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Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Chloro(1,5-cyclooctadiene)rhodium(I) dimer structure

CAS No.: 12092-47-6

Chemical Name:: Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Synonyms: Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium;Chloro(1,5-cyclooctadiene)rhodiuM(I);Rhodium, di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-;1,5-Cyclooctadienerhodium(I) chloride dimer, Chloro(1,5-cyclooctadiene)rhodium(I) dimer, Rhodium(I) chloride 1,5-Cyclooctadiene complex dimer;rhodium(1+);[Rh(C8H12)Cl]2;[Rh(1,5-cod)Cl]2;bis(chlororhodium);Chloro(1,5-cycloocta;Di-mu-chlorobis(1,5-cyclooc

CBNumber:: CB9406940

Molecular Formula:: C16H24Cl2Rh2

Molecular Weight:: 493.08

MDL Number:: MFCD00012415

MOL File:: 12092-47-6.mol

MSDS File:: SDS

Last updated:2024-12-18 14:15:30

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Chloro(1,5-cyclooctadiene)rhodium(I) dimer Properties

Melting point	243 °C (dec.) (lit.)
Density	1.94[at 20℃]
vapor pressure	0Pa at 25℃
storage temp.	Inert atmosphere,Room Temperature
solubility	Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.
form	Crystals or Crystalline Powder
color	Orange to orange-brown
Water Solubility	1.56g/L at 20℃
Sensitive	Air Sensitive & Hygroscopic
Exposure limits	ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3 NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
Stability	hygroscopic
LogP	3.16 at 20℃
FDA UNII	7BR4HR5Q6M
NIST Chemistry Reference	Bis(1,5-cyclooctadienerhodium chloride)(12092-47-6)
EPA Substance Registry System	Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di- (12092-47-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H319

Precautionary statements

P264-P280-P305+P351+P338-P337+P313

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-37/39

WGK Germany

TSCA

Yes

HS Code

28439000

NFPA 704

	1
0		0

Chloro(1,5-cyclooctadiene)rhodium(I) dimer price More Price(50)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	227951	Chloro(1,5-cyclooctadiene)rhodium(I) dimer 98%	12092-47-6	5g	$3830	2024-03-01	Buy
TCI Chemical	B1045	Chloro(1,5-cyclooctadiene)rhodium(I) Dimer >98.0%(T)	12092-47-6	1g	$523	2024-03-01	Buy
TCI Chemical	B1045	Chloro(1,5-cyclooctadiene)rhodium(I) Dimer >98.0%(T)	12092-47-6	100mg	$89	2024-03-01	Buy
Alfa Aesar	010466	Chloro(1,5-cyclooctadiene)rhodium(I) dimer	12092-47-6	250mg	$137	2023-06-20	Buy
Alfa Aesar	010466	Chloro(1,5-cyclooctadiene)rhodium(I) dimer	12092-47-6	1g	$480	2023-06-20	Buy

Product number	Packaging	Price	Buy
227951	5g	$3830	Buy
B1045	1g	$523	Buy
B1045	100mg	$89	Buy
010466	250mg	$137	Buy
010466	1g	$480	Buy

Chloro(1,5-cyclooctadiene)rhodium(I) dimer Chemical Properties,Uses,Production

Reaction

Catalyst for coupling 1,3-dienes with activate methylene compounds.
Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones.
Rhodium source for asymmetric reductive aldol reaction.
Cis-hydroboration of terminal alkynes.
Rhodium source for [5 + 2] additions.
Highly enantioselective for [2+2+2] carbocyclization reactions.
Enantioselective hydroboration of cyclopropenes.

Chemical Properties

orange crystals

Uses

It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.

Uses

Chloro(1,5-cyclooctadiene)rhodium(I) dimer ([Rh(COD)Cl]₂) can be:

Employed for the synthesis of rhodium complex of heterocyclic carbenes (NHCs).
Modified and coated on the surface of ferrite magnetic nanoparticles for catalyzing hydroformylation reaction of olefins.
Used for the synthesis of triple-layer structure to be used as a ring-opening polymerization catalyst.
As an effective catalyst for dehydrogenation of amine-borane adducts (hydrogen storage materials) such as ammonia-borane.

General Description

This product has been enhanced for catalytic efficiency.

Flammability and Explosibility

Not classified

Chloro(1,5-cyclooctadiene)rhodium(I) dimer synthesis

Synthesis of Chloro(1,5-cyclooctadiene)rhodium(I) dimer from Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-

Chloro(1,5-cyclooctadiene)rhodium(I) dimer Preparation Products And Raw materials

Raw materials

Ethanol Rhodium(III) chloride hydrate Ethyl acetate 1,5-Cyclooctadiene Dichloro(1,5-cyclooctadiene)palladium(II)

Silver hexafluorophosphate Chloro(triphenylphosphine)gold Chlorotriphenyltin

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Preparation Products

Chloro(1,5-cyclooctadiene)rhodium(I) dimer Suppliers

Global( 341)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Weibang Biotechnology Co., Ltd	+8615531157085	abby@weibangbio.com	China	8810	58
Frapp's ChemicalNFTZ Co., Ltd.	+86 (576) 8169-6106	sales@frappschem.com	China	880	50
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29791	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18751	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
Hangzhou FandaChem Co.,Ltd.	+8615858145714	FandaChem@Gmail.com	China	9139	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32957	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29880	58
Nanjing Dolon Biotechnology Co.,Ltd.	18905173768	sales@dolonchem.com	CHINA	2972	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28172	58

Supplier	Advantage
Hebei Weibang Biotechnology Co., Ltd	58
Frapp's ChemicalNFTZ Co., Ltd.	50
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Nanjing Dolon Biotechnology Co.,Ltd.	58
Hubei Jusheng Technology Co.,Ltd.	58

View Lastest Price from Chloro(1,5-cyclooctadiene)rhodium(I) dimer manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-12-13	Chloro(1,5-cyclooctadiene)rhodium(I) dimer 12092-47-6	US $0.00 / KG	1KG	98%min	30tons/month	WUHAN FORTUNA CHEMICAL CO., LTD
2024-10-28	Chloro(1.5-cyclooctadiene)rhodium(I) Dimer 12092-47-6	US $0.00 / KG	1KG	99%	10 mt	Hebei Weibang Biotechnology Co., Ltd
2024-10-17	Chloro(1,5-cyclooctadiene)rhodium(I) dimer 12092-47-6	US $0.00 / KG	1KG	99%	500000kg	Hebei Weibang Biotechnology Co., Ltd

Chloro(1,5-cyclooctadiene)rhodium(I) dimer
12092-47-6
US $0.00 / KG
98%min
WUHAN FORTUNA CHEMICAL CO., LTD

Chloro(1.5-cyclooctadiene)rhodium(I) Dimer
12092-47-6
US $0.00 / KG
99%
Hebei Weibang Biotechnology Co., Ltd

Chloro(1,5-cyclooctadiene)rhodium(I) dimer
12092-47-6
US $0.00 / KG
99%
Hebei Weibang Biotechnology Co., Ltd

Chloro(1,5-cyclooctadiene)rhodium(I) dimer Spectrum

Chloro(1,5-cyclooctadiene)rhodium(I) dimer(12092-47-6)IR1 Chloro(1,5-cyclooctadiene)rhodium(I) dimer(12092-47-6)IR2

12092-47-6(Chloro(1,5-cyclooctadiene)rhodium(I) dimer)Related Search:

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Bis(1,5-cyclohexadiene)-mu,mu'-dichlorodirhodium Bis(cycloocta-1,5-diene)dichlorodirhodium Chloro(1,5-cyclooctadiene)rhodium dimer Dichloro-bis-1,5-cyclooctadiene dirhodium Di-mu-chlorobis(1,5-cyclooctadiene)dirhodium di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-rhodiu Rhodium 1,5-cyclooctadiene chloride dimer Rhodium chloro(cycloocta-1,5-diene) dimer Rhodium, di-mu-chlorobis(1,5-cyclooctadiene)di- RHODIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER Chloro(1,5-cyclooctadiene)rhodium(I) dimmer,98% (1,5-Cyclooctadiene)rhodiumchloridedimer Chloro(1,5-cycloocta Chloro-(15-cyclooctadiene)-rhodiuM(I)-diMer ([Rh(COD)CI]2 Chloro(1,5-cyclooctadiene)rhodiuM (I) diMer ,98% [C% : 38.62%-39.22%] Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer, Min. 40.8% Rh 500MG Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer,98% [Rh(COD)Cl]2 Bis(1,5-cyclooctadiene)dirhodium(I) Dichloride 1,5-Cyclooctadiene Rhodium(I) Chloride Dimer Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer/ Bis(1,5-cyclooctadienerhodiuM chloride) RhodiuM, di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]di- Dichlorobis(1,5-cyclooctadiene)rhodiuM(I) diMer Chloro(1,5-cyclooctadiene)rhodium(Ⅰ) dimer Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer, 41% Rh, Product of UMicore Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer,[Rh(COD)Cl]2 Chloro(1,5-cyclooctadiene)rhodiuM(Ⅰ) diMer, 41% Rh, Product of UMicore 1,5-CYCLOOCTADIENE RHODIUM(I) CHLORIDE DIMER DI-MU-CHLOROBIS[(1,2,5,6-N)-1,5-CYCLOOCTADIENE]DIRHODIUM DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIRHODIUM DI-MU-CHLOROBIS[(ETA-CYCLOOCTA-1,5-DIENE)RHODIUM (I)] CHLORO(1,5-CYCLOOCTADIENE)RHODATE (I) DIMER CHLORO(1,5-CYCLOOCTADIENE)RHODIUM(I) DIMER Bis(1,5-cyclooctadienerhodium chloride) BIS(1,5-CYCLOOCTADIENE)DIRHODIUM(I) DICHLORIDE BIS(1,5-CYCLOOCTADIENE)-MU,MU'-DICHLORO DIRHODIUM di-mu-chloro-bis(hapto-1,5-cyclooctadiene)dirhodium(I) CHLORO(1,5-CYCLOOCTADIENE)RHODIUM(I) DI& Chloro(1,5-cyclooctadiene)rhodium(I), dimer, 99.9% DI-CHLORO-BIS-(CYCLOOCTA-1,5-DIENE)DIRHODIUM(I) Chloro(1,5-cyclooctadiene)rhodium(I) dimer, min. 40.8% Rh 4-cycloocta-1,5-diene)dirhodium(I) RhodiuM, di-M-chlorobis[(1,2,5,6-h)-1,5-cyclooctadiene]di- Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer 98% Chloro(1,5-cyclooctadiene)rhodium(I)dimer,98% di- mu -chlorobis[(1,2,5,6- eta)-1,5-cyclooctadiene]di-rhodiu chloro(1,5-cyclooctadiene)rhodium(i) dimer DICHLORO(1,5-CYCLOOCTADIENE)RHODIUM(I) DIMER bis((1z,5z)-cycloocta-1,5-diene) bis(chlororhodium) [Rh(C8H12)Cl]2 Bis((1,5-cyclooctadiene)(chloro)rhodium) Chloro(1,5-cyclooctadiene) rhodium(I) dimmer Di-mu-chlorobis(1,5-cyclooc Di-mu-chlorobis(1,5-cyclooctadiene)dirh Chloro(cycloocta-1,5-diene)rhodium(I) dimer 98% Chloro(cycloocta-1,5-diene)rhodium(I) dimer (1,5-Cyclooctadiene)rhodium chloride dimer【Bis(1,5-cyclooctadiene)dirhodium(I) Dichloride】 Chloro(1,5-cyclooctadiene)rhodium(I) Dimer > Di-μ-chlorobis(η-cycloocta-1,5-diene)rhodium(Ⅰ) ooctadiene)rhodium(I) dimer