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4-Chlorophenol

4-Chlorophenol structure

CAS No.: 106-48-9

Chemical Name:: 4-Chlorophenol

Synonyms: PARA CHLORO PHENOL;P-CHLOROPHENOL;4-CHLORPHENOL;4-chloro-1-hydroxybenzene;Chloroether;Phenol,4-chloro-;4-Chlorophenol(form2);4-Chlorophenol 5g [106-48-9];4-CHLOROPHENOL SOLUTION 725 MG/L FORAOX DETERMINATION ACCORDING TO DIN 38409-H41;(GC)>98%

CBNumber:: CB9477357

Molecular Formula:: C6H5ClO

Molecular Weight:: 128.56

MDL Number:: MFCD00002318

MOL File:: 106-48-9.mol

MSDS File:: SDS

Last updated:2024-08-21 22:41:43

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4-Chlorophenol Properties

Melting point	42-45 °C
Boiling point	220 °C (lit.)
Density	1.306 g/mL at 25 °C (lit.)
vapor density	4.43 (vs air)
vapor pressure	1 mm Hg ( 49.8 °C)
refractive index	1.5579
Flash point	240 °F
storage temp.	2-8°C
solubility	ethanol: soluble50mg/mL, clear to very slightly hazy, colorless to faintly brownish-yellow
form	Low Melting Crystalline Mass
pka	9.18(at 25℃)
color	White to pale yellow
Odor	Phenolic
Odor Threshold	30 ppm
Water Solubility	2.7 g/100 mL (20 ºC)
Sensitive	Air Sensitive
Merck	14,2154
BRN	507004
Dielectric constant	9.5（54.0℃）
Stability	Stable. Incompatible with acid chlorides, acid anhydrides, oxidizing agents, iron.
LogP	2.5 at 35℃
CAS DataBase Reference	106-48-9(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	3DLC36A01X
NIST Chemistry Reference	p-Chlorophenol(106-48-9)
EPA Substance Registry System	p-Chlorophenol (106-48-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS07,GHS09

Signal word

Danger

Hazard statements

H302+H312+H332-H314-H411

Precautionary statements

P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338

Hazard Codes

Xn,N

Risk Statements

20/21/22-51/53-50

Safety Statements

28-61-28A-24/25-60-36/37

RIDADR

UN 2020 6.1/PG 3

WGK Germany

RTECS

SK2800000

10-23

TSCA

Yes

HazardClass

6.1

PackingGroup

III

HS Code

29081000

Toxicity

LD50 orally in rats: 0.67 g/kg (Deichmann)

NFPA 704

	1
4		0

4-Chlorophenol price More Price(30)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	8.02254	4-Chlorophenol for synthesis	106-48-9	100g	$43.8	2024-03-01	Buy
Sigma-Aldrich	8.02254	4-Chlorophenol for synthesis	106-48-9	500g	$95.9	2024-03-01	Buy
Sigma-Aldrich	PHR2596	Parachlorophenol Pharmaceutical Secondary Standard; Certified Reference Material	106-48-9	1G	$267	2024-03-01	Buy
Sigma-Aldrich	8.02254	4-Chlorophenol for synthesis	106-48-9	1kg	$145	2024-03-01	Buy
Sigma-Aldrich	185787	4-Chlorophenol ≥99%	106-48-9	5g	$21.3	2024-03-01	Buy

Product number	Packaging	Price	Buy
8.02254	100g	$43.8	Buy
8.02254	500g	$95.9	Buy
PHR2596	1G	$267	Buy
8.02254	1kg	$145	Buy
185787	5g	$21.3	Buy

4-Chlorophenol Chemical Properties,Uses,Production

Chemical Properties

All isomers have a characteristic odor.

Chemical Properties

off-white to light tan crystals or powder

Uses

Biocide; disinfectant for home, hospital and farm.

Uses

antineoplastic

Uses

It is used as main raw material of compounding for medicine, dye, plastic and other industries. 4-Chlorophenol was used in visible-light-induced degradation of 4-chlorophenol in aqueous suspension of pure TiO2.

Uses

Intermediates of Liquid Crystals

Definition

ChEBI: A monochlorophenol substituted at the pare position by a chlorine atom.

Synthesis Reference(s)

The Journal of Organic Chemistry, 50, p. 2145, 1985 DOI: 10.1021/jo00212a029
Tetrahedron Letters, 24, p. 3117, 1983 DOI: 10.1016/S0040-4039(00)88111-3

General Description

White crystals with a strong phenol odor Slightly soluble to soluble in water, depending on the isomer, and denser than water. Noncombustible. Used as an intermediate in organic synthesis of dyes and drugs.

Air & Water Reactions

Slightly soluble to soluble in water.

Reactivity Profile

CHLOROPHENOLS, SOLID are incompatible with acid chlorides, acid anhydrides and oxidizing agents. Also incompatible with iron . Liquefy and darken in color at temperatures above 108°F.

Hazard

Toxic by skin absorption, inhalation, or ingestion; strong irritant to tissue.

Health Hazard

Inhalation causes headache, dizziness, weak pulse. Ingestion causes irritation of mouth and stomach; headache, dizziness, weak pulse. Contact with eyes causes severe irritation and burning. Contact with skin causes irritation and burn; if absorbed, causes same symptoms as inhalation.

Fire Hazard

Special Hazards of Combustion Products: Toxic and irritating hydrogen chloride and chlorine gases may form in fires.

Flammability and Explosibility

Not classified

Safety Profile

Poison by inhalation and intraperitoneal routes. Moderately toxic by ingestion, skin contact, and subcutaneous routes. A severe skin and eye irritant. Human systemic effects by inhalation: excitement, irritability. Mutation data reported. Combustible when exposed to heat or flame. To fight fire, use water, spray, mist, fog, foam, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also CHLOROPHENOLS and CHLORIDES.

Potential Exposure

Monochlorophenols are used in the manufacture of fungicides, slimicides, bactericides, pesticides, herbicides, disinfectants, wood and glue preservatives; in the production of phenolic resins; in the extraction of certain minerals from coal; as a denaturant for ethanol; as an antiseptic; as a disinfectant, and others.

Shipping

UN 2020 (solid); UN2021 (liquid) Chlorophenols, solid and liquid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Distil the phenol, then crystallise it from pet ether (b 40-60o) or hexane, and dry it under vacuum over P2O5 at room temperature. [Bernasconi & Paschalis J Am Chem Soc 108 2969 1986, Beilstein 6 IV 820.]

Incompatibilities

May form explosive mixture with air. Contact with oxidizing agents can cause fire and explosion hazard. Heat produces hydrogen chloride and chlorine. Corrosive to aluminum, copper and other chemically active metals.

Waste Disposal

Incinerate in admixture with flammable solvent in furnace equipped with afterburner and scrubber.

4-Chlorophenol Preparation Products And Raw materials

Raw materials

2-Chlorophenol Phenol 2,4-Dichlorophenol Sulfuryl chloride p-Dichlorobenzene

Preparation Products

Chlorzoxazone ALUMINUM CLOFIBRATE 5-chloro-m-xylene-2,alpha,alpha'-triol 2-(2-CHLOROETHOXY)-BENZENESULFONAMIDE Triadimenol

4-CHLOROPHENETOLE 4-Chlorophenoxyacetic acid Triadimefon 2,6-DIFORMYL-4-CHLOROPHENOL 1,4-Dihydroxyanthraquinone

4-CHLOROPHENOXYACETYL CHLORIDE Dichlorophen 4-Hydroxyphenylboronic acid pinacol ester 4-Mercaptophenol 3,4'-Dichlorodiphenyl ether

4,4'-Biphenol 4-(Trifluoromethoxy)chlorobenzene Mefentrifluconazole Azoic Diazo Component 33 1,4-Dihydroxyanthraquinone

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4-Chlorophenol Suppliers

Global( 534)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5893	58
Hebei Dangtong Import and export Co LTD	+86-13910575315 +86-13910575315	admin@hbdangtong.com	China	1000	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20287	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29791	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18779	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
Hangzhou FandaChem Co.,Ltd.	+8615858145714	FandaChem@Gmail.com	China	9214	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32957	60
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +8618949832763	info@tnjchem.com	China	2986	55
Tianjin Zhongxin Chemtech Co., Ltd.	+86-022-66880623 +8618622897568	sales@tjzxchem.com	China	563	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co,.LTD	58
Hebei Dangtong Import and export Co LTD	58
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
Hefei TNJ Chemical Industry Co.,Ltd.	55
Tianjin Zhongxin Chemtech Co., Ltd.	58

View Lastest Price from 4-Chlorophenol manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-11-21	4-Chlorophenol 106-48-9	US $1.00 / KG	1KG	99%	1000mt/year	Jinan Finer Chemical Co., Ltd
2024-10-29	P-Chlorophenol 106-48-9	US $0.00 / kg	20kg	99%	20 tons	Qingdao RENAS Polymer Material Co., Ltd.
2024-10-24	4-Chlorophenol 106-48-9	US $25.00-15.00 / kg	1kg	99%	20	Hebei Dangtong Import and export Co LTD

4-Chlorophenol
106-48-9
US $1.00 / KG
99%
Jinan Finer Chemical Co., Ltd

P-Chlorophenol
106-48-9
US $0.00 / kg
99%
Qingdao RENAS Polymer Material Co., Ltd.

4-Chlorophenol
106-48-9
US $25.00-15.00 / kg
99%
Hebei Dangtong Import and export Co LTD

4-Chlorophenol Spectrum

4-Chlorophenol(106-48-9)MS 4-Chlorophenol(106-48-9)¹HNMR 4-Chlorophenol(106-48-9)¹³CNMR 4-Chlorophenol(106-48-9)IR1 4-Chlorophenol(106-48-9)IR2 4-Chlorophenol(106-48-9)IR3 4-Chlorophenol(106-48-9)Raman 4-Chlorophenol(106-48-9)ESR

106-48-9(4-Chlorophenol)Related Search:

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