ChemicalBook >> CAS DataBase List >>(R)-(-)-Benzyl glycidyl ether
(R)-(-)-Benzyl glycidyl ether
- CAS No.
- 14618-80-5
- Chemical Name:
- (R)-(-)-Benzyl glycidyl ether
- Synonyms
- tert-butyl 3-oxoazepane-1-carboxylate;azepan-3-one;dicyclopropylmethanamine;tert-butyl 3-hydroxyazepane-1-carboxylate;2-(trimethylsilyl)ethanamine;benzyl piperidin-3-ylcarbamate;(2R)-2-(Benzyloxymethyl)oxirane;benzyl 3-hydroxypiperidine-1-carboxylate;tert-butyl 4-hydroxyazepane-1-carboxylate;5-TMP,2Na
- CBNumber:
- CB9320637
- Molecular Formula:
- C10H12O2
- Molecular Weight:
- 164.2
- MDL Number:
- MFCD00068409
- MOL File:
- 14618-80-5.mol
- MSDS File:
- SDS
Last updated:2024-11-18 17:01:59
| Melting point | 88-93°C |
|---|---|
| alpha | -5.4 º (c=5 in toluene) |
| Boiling point | 130 °C (0.1 mmHg) |
| Density | 1.077 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| form | paste (yellow) |
| Specific Gravity | 1.077 |
| color | Colorless to Almost colorless |
| optical activity | [α]20/D 5.4°, c = 5 in toluene |
| Water Solubility | Soluble in water. |
| BRN | 3588399 |
| CAS DataBase Reference | 14618-80-5(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36-37/39 | |||||||||
| RIDADR | NA 1993 / PGIII | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | TX2860020 | |||||||||
| HS Code | 29109000 | |||||||||
| Toxicity | mic-sat 660 nmol/plate MUREAV 298,197,1993 | |||||||||
| NFPA 704 |
|
(R)-(-)-Benzyl glycidyl ether price More Price(44)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 791547 | Titania paste, transparent | 14618-80-5 | 10G | $225 | 2024-03-01 | Buy |
| Sigma-Aldrich | 791547 | Titania paste, transparent | 14618-80-5 | 20G | $326 | 2024-03-01 | Buy |
| Sigma-Aldrich | 720429 | 1H-Pyrazol-3-ylboronic acid hydrate | 14618-80-5 | 1g | $251 | 2023-06-20 | Buy |
| Sigma-Aldrich | 363529 | (R)-(?)-Glycidyl benzyl ether 99% | 14618-80-5 | 1g | $42.4 | 2023-06-20 | Buy |
| TCI Chemical | B2238 | Benzyl (R)-(-)-Glycidyl Ether >98.0%(GC) | 14618-80-5 | 1g | $19 | 2024-03-01 | Buy |
(R)-(-)-Benzyl glycidyl ether Chemical Properties,Uses,Production
Chemical Properties
Colorless to light yellow liqui
Uses
Used in the preparation of the lactone fragment of compactin and mevinolin. Chiron in the preparation of syn-1,3-polyols, dideoxynucleosides, and a spiroacetal cyanohydrin.
Synthesis Reference(s)
Tetrahedron Letters, 21, p. 4807, 1980 DOI: 10.1016/0040-4039(80)80145-6
General Description
1H-Pyrazol-3-ylboronic acid hydrate can be used as a reactant in the Suzuki-Miyaura coupling reaction to synthesize pyrazole derivatives by reacting with different aryl halides over the palladium catalyst.
Safety Profile
Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.
Purification Methods
This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]
(R)-(-)-Benzyl glycidyl ether Preparation Products And Raw materials
Global( 320)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32957 | 60 |
| Shanghai Arbor Chemical Co., Ltd. | 021-60451682 | act@arborchemical.com | CHINA | 904 | 58 |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 8497 | 58 |
| Changzhou Ditong Chemical Co.,Ltd | +86-0519-88299272 | info@edengenechem.com | China | 2158 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49374 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29811 | 58 |
View Lastest Price from (R)-(-)-Benzyl glycidyl ether manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-11-18 | (R)-(-)-Benzyl glycidyl ether
14618-80-5
|
US $0.00-0.00 / KG | 1KG | 98.0% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd | |
 |
2021-07-02 | (R)-()-Glycidyl benzyl ether
14618-80-5
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | |
 |
2020-01-13 | (R)-(-)-Benzyl glycidyl ether
14618-80-5
|
US $9.80 / KG | 1g | ≥99% | 100kg | Career Henan Chemical Co |
-
- (R)-(-)-Benzyl glycidyl ether
14618-80-5
- US $0.00-0.00 / KG
- 98.0%
- Shaanxi Dideu New Materials Co. Ltd
-
- (R)-()-Glycidyl benzyl ether
14618-80-5
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- (R)-(-)-Benzyl glycidyl ether
14618-80-5
- US $9.80 / KG
- ≥99%
- Career Henan Chemical Co
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