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4,4'-Biphenol

4,4'-Biphenol structure

CAS No.: 92-88-6

Chemical Name:: 4,4'-Biphenol

Synonyms: BIPHENOL;DOD;PPDP;BIPHENOL S;4,4'-DIHYDROXYBIPHENYL;UBL5;[1,1'-Biphenyl]-4,4'-diol;(1R,2R)-Cyclohexane-1,2-diol;asmdod;Asm dod

CBNumber:: CB7448740

Molecular Formula:: C12H10O2

Molecular Weight:: 186.21

MDL Number:: MFCD00002348

MOL File:: 92-88-6.mol

MSDS File:: SDS

Last updated:2024-12-18 14:15:30

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4,4'-Biphenol Properties

Melting point	280-282 °C(lit.)
Boiling point	280.69°C (rough estimate)
Density	1.22
vapor pressure	0Pa at 25℃
refractive index	1.6010 (estimate)
storage temp.	Sealed in dry,Room Temperature
pka	9.74±0.26(Predicted)
form	Powder
color	Off-white to light beige or light gray
Water Solubility	sparingly soluble
BRN	1908886
LogP	2.7 at 20℃
CAS DataBase Reference	92-88-6(CAS DataBase Reference)
EWG's Food Scores	2
FDA UNII	R8994A0904
NIST Chemistry Reference	p,p'-Biphenol(92-88-6)
EPA Substance Registry System	4,4'-Biphenyldiol (92-88-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS07

Signal word

Warning

Hazard statements

H252-H317-H412

Precautionary statements

P235-P261-P272-P273-P280-P302+P352

Hazard Codes

Risk Statements

21-36/37/38-37/38/68-36

Safety Statements

26-36-24/25-36/37

RIDADR

3077

WGK Germany

RTECS

DV4725000

TSCA

Yes

HazardClass

PackingGroup

III

HS Code

29061900

Toxicity

LD50 orl-rat: 9850 mg/kg TXAPA9 28,313,74

NFPA 704

	1
2		0

4,4'-Biphenol price More Price(39)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	168734	4,4′-Dihydroxybiphenyl 97%	92-88-6	25g	$120	2024-03-01	Buy
Sigma-Aldrich	168734	4,4′-Dihydroxybiphenyl 97%	92-88-6	100g	$356	2024-03-01	Buy
TCI Chemical	B0464	4,4'-Dihydroxybiphenyl >99.0%(GC)	92-88-6	25g	$60	2024-03-01	Buy
TCI Chemical	B0464	4,4'-Dihydroxybiphenyl >99.0%(GC)	92-88-6	100g	$138	2024-03-01	Buy
Alfa Aesar	B22240	4,4'-Dihydroxybiphenyl, 99%	92-88-6	25g	$84	2024-03-01	Buy

Product number	Packaging	Price	Buy
168734	25g	$120	Buy
168734	100g	$356	Buy
B0464	25g	$60	Buy
B0464	100g	$138	Buy
B22240	25g	$84	Buy

4,4'-Biphenol Chemical Properties,Uses,Production

Chemical Properties

Powder

Uses

Biphenol is an intermediate used in the manufacture of thermoplastics such as liquid crystalline polymers (LCP), polyesters, polycarbonates and polysulfones.

Uses

4,4'-biphenol be used intermediate liquid crystal polymers raw materials. Synthetic polymers, due to its excellent heat resistance, it is used as polyester, urethane modified monomer, polycarbonate, polysulfone, and epoxy resin, for the manufacture of an excellent engineering plastics and composite materials. Antioxidant antioxidants for rubber and plastics. Dye intermediates or petroleum products stabilizer.

Uses

Intermediates of Liquid Crystals

Definition

ChEBI: A member of the class of hydroxybiphenyls that is biphenyl with hydroxy groups at positions 4 and 4'.

Production Methods

4,4'-Biphenol can be synthesized in excellent yields by debutylation of 3,3',5,5'-tetra-tert-butyl-4,4'-dihydroxybiphenyl. Other production processes are the alkaline fusion of 4,4'-biphenyldisulfonic acid, the boil down of benzidinebisdiazonium salts, and the decarboxylation of 4,4'-dihydroxybiphenyl-2-carboxylic acid. Symmetrically alkylated 4,4'-dihydroxybiphenyls such as 4,4'-dihydroxy-2,2',3,3',5,5',6,6'-hexamethylbiphenyl are preferably obtained by the oxidative coupling of the corresponding substituted monophenols. Here, diphenoquinones are generally formed in the first step which must be reduced. Phenol itself always gives isomeric mixtures of dihydroxybiphenyls on coupling with various oxidants. These mixtures are also formed by alkaline fusion of 4,4'-dihydroxybiphenylsulfone.

Flammability and Explosibility

Not classified

Safety Profile

Poison by intraperitoneal route.Moderately toxic by skin contact. Mildly toxic byingestion. Human mutation data reported. When heated todecomposition it emits acrid smoke and irritating fumes.

Purification Methods

Recrystallise the biphenol from aqueous EtOH preferably under N2 to avoid oxidation to the extended qiunone. It is characterized as the dimethyl derivative (4,4’-dimethoxybiphenyl) from which it is prepared by demethylation. The dimethoxy derivative has m 176.5-177o (from AcOH, EtOH, hexane or *C6H6) and sublimes in vacuo. [Williamson & Rodebush J Am Chem Soc 63 3019 1941, Beilstein 6 I 485, 6 II 962, 6 III 6389, 6 IV 6651.]

4,4'-Biphenol synthesis

Synthesis of 4,4'-Biphenol from 3,3',5,5'-TETRA(TERT-BUTYL)[1,1'-BIPHENYL]-4,4'-DIOL

4,4'-Biphenol Preparation Products And Raw materials

Raw materials

4,4'-Bis(trimethylsilyloxy)biphenyl 6,6'-DI-TERT.BUTYL-4,4'-BI-ORTHO-CRESOL 4-HYDROXY-4'-METHOXYBIPHENYL 4,4'-Dimethoxybiphenyl 3,3',5,5'-TETRA(TERT-BUTYL)[1,1'-BIPHENYL]-4,4'-DIOL

4-Hydroxy-4'-fluorobiphenyl 4,4'-Difluorobiphenyl 1-Chloro-4-fluorobenzene 4-Bromophenol

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Preparation Products

4'-Hydroxy-4-biphenylcarbonitrile 6fapbp 3,3',5,5'-tetraformyl-4,4'-biphenyldiol 4,4'-BIPHENYLDICARBONITRILE Cyanic acid, [1,1'-biphenyl]-4,4'-diyl ester

[1,1'-biphenyl]-4,4'-diyl bis(2-Methylacrylate) 3,3',5,5'-tetrabromo-[1,1'-biphenyl]-4,4'-diol

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4,4'-Biphenol Suppliers

Global( 528)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
HANGZHOU HAILAN CHEMICAL CO.,LTD.	+86-57156122185 +86-15967590394	sales@hailan-chem.com	China	400	58
Jiangxi Huihe Chemical Co., Ltd.	+86-19189228086 +8618858568638	wuzhouding@huihecrop.com	China	886	58
JiangXi Bobert Imp&Exp Co.,LTD	+8618071643627	rze2024@163.com	China	226	58
Hebei Weibang Biotechnology Co., Ltd	+8615531157085	abby@weibangbio.com	China	8807	58
Hebei Mojin Biotechnology Co., Ltd	+86 13288715578 +8613288715578	sales@hbmojin.com	China	12834	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5889	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20283	58
Hebei Saisier Technology Co., LTD	+86-18400010335 +86-18034520335	admin@hbsaisier.cn	China	1016	58
Hebei Zhuanglai Chemical Trading Co.,Ltd	+8613343047651	admin@zlchemi.com	China	3002	58
Hebei Longbang Technology Co., LTD	+86-18633929156 +86-18633929156	admin@hblongbang.com	China	941	58

Supplier	Advantage
HANGZHOU HAILAN CHEMICAL CO.,LTD.	58
Jiangxi Huihe Chemical Co., Ltd.	58
JiangXi Bobert Imp&Exp Co.,LTD	58
Hebei Weibang Biotechnology Co., Ltd	58
Hebei Mojin Biotechnology Co., Ltd	58
Hebei Chuanghai Biotechnology Co,.LTD	58
Henan Fengda Chemical Co., Ltd	58
Hebei Saisier Technology Co., LTD	58
Hebei Zhuanglai Chemical Trading Co.,Ltd	58
Hebei Longbang Technology Co., LTD	58

View Lastest Price from 4,4'-Biphenol manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-12-26	4,4'-Biphenol 92-88-6	US $10.00 / kg	1kg	99%	20ton	Hebei Zhuanglai Chemical Trading Co.,Ltd
2024-12-26	4,4'-Biphenol 92-88-6	US $6.00 / kg	1kg	99%	2000KG/Month	HebeiShuoshengImportandExportco.,Ltd
2024-12-24	4,4'-Biphenol 92-88-6	US $6.00 / kg	1kg	More than 99%	2000KG/Month	Hebei Longbang Technology Co., Ltd

4,4'-Biphenol
92-88-6
US $10.00 / kg
99%
Hebei Zhuanglai Chemical Trading Co.,Ltd

4,4'-Biphenol
92-88-6
US $6.00 / kg
99%
HebeiShuoshengImportandExportco.,Ltd

4,4'-Biphenol
92-88-6
US $6.00 / kg
More than 99%
Hebei Longbang Technology Co., Ltd

4,4'-Biphenol Spectrum

4,4'-Biphenol(92-88-6)¹HNMR 4,4'-Biphenol(92-88-6)IR1 4,4'-Biphenol(92-88-6)IR2 4,4'-Biphenol(92-88-6)Raman

92-88-6(4,4'-Biphenol)Related Search:

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4,4'-Dimethylbiphenyl 4-Phenylphenol Hydroquinone Benzidine 4-tert-Butylcatechol

1-Hydroxyethylidene-1,1-diphosphonic acid 6,6’-diamino-m’-bipheno 2,2'-Biphenol

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(1,1’-Biphenyl)-4,4’-diol BIPHENYL-4,4'-DIOL 4,4'-BIPHENOL 4,4'-BIPHENYLDIOL 1-(9,10-dihydroanthracen-1-yl)-9,10-dihydroanthracene Biphenyl-4,4'-diol 4,4'-Dihydroxybiphenyl 4,4'-Dihydroxydiphenyl 4,4'-Diphenol P,P'-BIPHENOL P,P'-DIPHENOL P,P'-DIHYDROXYBIPHENYL DOD)4,4'-Dihydroxy 4,4'-Dihydroxydiphenyl (DOD) 4,4- twohydroxydiphenyl 4,4'-Dihydroxybiphenyl 97% 4,4'-Dihydroxybiphenyl, 97+% NIMA-interacting protein 1 PIN1 human 4,4'-Dihydroxybiphenyl Vetec(TM) reagent grade, 97% 4,4′-Dihydroxybiphenyl, >=98% 4,4'-Dihydroxy-1,1'-biphenyl 4,4'-Dioxydiphenyl Antioxidant DOD antioxidantdod Asm dod asmdod para,para'-Biphenol p-Dihydroxydiphenyl Phenol p-(p-Hydroxyphenyl)- USAF do-30 usafdo-30 [1,1’-biphenyl]-4,4’-diol 4,4’-bisphenol 4,4'-DIPHENOL 4,4'-DIHYDROXYDIPHENYL 4 4'-BIPHENOL SUBLIMED ZONE-REFINED & 4,4''-BIPHENOL, REFINED 99.5+% 4,4''-BIPHENOL, 99.94% JAPAN IMPORT 4,4μ-Biphenol, 4,4μ-Biphenyldiol, 4,4μ-Diphenol 4,4'-Biphenol,97% 4,4'-Dihydroxybiphenyl ,99% 4,4'-Diphenol PPDP 4,4'-Bipheno 4'-Biphenol 4,4'-Dihydroxybiphenyl, 99%, for synthesis 4,4'-Biphenol > 4,4'-Dihydroxybiphenyl@100 μg/mL in MeOH 4,4'-Biphenol,99% 4,4'-Biphenol ISO 9001：2015 REACH 4,4'-Biphenol 92-88-6 4-(4-hydroxyphenyl)phenol BIPHENOL BIPHENOL S PPDP UBL5 DOD [1,1'-Biphenyl]-4,4'-diol 4,4'-DIHYDROXYBIPHENYL (1R,2R)-Cyclohexane-1,2-diol -Dihydroxybiphenyl