ChemicalBook >> CAS DataBase List >>cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II)

cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II)

CAS No.
1152310-69-4
Chemical Name:
cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II)
Synonyms
C106 Dye;C106 Dye >=85% (HPLC);cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II);Ruthenate(2-), [[2,2′-bipyridine]-4,4′-dicarboxylato(2-)- N1,N1′][4,4′-bis[5-(hexylthio)-2-thienyl]-2,2′-bipyridine- N1,N1′]bis(thiocyanato-N)-
CBNumber:
CB92755637
Molecular Formula:
C44H43N6O4RuS6-
Molecular Weight:
1013.3
MDL Number:
MFCD28118913
MOL File:
1152310-69-4.mol
Last updated:2023-09-01 13:10:41

cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II) Properties

form powder (black)
color Black
Melting point 196 °C (lit.)
solubility Acetonitrile and tert-butyl alcohol (volume ratio: 1/1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H317-H319-H335
Precautionary statements  P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38-43
Safety Statements  26
WGK Germany  3

cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II) price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 791393 C106 Dye ≥85% (HPLC) 1152310-69-4 250mg $314 2023-06-20 Buy
Product number Packaging Price Buy
791393 250mg $314 Buy

cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II) Chemical Properties,Uses,Production

Description

Cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II), also called C106 Dye,  is a ruthenium-based organometallic complex. Because of its high-absorptioncoefficient, it is often used to fabricate of a high-efficiency dye-sensitized solar cell. The light-harvesting efficiency of the device can be improved by  selecting two sensitizers (C106 and organic D131) as co-sensitization. The complementary absorption spectra, favorable energy level alignment, and better surface coverage of the two dyes can reduce recombination and increase electron lifetime, improve Jsc and Voc[1-3]. 

Uses

A ruthenium dye for high-efficiency dye-sensitized solar cells

Power conversion efficiencies of 11.7-12.1% achieved in high-efficiency dye-sensitized solar cells under air-mass 1.5G simulated sunlights.

References

[1] High-Efficiency Dye-Sensitized Solar Cells: The Influence of Lithium Ions on Exciton Dissociation, Charge Recombination, and Surface States. DOI:10.1021/nn101384e.
[2] A selective co-sensitization approach to increase photon conversion efficiency and electron lifetime in dye-sensitized solar cells. DOI: 10.1039/c2cp42959d.
[3] Novel and Stable D–A?π–A Dyes for Efficient Solid-State Dye-Sensitized Solar Cells. DOI: 10.1021/acsomega.7b00067.

cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II) Suppliers

Global( 7)Suppliers
Supplier Tel Email Country ProdList Advantage
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 52927 58
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Energy Chemical 021-58432009 400-005-6266 marketing1@energy-chemical.com China 44843 58
Supplier Advantage
Aladdin Scientific
58
Sigma-Aldrich 80
Energy Chemical 58
C106 Dye cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)( 4,4′-bis(5-(hexylthio)thiophen-2-yl)-2,2′-bipyridyl)ruthenium(II) Ruthenate(2-), [[2,2′-bipyridine]-4,4′-dicarboxylato(2-)- N1,N1′][4,4′-bis[5-(hexylthio)-2-thienyl]-2,2′-bipyridine- N1,N1′]bis(thiocyanato-N)- C106 Dye >=85% (HPLC) 1152310-69-4 C44H44N6O4RuS6