ChemicalBook >> CAS DataBase List >>(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE

CAS No.
494227-36-0
Chemical Name:
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
Synonyms
MANDYPHOS SL-M003-1;]-1,1'-bis[di(3,5-trifL;(aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis{bis[3,5-bis(trifl;(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phos;(SP,SμP)-1,1μ-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene;(αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-,2'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}ferrocene;(SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoroMethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(diMethylaMino)benzyl]ferrocene;(R,R)-1,1'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE;(1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene;(1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene
CBNumber:
CB9671090
Molecular Formula:
C60H42F24FeN2P210*
Molecular Weight:
1364.74
MDL Number:
MFCD04117703
MOL File:
494227-36-0.mol
Last updated:2023-04-23 13:52:06

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Properties

alpha -250.2° (c 1.0, CHCl3)
form solid
color orange-red
Stability store cold

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3
HS Code  29319090

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 73467 (SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97% 494227-36-0 100mg $94 2021-12-16 Buy
Sigma-Aldrich 73467 (SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97% 494227-36-0 500mg $378 2021-12-16 Buy
Strem Chemicals 26-0244 (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97% 494227-36-0 100mg $96 2024-03-01 Buy
Strem Chemicals 26-0244 (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97% 494227-36-0 500mg $355 2024-03-01 Buy
Strem Chemicals 26-0244 (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97% 494227-36-0 2g $1207 2024-03-01 Buy
Product number Packaging Price Buy
73467 100mg $94 Buy
73467 500mg $378 Buy
26-0244 100mg $96 Buy
26-0244 500mg $355 Buy
26-0244 2g $1207 Buy

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Chemical Properties,Uses,Production

Reaction

  1. Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates.
  2. Ligand for Rh-catalyzed hydrogenation of αand β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3diketones.
  3. Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives.
  4. Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones.
  5. Ligand for Cu-catalyzed enantioselective hydroboration of αand β-unsaturated esters and nitriles.
Reactions of 494227-36-0

Chemical Properties

Orange powder

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 37)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18781 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32951 60
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29811 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
+86-021-61551413 +8618813727289 contact@trustwe.com China 5738 58
Henan Allgreen Chemical Co.,LTD
+86-37155567971 +86-13633837469 info@allgreenchem.com China 5983 58
Shaoxin Catsyn Co., Ltd.
+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6114 58
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 52925 58
Mainchem Co., Ltd. +86-0592-6210733 sale@mainchem.com China 32343 55
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109 market03@meryer.com China 40228 62

View Lastest Price from (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE pictures 2020-01-13 (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
494227-36-0
US $1.00 / KG 1KG 98% 200kgs Career Henan Chemical Co
MANDYPHOS SL-M003-1 (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE (aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis{bis[3,5-bis(trifl (S,S)-(-)-2,2'-Bis((R)-(N,N-dimethylamino)-(phenyl)methyl)-1,1'-di(bis(3,5-trifluoromethylphenyl)phosphino)ferrocene (R,R)-1,1'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE (S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-DI[BIS(3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINO]FERROCENE (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene,min.97% (r,r)-1,1'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2'-bis[(r)-α-(dimethylamino)benzyl]ferrocene (acc to cas) (αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-,2'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}ferrocene (SP,SμP)-1,1μ-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene Mandyphos SL-M003-1, (1R,1μR)-1,1μ-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2μ-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS) (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl) phosphino]ferrocene, min. 97% (S,S)-(-)-2,2'-Bis[(R)-(N,N-diMethylaMino)(phenyl)Methyl]-1,1'-bis[di(3,5-trifluoroMethylphenyl)phosphino]ferrocene (aR,aR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis[di(bis-(3,5-trifluoromethyl)phenyl)-phosphino]ferrocene (aR,aR)-2,2'-Bis(a-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis[di-(bis(3,5-trifluoromethyl)-phenyl)phosphino]-ferrocene (1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phos ]-1,1'-bis[di(3,5-trifL (S,S)Fc-1,1’-Bis[bis[3,5-bis(trifluoromethyl)phenyl] phosphino]-2,2’-bis[(R,R)C-(N,N-dimethylamino) phenylmethyl]ferrocene (SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoroMethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(diMethylaMino)benzyl]ferrocene (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene (1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene,97% 494227-36-0 C60H42F24FeN2P2 Solvias Ligands Privileged Ligands Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Chiral Phosphine Ferrocene Series Mandyphos Series