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2-Hydroxybenzyl alcohol

CAS No.
90-01-7
Chemical Name:
2-Hydroxybenzyl alcohol
Synonyms
SALICYL ALCOHOL;SALIGENIN;Salicylic alcohol;SALIGENOL;1‐(2‐Hydroxyphenyl)‐methanol;SALICAIN;Diathesin;SALIGENINE;α,2-toluenediol;α,2-Toluenediol
CBNumber:
CB9303076
Molecular Formula:
C7H8O2
Molecular Weight:
124.14
MDL Number:
MFCD00004617
MOL File:
90-01-7.mol
MSDS File:
SDS
Last updated:2024-11-20 11:41:24

2-Hydroxybenzyl alcohol Properties

Melting point 83-85 °C(lit.)
Boiling point 190.92°C (rough estimate)
Density 1,613 g/cm3
refractive index 1.5035 (estimate)
storage temp. Store below +30°C.
solubility ethanol: soluble5%, clear to very slightly hazy, colorless to light yellow
pka pK1:9.92 (25°C)
form Crystalline Flakes or Powder
color Light beige
Water Solubility 67 g/L (22 ºC)
Merck 14,8325
BRN 1907195
Stability Stable. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents.
LogP 0.730
CAS DataBase Reference 90-01-7(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances SALIGENIN
EWG's Food Scores 1
FDA UNII FA1N0842KB
NIST Chemistry Reference Salicyl alcohol(90-01-7)
EPA Substance Registry System 2-Hydroxybenzenemethanol (90-01-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H335-H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  DO6430000
TSCA  Yes
HS Code  29072900
NFPA 704
1
2 0

2-Hydroxybenzyl alcohol price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.20662 2-Hydroxybenzyl alcohol for synthesis 90-01-7 50g $73.9 2024-03-01 Buy
Sigma-Aldrich 8.20662 2-Hydroxybenzyl alcohol for synthesis 90-01-7 250g $324 2024-03-01 Buy
Sigma-Aldrich 166952 2-Hydroxybenzyl alcohol 99% 90-01-7 25g $51.6 2024-03-01 Buy
Sigma-Aldrich 166952 2-Hydroxybenzyl alcohol 99% 90-01-7 100g $129 2024-03-01 Buy
TCI Chemical H0223 2-Hydroxybenzyl Alcohol >98.0%(GC) 90-01-7 25g $61 2024-03-01 Buy
Product number Packaging Price Buy
8.20662 50g $73.9 Buy
8.20662 250g $324 Buy
166952 25g $51.6 Buy
166952 100g $129 Buy
H0223 25g $61 Buy

2-Hydroxybenzyl alcohol Chemical Properties,Uses,Production

Chemical Properties

Salicyl alcohol: (saligenin, o-hydroxy benzyl alcohol) crystallizes from water in the form of needles or white rhombic crystals. It occurs in nature as the bitter glycoside, salicin CAS: 138-52-3, which is isolated from the bark of Salix helix, S. pentandra, S. praecos, some other species of willow trees, and the bark of a number of species of poplar trees such as Polpulus balsamifera, P. candicans, and P. nigra.

Chemical Properties

light brown crystalline powder

Uses

2-Hydroxybenzyl Alcohol is a phenolic component of a part of a salix bark extract which maintains a minor anti-depressant effect. Phenolic analog with potential for anti-melanomic effect. Also It is an intermediate in the production of phenol formaldehyde res ins (may remain after condensation of the resin); sensitizer in phenol-formaldehyde resins; in loeal anesthetics.

Uses

anesthetic (local), antiinflammatory

Definition

ChEBI: A hydroxybenzyl alcohol that is phenol substituted by a hydroxymethyl group at C-2.

Synthesis Reference(s)

The Journal of Organic Chemistry, 60, p. 5314, 1995 DOI: 10.1021/jo00121a060
Tetrahedron Letters, 10, p. 1739, 1969

General Description

2-Hydroxybenzyl alcohol participates in the selective ring opening reaction of 4H-1,3,2-benzodioxasilines.

Contact allergens

Methylol phenols are sensitizers contained in resins based on phenol and formaldehyde of the resol type. Cross-reactivity is possible with other phenol derivative molecules.

Purification Methods

Crystallise saligenine from water or EtOH/*C6H6 (m 89o). [Beilstein 6 III 4537, 6 IV 5896.]

18544-92-8
90-01-7
Synthesis of 2-Hydroxybenzyl alcohol from Benzene, 1-[(trimethylsilyl)oxy]-2-[[(trimethylsilyl)oxy]methyl]-
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View Lastest Price from 2-Hydroxybenzyl alcohol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Salicyl alcohol pictures 2024-11-19 Salicyl alcohol
90-01-7
US $34.00 / g 99.5% 10g TargetMol Chemicals Inc.
Salicyl alcohol pictures 2024-11-19 Salicyl alcohol
90-01-7
US $34.00 / g 99.5% 10g TargetMol Chemicals Inc.
2-Hydroxybenzyl alcohol pictures 2024-08-07 2-Hydroxybenzyl alcohol
90-01-7
US $0.00-0.00 / KG 1KG 99.0% 1000KG Shaanxi Dideu Medichem Co. Ltd
2-hydroxy-benzenemethano 2-Hydroxybenzenemethanol 2-hydroxy-Benzenemethanol 2-Hydroxymethylphenol alpha,2-Dihydroxytoluene alpha-Hydroxy-o-cresol Benzenemethanol, 2-hydroxy- Benzyl alcohol, o-hydroxy- Diathesin o-hydroxy-benzylalcoho o-Methylolphenol 2-METHYLOLPHENOL 2-HYDROXYBENZYL ALCOHOL HYDROXYBENZYL-2 ALCOHOL RARECHEM AL BD 0029 SALIGENINE SALICAIN O-(HYDROXYMETHYL)PHENOL O-HYDROXYBENZYL ALCOHOL Orthohydroxybenzyl alcohol 2-Hydroxybenzyl alcohol 99% ,2-Dihydroxytoluene 2-hydroxybenzyl alcool 2-Monomethylol phenol Salicyl alcohol~Saligenin 2-Hydroxy Benzyl Alcohol o-Hydroxy Benzyl Alcohol 2-Hydroxybenzylalcohol,99% MONOMETHYLOLPHENOL SALICYL ALCOHOL(RG) α,2-toluenediol 2-hydroxybenzyl alchol a,2-Dihydroxytoluene a-Hydroxy-o-cresol 2-Hydroxybenzyl alcohol,97% o-Hydroxybenzalcohol ω-Hydroxy-o-cresol Hydroxyphenylacetic Methanol 2-Hydroxybenzyl alcohol, (2-Hydroxyphenyl)methanol 2-Hydroxybenzyl alcohol, 97% 25GR 2-Methylolphenol Salicyl Alcohol Saligenin 2-Hydroxybenzyl alcohol CAS:90-01-7 2-HydroxybenzylAlcohol> 2-Hydroxybenzyl Alcohol,>98% 2-HYDROXYBENZYL ALCOHOL FOR SYNTHESIS SALIGENIN SALIGENOL SALICYL ALCOHOL Salicylic alcohol 1‐(2‐Hydroxyphenyl)‐methanol α,2-Toluenediol Salicyl alcohol(2-Methylolphenol,Diathesin,Salicain,Salicyl alcohol,Salicylic alcohol,Saligenin,Saligenol,o-(Hydroxy...) 90-01-7 1990-01-7 1990-1-7 90-10-7 1990-01-07 C6H4OHCH2OH ALCOHOL