ChemicalBook >> CAS DataBase List >>1,5-Diphenylcarbazide

1,5-Diphenylcarbazide

CAS No.
140-22-7
Chemical Name:
1,5-Diphenylcarbazide
Synonyms
DIPHENYLCARBAZIDE;dianilinourea;Diphenylcartazide;1,3-dianilinourea;Diphenylaminourea;BIPHENYL CARBAZIDE;TIMTEC-BB SBB008713;S-DIPHENYLCARBAZIDE;DiphenylCarbazideGr;1,5-Diphenylcarbazid
CBNumber:
CB9266061
Molecular Formula:
C13H14N4O
Molecular Weight:
242.28
MDL Number:
MFCD00003013
MOL File:
140-22-7.mol
MSDS File:
SDS
Last updated:2023-05-04 17:34:33

1,5-Diphenylcarbazide Properties

Melting point 170-175 °C(lit.)
Boiling point 385.1°C (rough estimate)
Density 1.31 g/cm3
refractive index 1.6120 (estimate)
storage temp. 2-8°C
solubility aqueous acetone: passes test
form Powder or Flakes
pka 9.98±0.43(Predicted)
color White to cream
Odor Odorless
Water Solubility Soluble in glacial acetic acid, alcohol and acetone. Slightly soluble in water.
Sensitive Light Sensitive
Merck 14,3321
BRN 752039
Stability Stable. Light sensitive. Incompatible with strong oxidizing agents.
CAS DataBase Reference 140-22-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 1W1XPA8N0P
NIST Chemistry Reference N'',n'''-diphenylcarbonohydrazide(140-22-7)
EPA Substance Registry System Carbonic dihydrazide, 2,2'-diphenyl- (140-22-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  FF2750000
8-10-23
TSCA  Yes
HazardClass  IRRITANT
HS Code  29280090
NFPA 704
1
2 1

1,5-Diphenylcarbazide price More Price(51)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 259225 1,5-Diphenylcarbazide ACS reagent 140-22-7 25g $126 2024-03-01 Buy
Sigma-Aldrich 259225 1,5-Diphenylcarbazide ACS reagent 140-22-7 100g $257 2024-03-01 Buy
Sigma-Aldrich 1.03091 1,5-Diphenylcarbazide GR for analysis and redox indicator ACS,Reag. Ph Eur 140-22-7 25g $178 2024-03-01 Buy
Sigma-Aldrich 1.03091 1,5-Diphenylcarbazide GR for analysis and redox indicator ACS,Reag. Ph Eur 140-22-7 100g $578 2024-03-01 Buy
TCI Chemical D1513 1,5-Diphenylcarbonohydrazide >98.0%(HPLC) 140-22-7 25g $59 2024-03-01 Buy
Product number Packaging Price Buy
259225 25g $126 Buy
259225 100g $257 Buy
1.03091 25g $178 Buy
1.03091 100g $578 Buy
D1513 25g $59 Buy

1,5-Diphenylcarbazide Chemical Properties,Uses,Production

Chemical Properties

white crystals or powder

Uses

1,5-Diphenylcarbazide is used in the colorimetric determination of chromium, osmium as well as in the detection of cadmium, mercury, magnesium, emetine and aldehydes.

Uses

As indicator in titrating Fe; for the colorimetric determination of Cr, detection of Cd, Hg, Mg, aldehydes, emetine.

Uses

1,5-Diphenylcarbazideis a carbazide derivative used in the colorimteric determination of chromium as well as in the detection of cadmium, mercury, magnesium and aldehydes.

Definition

ChEBI: Diphenylcarbazide is a member of phenylhydrazines.

General Description

1,5-Diphenylcarbazide is a colorimetric reagent commonly employed in the determination of trace metals.

Purification Methods

A common impurity is phenyl-semicarbazide which can be removed by chromatography: ~8g in H2O is placed on a column (polyamide 6 powder, Macherey-Nagel-GmbH-Germany, washed several times with MeOH), eluted with H2O/MeOH/AcOH (1:3:0.04) at 7-8 drops/second, then eluted with the same solvent mixture but diluted 5 fold with H2O. The purification is followed by UV light at 280nm. The effluent is evaporated to dryness in vacuo at ~28o. [chromatography, IR & UV: Willems et al. Anal Chim Acta 51 544 1970]. Recrystallise it from EtOH by adding CCl4 to induce crystallisation, or AcOH to give a white crystalline powder which turns pink in air. It is air and light sensitive and should be stored in the dark under N2. [Beilstein 15 H 292, 15 IV 182.]

4453-80-9
140-22-7
Synthesis of 1,5-Diphenylcarbazide from Methanone, nitro(2-phenyldiazenyl)-, 2-phenylhydrazone
Global( 431)Suppliers
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Shanghai Daken Advanced Materials Co.,Ltd
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View Lastest Price from 1,5-Diphenylcarbazide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1.5-Diphenylcarbonohydrazide pictures 2021-07-13 1.5-Diphenylcarbonohydrazide
140-22-7
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
1.5-Diphenylcarbonohydrazide pictures 2021-07-09 1.5-Diphenylcarbonohydrazide
140-22-7
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
1,5-Diphenylcarbazide pictures 2020-02-02 1,5-Diphenylcarbazide
140-22-7
US $1.00 / KG 1KG 99%HPLC 200KG Career Henan Chemical Co
1,5-Diphenylcabohydrazide 1,5-diphenyl-carbohydrazid 1,5-Diphenylcarbohydrazine 2,2’-diphenylcarbazide Diphenylcarbazide p.a. 1,5-Diphenylcarbazid TIMTEC-BB SBB008713 Diphenylcartazide syM-Diphenylcarbazide, 98%, ACS reagent syM-Diphenylcarbazide, for analysis ACS, 98% 100GR 1,5-DIPHENYLCARBAZIDE GR FOR ANALYSIS AN 1,5-DIPHENYLCARBAZIDE 1,5-DIPHENYLCARBOHYDRAZIDE 1,5-DIPHENYLCARBONOHYDRADIDE 1,5-DIPHENYLCARBONOHYDRAZIDE S-DIPHENYLCARBOHYDRAZIDE S-DIPHENYLCARBAZIDE SYM-DIPHENYLACARBAZIDE SYM-DIPHENYLCARBAZIDE TwophenylseMicarbazide 1,5-Diphenylcarbazide reagent grade 2,2’-diphenyl-carbonicdihydrazid 2,2’-diphenylcarbonicdihydrazide 2,2’-diphenyl-Carbonicdihydrazide 2,2’-Diphenylcarbonicdihy-drazide 1,5-DIPHENYLCARBAZIDE, A.C.S. REAGENT DiphenylCarbazideGr DiphenylCarbazide-(1,5-DiphenylCarbazide) DiphenylCarbazideGr-(1,5-DiphenylCarbazideGr) 2,2'-Diphenylcarbazide 2,2'-Diphenylcarbonic dihydrazide Carbohydrazide, 1,5-diphenyl- Carbonic dihydrazide, 2,2'-diphenyl- n,n’-diphenylcarbazide sym-Diphenylcarbazide, 99+% 1,5-DIPHENYLCARBOHYDRAZIDE REAGENT (ACS) 1,5-diphenylcarbazide, acs dianilinourea 1,5-DIPHENYLCARBAZIDE 98+% 1,5-DIPHENYLCARBAZIDE AR 1,5-Diphenylcarbohydrazide ACS 1,5-Diphenylcarbazide, 97+% 1,5-Diphenylcarbohydrazide, sym.-Diphenylcarbazide 1,5-Diphenylcarbohydrazide, Reagent Sym-diphenylcarbazide, 98%, for analysis ACS sym-Diphenylcarbazide, for analysis ACS N'',N'''-diphenylcarbonohydrazide 1,5-Diphenylcarbazide, reagent grade, ACS 1,5-Diphenylcarbazide, 97.5%, ACS reagent Diphenyl hydrazine indicator solution 1,5-DIPHENYLCARBOHYDRAZIDE PWD 1,5-DIPHENYLCARBOHYDRAZIDE, REAGENT (ACS)1,5-DIPHENYLCARBOHYDRAZIDE, REAGENT (ACS)1,5-DIPHENYLCARBOHYDRAZIDE, REAGENT (ACS) amino-(hydrazinecarbonyl)-diphenylammonium 1,5-Diphenylcarbonohydrazide> 1,5-Diphenylcarbazide,99% Diphenyl carbazide, GR 98%+ CAS No.140-22-7 1,5-Diphenylcarbazide 1,5-DipHenylcarbazide, Extra Pure, SLR, Fisher Chemical