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Triethylamine trihydrofluoride

CAS No.
73602-61-6
Chemical Name:
Triethylamine trihydrofluoride
Synonyms
HF;TEA.3HF;TRIETHYLAMINE TRIS(HYDROGEN FLUORIDE);TREAT-HF;trihydrofluoride;riethylamine trihydrofluoride;HYDROGEN FLUORIDE TRIETHYLAMINE;TRIETHYLAMINE TRISHYDROFLUORIDE;MEC-82;Hf triethylaMine
CBNumber:
CB9356360
Molecular Formula:
C6H18F3N
Molecular Weight:
161.21
MDL Number:
MFCD00043294
MOL File:
73602-61-6.mol
MSDS File:
SDS
Last updated:2024-09-11 18:44:42

Triethylamine trihydrofluoride Properties

Melting point -29--27°C
Boiling point 70 °C15 mm Hg(lit.)
Density 0.989 g/mL at 25 °C(lit.)
refractive index n20/D 1.3915(lit.)
Flash point 190 °F
storage temp. Store below +30°C.
solubility soluble in Chloroform, Hexane
form Liquid
Specific Gravity 0.989
color Clear yellow to brown
PH 3 (H2O, 20℃)(saturated aqueous solution)
Water Solubility soluble
Sensitive Hygroscopic
BRN 5522945
Exposure limits ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
CAS DataBase Reference 73602-61-6(CAS DataBase Reference)
EPA Substance Registry System Ethanamine, N,N-diethyl-, trihydrofluoride (73602-61-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Signal word  Danger
Hazard statements  H300+H310+H330-H314
Precautionary statements  P260-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  T+,T,C,Xi,F
Risk Statements  26/27/28-35-36/37/38-20/21/22-11
Safety Statements  26-36/37/39-45-7/9-36/37-36-61-29-16-3
RIDADR  UN 3265 8/PG 2
WGK Germany  3
Hazard Note  Corrosive
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29211910
NFPA 704
2
4 1

Triethylamine trihydrofluoride price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.14371 Triethylamine trishydrofluoride for synthesis 73602-61-6 2ml $25.6 2024-03-01 Buy
Sigma-Aldrich 344648 Triethylamine trihydrofluoride 98% 73602-61-6 5g $28.7 2024-03-01 Buy
Sigma-Aldrich 8.14371 Triethylamine trishydrofluoride for synthesis 73602-61-6 10ml $79.2 2024-03-01 Buy
Sigma-Aldrich 344648 Triethylamine trihydrofluoride 98% 73602-61-6 1kg $1420 2024-03-01 Buy
TCI Chemical T2022 Triethylamine Trihydrofluoride >95.0%(T) 73602-61-6 10g $58 2024-03-01 Buy
Product number Packaging Price Buy
8.14371 2ml $25.6 Buy
344648 5g $28.7 Buy
8.14371 10ml $79.2 Buy
344648 1kg $1420 Buy
T2022 10g $58 Buy

Triethylamine trihydrofluoride Chemical Properties,Uses,Production

Application

The t-butyldimethylsilyl (TBDMS) group is the most widely used 2'-OH protection in synthesis of oligoribonucleotides. The TBDMS-group became much used particularly after it was combined with phosphoroamidite methodology and was also the choice when H-phosphonate based RNA-synthesis was introduced. Removal of TBDMS-protection is most commonly done with 1 M tetrabutylammonium fluoride (TBAF) in tetrahydrofuran (THF). These conditions has proven efficient.

Chemical Properties

clear yellow liquid

Uses

Mild and selective reagent that has been used in the fluorination of a wide variety of compounds. For a review, see Aldrichimica Acta.

Uses

Triethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.

General Description

Triethylamine trihydrofluoride (TREAT-HF) is a mild and selective reagent for the fluorination of a wide variety of compounds.

Triethylamine trihydrofluoride Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 405)Suppliers
Supplier Tel Email Country ProdList Advantage
LEAP CHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 24727 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-81148696 +86-15536356810 1022@dideu.com China 3882 58
Hebei Mojin Biotechnology Co.,Ltd
+86-15028179902 angelia@hbmojin.com China 1177 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18777 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1803 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070 product@chemlin.com.cn CHINA 3009 60
Fluoropharm Co., Ltd.
+86-0571-85586753; +8613336034509 sales@fluoropharm.com China 1376 60
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29883 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58

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View Lastest Price from Triethylamine trihydrofluoride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Triethylamine trihydrofluoride pictures 2024-09-12 Triethylamine trihydrofluoride
73602-61-6
US $0.00 / kg 1kg 99% 50000KG/month Hebei Mojin Biotechnology Co.,Ltd
Triethylamine trihydrofluoride pictures 2024-07-15 Triethylamine trihydrofluoride
73602-61-6
US $0.10 / KG 1KG 99.0% 1000 tons Shaanxi Dideu Medichem Co. Ltd
Triethylamine trihydrofluoride pictures 2022-10-09 Triethylamine trihydrofluoride
73602-61-6
US $0.00-0.00 / KG 1KG 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
HF 37% IN TRIETHYLAMINE MEC-82 TRIETHYLAMINE TRIHYDROFLUORIDE Triethylamin-trihydrofluoride TriethylamineX3Hf Hydrogen fluoride in triethylamine Ethanamine, N,N-diethyl-, trihydrofluoride Triethylamine trihydrofluoride 97% Triethylaminetrihydrofluoride97% HYDROGEN FLUORIDE IN TRIETHYLAMINE: TECH. TRIETHYLAMINE TRIHYDROFLUORIDE: CA 37% HF N,N-Diethylethanamine trihydrofluoride Triethylamine·3hydridefluorine salt Triethylamine·3hydrogen fluoride Triethylamine·trihydrofluoric acid Triethylamine Trihydrofluoride, ca HF Triethylamine trihydrofluoride ,98% Tris(ethyl)amine trihydrofluoride 97% Triethylaminetrihydrofluide Triethylamine trihydrofluoride,Hydrogen fluoride triethylamine Triethylamine trihyd TriethylaMine trihydrofluoride ,97.5% TriethylaMine trihydrofluoride, 97% 25ML TRIETHYLAMINE TRISHYDROFLUORIDE FOR SYNT EthanaMine, N,N-diethyl-, trihydrofluoride (9CI) TriethylaMine tri(hydrogen fluoride) EthanaMine,N,N-diethyl-, hydrofluoride (1:3) Hf triethylaMine TriethylaMine three hydrogen fluoride Triethylamine trishydrofluoride for synthesis amine trihydrofL Ethanamine,N,N-diethyl-, hydrofluoride Triethylamine trighdrofluoride Triethylamine trihydrofluoride ISO 9001:2015 REACH TIANFU-CHEM - Triethylamine trihydrofluoride HF HYDROGEN FLUORIDE TRIETHYLAMINE TRIETHYLAMINE TRISHYDROFLUORIDE TRIETHYLAMINE TRIS(HYDROGEN FLUORIDE) TEA.3HF TREAT-HF riethylamine trihydrofluoride trihydrofluoride Triethylamine-Trihydrofluoride 3-37% HF Triethanamine trihf Triethylamine trihydrofluoride,30-37% 73602-61-6 73602-61-2 C6H15Nx3HF CH3CH23N3HF C6H20F3N C2H53N3HF C6H18F3N C6H15N3FH C6H15N3HF C6H16N2FHF C-X Bond Formation (Halogen) Synthetic Reagents