungsten(IV)sulfide(99.5%-W) Wolframdisulfid TUNGSTEN(IV) SULFIDE: 99.5% tungsten disulphide Tungsten bisulfide Single layer tungsten(IV) disulfide, 1 mg/mL dispersion in water, size: 0.1 - 4 μm, thickness: approx. 1 nm Single layer tungsten(IV) disulfide, 1 mg/mL dispersion in ethanol, size: 0.1 - 4 μm, thickness: approx. 1 nm Tungsten(IV) Sulfide(WS2) nm 99.9%tungsten disulfide TUNGSTEN DISULFIDE, 99%TUNGSTEN DISULFIDE, 99%TUNGSTEN DISULFIDE, 99% EASCHEM Tungsten disulfide(WS2) TSKgel(R) DEAE-5PW Guards and Guardgel Kits Tungstendisulfide Inorganic Fullerenes ungstendisulfide Tungsten Disulfide Crystal Tungsten Disulfide Few-Layer Film Tungsten Disulfide Monolayer Film Tungsten(IV) sulphide, 99% Tungsten sulfide nanopowder, APS 90 nm, 99% Tungsten Sulde Tungsten Disulfide (WS2) Aerosol Spray (13Oz/369g) Tungsten Disulfide extrapure, 99.9% Tungsten Disulfide Coating TUNGSTEN DISULFIDE Tungsten Disulfide Nanopowder WS2 powder 0.88μm powder, 2  Tungsten (IV) sulfide, 99.9% Mechanically Exfoliated Monolayer WS2 On Substrates Monolayer Tungsten Disulfide (WS2) Quantum Dots Monolayer Tungsten Disulfide (WS2) Quantum Dots Powder CVD Method Monolayer WS2 Monolayer Tungsten Disulfide (WS2) Nano Size Monolayer Tungsten Disulfide (WS2) 12138-09-9 WS2 S2W Catalysis and Inorganic Chemistry