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ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL

CAS No.
6290-17-1
Chemical Name:
ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL
Synonyms
FRAISTONE;NSC 6547;fruity ketal;Fraistone(kosher);Astrin strawberry ester;ETHYL DIMETHYL DIOXOLANE ACETATE;Ethyl actoacetate propyleneglycol ketal;ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL;ETHYL-2,4-DIMETHYL-1,3-DIOXOLANE-2-ACETATE;Acetoaceticacid,ethylester,1,2-propyleneketal
CBNumber:
CB9387467
Molecular Formula:
C9H16O4
Molecular Weight:
188.22
MDL Number:
MFCD00151819
MOL File:
6290-17-1.mol
MSDS File:
SDS
Last updated:2024-07-21 22:12:10

ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL Properties

Boiling point 90°C 10mm
Density 1.042 g/mL at 25 °C(lit.)
vapor pressure 7.9Pa at 24℃
FEMA 4294 | CIS- AND TRANS-ETHYL 2,4-DIMETHYL-1,3-DIOXOLANE-2-ACETATE
refractive index 1.4280
Flash point 65°C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form clear liquid
color Colorless to Almost colorless
Odor at 100.00 %. fresh fruity apple strawberry licorice
Odor Type fruity
Water Solubility 1.244g/L at 24℃
JECFA Number 1715
BRN 138927
LogP 1.8 at 25℃
Substances Added to Food (formerly EAFUS) CIS- AND TRANS-ETHYL 2,4-DIMETHYL-1,3-DIOXOLANE-2-ACETATE
CAS DataBase Reference 6290-17-1(CAS DataBase Reference)
FDA UNII 087792Q4F6
EPA Substance Registry System 1,3-Dioxolane-2-acetic acid, 2,4-dimethyl-, ethyl ester (6290-17-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS02
Signal word  Warning
Hazard statements  H227
Precautionary statements  P210e-P280a-P370+P378a-P403+P235-P501a
Safety Statements  24/25-23
TSCA  Yes
HS Code  2932990090
NFPA 704
2
0 0

ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W429420 Ethyl dimethyl dioxolane acetate mixture of isomers, ≥97%, FG 6290-17-1 100g $40.7 2024-03-01 Buy
Sigma-Aldrich W429420 Ethyl dimethyl dioxolane acetate mixture of isomers, ≥97%, FG 6290-17-1 sample-k $59.8 2024-03-01 Buy
Sigma-Aldrich W429420 Ethyl dimethyl dioxolane acetate mixture of isomers, ≥97%, FG 6290-17-1 1kg $329 2024-03-01 Buy
TCI Chemical E1417 Ethyl 2-(2,4-Dimethyl-1,3-dioxolan-2-yl)acetate (mixture of diastereoisomers) 6290-17-1 25G $31 2024-03-01 Buy
TCI Chemical E1417 Ethyl 2-(2,4-Dimethyl-1,3-dioxolan-2-yl)acetate (mixture of diastereoisomers) 6290-17-1 100G $79 2024-03-01 Buy
Product number Packaging Price Buy
W429420 100g $40.7 Buy
W429420 sample-k $59.8 Buy
W429420 1kg $329 Buy
E1417 25G $31 Buy
E1417 100G $79 Buy

ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL Chemical Properties,Uses,Production

Aroma

Fruity-floral and warm, sweet odor of good tenacity. The wincy-"fermented-fruit-like" undertones resemble the odor of Strawberry preserve.

Uses in Perfume

ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL has found some use in perfume compositions where a certain deep-fruity note is desirable along with a floral complex. Jasmin, Tuberose, Gardenia and many other floral bases, spicy fragrances, etc. can achieve new and interesting "lifts" from this material, which has an overall effect resembling that of the alkyl-substituted Cyclopentenones and their homoiogues.

Physical properties

Colorless or pale straw-colored oily liquid. Insoluble in water, soluble in alcohol, miscible with oils.

Chemical Properties

ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL is a colorless liquid with a fresh, fruity odor reminiscent of apples and strawberries. It is mainly used to create fresh, fruity top notes to floral fragrances.
Thematerial is available by reaction of ethyl acetoacetate with propane-1,2-diol.

Definition

ChEBI: Cis- and trans-Ethyl 2,4-dimethyl-1,3-dioxolane-2-acetate is a fatty acid ester.

Production Methods

ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL can be produced from Propylene glycol and Ethyl acetoacetate. The latter acts as a ketone to condense with the glycol. The condcnsat ion is normally encouraged by a catalyst and carried out under conditions of azeotropic distillation.

Aroma threshold values

Medium strength odor, fruity type.

Trade name

Fraistone (IFF), Fragolane (Symrise)

57-55-6
141-97-9
6290-17-1
Synthesis of ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL from Propylene glycol and Ethyl acetoacetate

ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 126)Suppliers
Supplier Tel Email Country ProdList Advantage
JINING XINHE CHEMICAL CO., LTD
+8615318402391 sales@xinhepharma.com China 808 58
Nanjing Dolon Biotechnology Co.,Ltd.
18905173768 sales@dolonchem.com CHINA 2972 58
Hubei Jusheng Technology Co.,Ltd.
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Hubei xin bonus chemical co. LTD
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Career Henan Chemica Co
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ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23555 58
Xi'an MC Biotech, Co., Ltd.
029-89275612 +8618991951683 mcbio_sales@163.com China 2255 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250 1026@dideu.com China 23430 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com China 52861 58
ZHEJIANG JIUZHOU CHEM CO., LTD
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View Lastest Price from ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL pictures 2024-07-21 ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL
6290-17-1
US $0.00-0.00 / kg 1kg 98% 10ton JINING XINHE CHEMICAL CO., LTD
ETHYL-2,4-DIMETHYL-1,3-DIOXOLANE-2-ACETATE ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL ETHYL DIMETHYL DIOXOLANE ACETATE 1,3-Dioxolane-2-aceticacid,2,4-dimethyl-,ethylester Ethyl 2-(2,4-dimethyl-1,3-dioxolan-2-yl)acetate NSC 6547 3-dioxolane-2-aceticacid,2,4-dimethyl-ethylester Acetoaceticacid,ethylester,1,2-propyleneketal 2,4-Dimethyl-1,3-dioxolane-2-acetic acid ethyl ester~Ethyl 2,4-dimethyl-1,3-dioxolane-2-acetate Ethyl actoacetate propyleneglycol ketal 2,4-dimethyl-1,3-dioxolane-2-acetic acid ethyl ester CIS- AND TRANS-ETHYL 2,4-DIMETHYL-1,3-DIOXOLANE-2-ACETATE Natural Ethyl acetoacetate propylene glycol ketal Astrin strawberry ester Ethyl 2-(2,4-Dimethyl-1,3-dioxolan-2-yl)acetate (mixture of diastereoisomers) 2-(2,4-Dimethyl-1,3-dioxolan-2-yl)acetic Acid Ethyl Ester ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL USP/EP/BP Fraistone(kosher) fruity ketal FRAISTONE 6290-17-1 Alphabetical Listings E-F Flavors and Fragrances