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1,4,7,10,13-Pentaazatridecane

1,4,7,10,13-Pentaazatridecane Structure
1,4,7,10,13-Pentaazatridecane structure
CAS No.
112-57-2
Chemical Name:
1,4,7,10,13-Pentaazatridecane
Synonyms
TETRAETHYLENEPENTAMINE;Tetren;Tetraethyenepentamine;2-Ethanediamine;N1-(2-aMinoethyl)-N2-(2-((2-aMinoethyl)aMino)ethyl)ethane-1,2-diaMine;deh26;TETRENE;TETRAEN;D.E.H. 26;Texlin 400
CBNumber:
CB9715701
Molecular Formula:
C8H23N5
Molecular Weight:
189.3
MDL Number:
MFCD00008168
MOL File:
112-57-2.mol
Last updated:2024-12-18 14:15:32
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1,4,7,10,13-Pentaazatridecane Properties

Melting point -40 °C (lit.)
Boiling point 340 °C
Density 0.998 g/mL at 25 °C (lit.)
vapor density 6.53 (vs air)
vapor pressure <0.01 mm Hg ( 20 °C)
refractive index n20/D 1.505(lit.)
Flash point 365 °F
storage temp. Store below +30°C.
solubility 6540g/l
form Liquid
pka pK1:2.98(+5);pK2:4.72(+4);pK3:8.08(+3);pK4:9.10(+2);pK5:9.67(+1) (25°C,)
color Clear
PH 11.8 (20g/l, H2O, 20℃)
Odor ammonia odor
explosive limit 0.1-15%(V)
Water Solubility SOLUBLE
Sensitive air sensitive
BRN 506966
Stability Stable. Combustible. Incompatible with strong oxidizing agents, mineral acids, halogenated hydrocarbons, hydrogen peroxide.
CAS DataBase Reference 112-57-2(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances TETRAETHYLENEPENTAMINE
FDA 21 CFR 175.105; 175.300; 176.170; 176.180
EWG's Food Scores 2
FDA UNII YZD1C9KQ28
NIST Chemistry Reference Tetraethylenepentamine(112-57-2)
EPA Substance Registry System Tetraethylenepentamine (112-57-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H302+H312-H314-H317-H411
Precautionary statements  P261-P273-P280-P301+P312-P303+P361+P353-P305+P351+P338
Hazard Codes  C,N
Risk Statements  21/22-34-43-51/53
Safety Statements  26-36/37/39-45-61
RIDADR  UN 2320 8/PG 3
WGK Germany  2
RTECS  KH8585000
F  21
Autoignition Temperature 610 °F
HazardClass  8
PackingGroup  III
HS Code  29212900
Hazardous Substances Data 112-57-2(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 3990 mg/kg LD50 dermal Rabbit 660 mg/kg
NFPA 704
1
3 0

1,4,7,10,13-Pentaazatridecane price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich T11509 Tetraethylene pentamine technical grade 112-57-2 1kg $118 2024-03-01 Buy
Sigma-Aldrich T11509 Tetraethylene pentamine technical grade 112-57-2 2.5kg $249 2024-03-01 Buy
Sigma-Aldrich 8.14713 Tetraethylene pentamine (mixture of aliphatic amines) for synthesis 112-57-2 250ML $40.9 2024-03-01 Buy
Sigma-Aldrich 8.14713 Tetraethylene pentamine (mixture of aliphatic amines) for synthesis 112-57-2 1L $100 2024-03-01 Buy
TCI Chemical T0098 Tetraethylenepentamine (so called) 112-57-2 25g $17 2024-03-01 Buy
Product number Packaging Price Buy
T11509 1kg $118 Buy
T11509 2.5kg $249 Buy
8.14713 250ML $40.9 Buy
8.14713 1L $100 Buy
T0098 25g $17 Buy

1,4,7,10,13-Pentaazatridecane Chemical Properties,Uses,Production

Chemical Properties

Tetraethylenepentamine is a yellow, viscous liquid.

Chemical Properties

colourless to green-yellow viscous liquid

Uses

Solvent for sulfur, acid gases, and various resins and dyes; saponifying agent for acidic materials; manufacture of synthetic rubber; dispersant in motor oils; intermediate for oil additives.

Definition

ChEBI: Tetraethylenepentamine is a polyazaalkane. It has a role as a copper chelator.

General Description

A viscous liquid. Slightly less dense than water. Vapors heavier than air. Corrosive to the eyes, skin, mouth, throat and stomach. Vapors irritate the eyes and corrosive to the upper respiratory tract. Vapors may irritate the eyes. Flash point 325°F.

Air & Water Reactions

Soluble in water. Hygroscopic.

Reactivity Profile

1,4,7,10,13-Pentaazatridecane is hygroscopic. 1,4,7,10,13-Pentaazatridecane can react with oxidizing materials and strong acids. 1,4,7,10,13-Pentaazatridecane may attack some forms of plastics.

Hazard

Strong irritant to eyes and skin.

Health Hazard

Inhalation may cause nausea and slight irritation; compound is a sensitizer, and prolonged contact may cause asthma. Ingestion can cause burns of mouth, esophagus, and possibly stomach. Contact with eyes or skin may cause burns. Repeated skin contact may cause dermatitis.

Fire Hazard

Special Hazards of Combustion Products: Ammonia and toxic oxides of nitrogen may form in fires.

Safety Profile

Poison by ingestion and intravenous routes. Moderately toxic by skin contact. Mutation data reported. A corrosive irritant to skin, eyes, and mucous membranes. Combustible when exposed to heat or flame. Can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits toxic fumes of NOx.

Potential Exposure

Tetraethylenepentamine is used as a solvent for resins and dyes, in manufacture of synthetic rubber; and intermediate for oil additives; in papermaking.

Shipping

UN2320 Tetraethylenepentamine, Hazard class: 8; Labels: 8-Corrosive material.

Purification Methods

Distil the amine under vacuum. Also purify via its penta hydrochloride, nitrate or sulfate. Jonassen, Frey and Schaafsma [J Phys Chem 61 504 1957] cooled a solution of 150g of the base in 300mL of 95% EtOH, and added dropwise 180mL of conc HCl, keeping the temperature below 20o. The white precipitate was filtered off, crystallised three times from EtOH/water, then washed with diethyl ether and dried by suction. Reilley and Holloway [J Am Chem Soc 80 2917 1958], starting with a similar solution cooled to 0o, added slowly (keeping the temperature below 10o) a solution of 4.5g-moles of HNO3 in 600mL of aqueous 50% EtOH (also cooled to 0o). The precipitate was filtered by suction, recrystallised five times from aqueous 5% HNO3, then washed with acetone and absolute EtOH and dried at 50o. [For purification via the sulfate see Reilley and Vavoulis (Anal Chem 31 243 1959), and for an additional purification step using the Schiff base with benzaldehyde see Jonassen et al. J Am Chem Soc 79 4279 1957]. [Beilstein 4 IV 1244.]

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. This chemical is strongly alkaline; reacts with acids.

1,4,7,10,13-Pentaazatridecane synthesis

141-43-5
110-85-0
103-76-4
140-31-8
112-57-2
107-15-3
111-40-0
112-24-3
Synthesis of 1,4,7,10,13-Pentaazatridecane from Monoethanolamine

1,4,7,10,13-Pentaazatridecane Preparation Products And Raw materials

Raw materials

AZIRIDINE TRIMER N,N,N'-tris(2-aminoethyl)ethylenediamine 1-(2-Hydroxyethyl)-2-imidazolidinone

Preparation Products

Diethylenetriamine cmtirust agent T-708 ironicion stabilzer additive EQD-3 noncyanide zinc plating additive-TDAE
Triethylenetetramine Triethylenediamine 2-(2-(2-aminoethylamino)ethylamino)ethanol N-[2-(1-piperazinyl)ethyl]ethylenediamine

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1,4,7,10,13-Pentaazatridecane Suppliers

Global( 350)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd 		+86 13288715578 +8613288715578 sales@hbmojin.com China 12834 58
Hebei Yanxi Chemical Co., Ltd. 		+8617531190177 peter@yan-xi.com China 5857 58
Hebei Chuanghai Biotechnology Co,.LTD 		+86-13131129325 sales1@chuanghaibio.com China 5889 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20284 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
Hangzhou FandaChem Co.,Ltd. 		+8615858145714 FandaChem@Gmail.com China 9087 55
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29880 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28172 58
Hubei xin bonus chemical co. LTD 		86-13657291602 linda@hubeijusheng.com CHINA 22963 58
Chongqing Chemdad Co., Ltd 		+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
Supplier Advantage
Hebei Mojin Biotechnology Co., Ltd 		58
Hebei Yanxi Chemical Co., Ltd. 		58
Hebei Chuanghai Biotechnology Co,.LTD 		58
Henan Fengda Chemical Co., Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Hangzhou FandaChem Co.,Ltd. 		55
career henan chemical co 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Hubei xin bonus chemical co. LTD 		58
Chongqing Chemdad Co., Ltd 		58

View Lastest Price from 1,4,7,10,13-Pentaazatridecane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,4,7,10,13-Pentaazatridecane pictures 2024-10-25 1,4,7,10,13-Pentaazatridecane
112-57-2
 US $0.00 / kg 1kg 0.99 20 tons Hebei Yanxi Chemical Co., Ltd.
1,4,7,10,13-Pentaazatridecane pictures 2024-10-11 1,4,7,10,13-Pentaazatridecane
112-57-2
 US $5.00-2.00 / KG 1KG 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
1,4,7,10,13-Pentaazatridecane pictures 2023-12-23 1,4,7,10,13-Pentaazatridecane
112-57-2
 US $42.00-2000.00 / KG 1KG 99% 2000 ton/year Henan Fengda Chemical Co., Ltd

1,4,7,10,13-Pentaazatridecane Spectrum

1,4,7,10,13-Pentaazatridecane(112-57-2)1HNMR1,4,7,10,13-Pentaazatridecane(112-57-2)IR11,4,7,10,13-Pentaazatridecane(112-57-2)IR21,4,7,10,13-Pentaazatridecane(112-57-2)Raman

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n-(2-aminoethyl)-n’-[2-[(2-aminoethyl)amino]ethyl]-2-ethanediamine N1-{2-[2-(2-Amino-ethylamino)-ethylamino]-ethyl}-ethane-1,2-diamine tetraethylenepentamine(tepa) tetraethylpentylamine Texlin 400 TETRAETHYLENE PENTAMINE (MIXTURE OF ALIP TEPA) Tetraethylenepenta TETRENE Tetraethylenepentaminie TETRAETHYLENPENTAMINE TETRAEN Bis(-2-aminoethyl)ethylenediamine 1,11-diamino-3,6,9-triazaundecane TETRAETHYLENEPENTAMINE, TECH. TETRAETHYLENEPENTAMINE, MIXTURE Tetraethylenepentamine,~90% Tetraethylenepeentamine 1,4,7,10,13-PENTAAZATRIDECANE 3,6,9-triaza-1,11-undecanediamine 3,6,9-triazaundecamethylenediamine TetraethylenepentaMine technical grade TETRAETHYLENEPENTAMINE: TECH., (CA. 50% LINEAR, 41% BRANCHED, 5% TRIETHYLENETETRAMINE, 4% POLYETHYLENE POLYAMINES) TETRAEN TEPA (DOW) (Tetraethylenepentamine) 1,2-Ethanediamine, N-(2-aminoethyl)-N'-[2-[(2-aminoethyl)amino]ethyl]- 2-Ethanediamine,N-(2-aminoethyl)-N’-[2-[(2-aminoethyl)amino]ethyl]-1 3,6,9-Triazaundecane-1,11-diamine bis-(2-(2-amino-ethylamino)-ethyl)-amine D.E.H. 26 deh26 n-(2-aminoethyl)-n-(2-((2-aminoethyl)amino)ethyl-1,2-ethanediamine) n-(2-aminoethyl)-n’-(2-((2-aminoethyl)amino)ethyl)-2-ethanediamine Four pentaMine Tetraethylenepentamine TETRAEN, tech. gr. (so called) TetraethylenepentaMine  TetraethylenepentaMine, tech. 250GR TetraethylenepentaMine, tech. 500GR Tetraethylenepentamine,techgr.(~50%linear,41%branched,5%Triethylenetetramine,4%polyethylenepolyamines)TETRAEN Tetraethylenpentamin Tetraethylenepentamine Alkylene polyamine Tetraethylenepentamine (so called) 3,6,9-triazaundecamethylenediamine tetraethylenepentamine N'-(2-Aminoethyl)-N-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine 2,2'-Iminobis(ethyleneimino)bis(ethanamine) Tetrathylenepentamin N'-[2-[2-(2-aminoethylamino)ethylamino]ethyl]ethane-1,2-diamine Tetraethylenepentamine, 95%, tech. 1,2-Ethanediamine, N1-(2-aminoethyl)-N2-[2-[(2-a minoethyl)amino]ethyl]- Tetraethylenepentamine (mixture of branched chain isomers and cyclic compounds) Pentaazatridecane 1,4,7,10,13-Pentaazatridecane ISO 9001：2015 REACH N1-(2-aMinoethyl)-N2-(2-((2-aMinoethyl)aMino)ethyl)ethane-1,2-diaMine Tetraethyenepentamine Tetren TETRAETHYLENEPENTAMINE 2-Ethanediamine thylene pentamine Tetr&Æ