Triethylamine trihydrofluoride
- CAS No.
- 73602-61-6
- Chemical Name:
- Triethylamine trihydrofluoride
- Synonyms
- HF;TEA.3HF;TRIETHYLAMINE TRIS(HYDROGEN FLUORIDE);TREAT-HF;trihydrofluoride;riethylamine trihydrofluoride;HYDROGEN FLUORIDE TRIETHYLAMINE;TRIETHYLAMINE TRISHYDROFLUORIDE;MEC-82;Hf triethylaMine
- CBNumber:
- CB9356360
- Molecular Formula:
- C6H18F3N
- Molecular Weight:
- 161.21
- MDL Number:
- MFCD00043294
- MOL File:
- 73602-61-6.mol
- MSDS File:
- SDS
Melting point | -29--27°C |
---|---|
Boiling point | 70 °C15 mm Hg(lit.) |
Density | 0.989 g/mL at 25 °C(lit.) |
refractive index |
n |
Flash point | 190 °F |
storage temp. | Store below +30°C. |
solubility | soluble in Chloroform, Hexane |
form | Liquid |
Specific Gravity | 0.989 |
color | Clear yellow to brown |
PH | 3 (H2O, 20℃)(saturated aqueous solution) |
Water Solubility | soluble |
Sensitive | Hygroscopic |
BRN | 5522945 |
Exposure limits |
ACGIH: TWA 2.5 mg/m3 NIOSH: IDLH 250 mg/m3 |
CAS DataBase Reference | 73602-61-6(CAS DataBase Reference) |
EPA Substance Registry System | Ethanamine, N,N-diethyl-, trihydrofluoride (73602-61-6) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05,GHS06 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H300+H310+H330-H314 | |||||||||
Precautionary statements | P260-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
Hazard Codes | T+,T,C,Xi,F | |||||||||
Risk Statements | 26/27/28-35-36/37/38-20/21/22-11 | |||||||||
Safety Statements | 26-36/37/39-45-7/9-36/37-36-61-29-16-3 | |||||||||
RIDADR | UN 3265 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
Hazard Note | Corrosive | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29211910 | |||||||||
NFPA 704 |
|
Triethylamine trihydrofluoride price More Price(34)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 8.14371 | Triethylamine trishydrofluoride for synthesis | 73602-61-6 | 2ml | $25.6 | 2024-03-01 | Buy |
Sigma-Aldrich | 344648 | Triethylamine trihydrofluoride 98% | 73602-61-6 | 5g | $28.7 | 2024-03-01 | Buy |
Sigma-Aldrich | 8.14371 | Triethylamine trishydrofluoride for synthesis | 73602-61-6 | 10ml | $79.2 | 2024-03-01 | Buy |
Sigma-Aldrich | 344648 | Triethylamine trihydrofluoride 98% | 73602-61-6 | 1kg | $1420 | 2024-03-01 | Buy |
TCI Chemical | T2022 | Triethylamine Trihydrofluoride >95.0%(T) | 73602-61-6 | 10g | $58 | 2024-03-01 | Buy |
Triethylamine trihydrofluoride Chemical Properties,Uses,Production
Application
The t-butyldimethylsilyl (TBDMS) group is the most widely used 2'-OH protection in synthesis of oligoribonucleotides. The TBDMS-group became much used particularly after it was combined with phosphoroamidite methodology and was also the choice when H-phosphonate based RNA-synthesis was introduced. Removal of TBDMS-protection is most commonly done with 1 M tetrabutylammonium fluoride (TBAF) in tetrahydrofuran (THF). These conditions has proven efficient.
Chemical Properties
clear yellow liquid
Uses
Mild and selective reagent that has been used in the fluorination of a wide variety of compounds. For a review, see Aldrichimica Acta.
Uses
Triethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.
General Description
Triethylamine trihydrofluoride (TREAT-HF) is a mild and selective reagent for the fluorination of a wide variety of compounds.
Triethylamine trihydrofluoride Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
LEAP CHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 24727 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-29-81148696 +86-15536356810 | 1022@dideu.com | China | 3882 | 58 |
Hebei Mojin Biotechnology Co.,Ltd | +86-15028179902 | angelia@hbmojin.com | China | 1177 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18777 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1803 | 55 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 | sales@fluoropharm.com | China | 1376 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29883 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
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View Lastest Price from Triethylamine trihydrofluoride manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-09-12 | Triethylamine trihydrofluoride
73602-61-6
|
US $0.00 / kg | 1kg | 99% | 50000KG/month | Hebei Mojin Biotechnology Co.,Ltd | ||
2024-07-15 | Triethylamine trihydrofluoride
73602-61-6
|
US $0.10 / KG | 1KG | 99.0% | 1000 tons | Shaanxi Dideu Medichem Co. Ltd | ||
2022-10-09 | Triethylamine trihydrofluoride
73602-61-6
|
US $0.00-0.00 / KG | 1KG | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. |
- Triethylamine trihydrofluoride
73602-61-6
- US $0.00 / kg
- 99%
- Hebei Mojin Biotechnology Co.,Ltd
- Triethylamine trihydrofluoride
73602-61-6
- US $0.10 / KG
- 99.0%
- Shaanxi Dideu Medichem Co. Ltd
- Triethylamine trihydrofluoride
73602-61-6
- US $0.00-0.00 / KG
- 98%
- Henan Aochuang Chemical Co.,Ltd.
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