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FEMA 2129

CAS No.
1319-88-6
Chemical Name:
FEMA 2129
Synonyms
BGA*;FEMA 2129;Benzalglycerin;BENZAL GLYCERYL ACETAL;Benzyl glyceryl acetal;Benzaldehyde glycrol acetal;BENZALDEHYDE GLYCERYL ACETAL;5-Hydroxy-2-phenyl-1,3-dioxan;2-PHENYL-1,3-DIOXOLANE-4-METHANOL;Benzaldehyde glycerol cyclic acetal
CBNumber:
CB9744329
Molecular Formula:
C10H12O3
Molecular Weight:
180.2
MDL Number:
MOL File:
1319-88-6.mol
MSDS File:
SDS
Last updated:2024-06-05 17:30:15

FEMA 2129 Properties

Boiling point 152-154 °C(Press: 12 Torr)
Density 1.2115 g/cm3(Temp: 25 °C)
FEMA 2129 | BENZALDEHYDE GLYCERYL ACETAL
color A colourless viscous liquid.
Odor at 100.00 %. cherry bitter almond sweet
Odor Type fruity
JECFA Number 838
LogP 1.98
Substances Added to Food (formerly EAFUS) BENZALDEHYDE GLYCERYL ACETAL
FDA UNII DTD5NUE52Q
EPA Substance Registry System Benzaldehyde, cyclic acetal with 1,2,3-propanetriol (1319-88-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312-P330-P501
Toxicity The acute oral LD50 value in rats was reported as 3?5 ml/kg (2.42-4.09 ml/kg) and the acute dermal LD50 value in rabbits as 5 ml/kg

FEMA 2129 price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Chem-Impex 33848 Benzylglycerylacetal,98-100%(GC),meetsFGspecifications,KOSHER,FEMA2129 98-100%(GC) 1319-88-6 100G $34.94 2021-12-16 Buy
Chem-Impex 33848 Benzylglycerylacetal,98-100%(GC),meetsFGspecifications,KOSHER,FEMA2129 98-100%(GC) 1319-88-6 250G $68.72 2021-12-16 Buy
American Custom Chemicals Corporation FFG0002104 BENZALDEHYDE GLYCERYL ACETAL 95.00% 1319-88-6 5MG $502.85 2021-12-16 Buy
Product number Packaging Price Buy
33848 100G $34.94 Buy
33848 250G $68.72 Buy
FFG0002104 5MG $502.85 Buy

FEMA 2129 Chemical Properties,Uses,Production

Aroma

Used in flavor compositions where lower volatility and improved stability towards air (oxygen) is desirable, and Benzaldehyde as such seems too volatile and unstable.
Benzaldehyde glycrol acetal will liberate Benzaldehyde under influence of heat, water or mild acid, conditions which frequently exist in functional products containing artificial flavor.
Benzaldehyde glycrol acetal itself has a very faint odor, barely reminiscent of Bitter Almond. Soluble in alcohol and oils.
Used in fruit flavors, imitation Almond, Cherry, Nut, etc. in concentrations equal to 100 ppm in the finished consumer product.
Chewing gum may contain up to 800 ppm of the acetal. Chewing gum is the most common outlet for this acetal.

Occurrence

Has apparently not been reported to occur in nature

Preparation

The α, α?- and α, β-isomers are obtained in mixture by heating glycerol and benzaldehyde to 145 to 170°C under a stream of CO2; the isomers are subsequently isolated, exploiting the solubility differences; the α, α?-isomer is readily converted to the α, β-form by heating in the presence of HCl.

Production Methods

Benzaldehyde glycrol acetal can be produced from Benzaldehyde and Glycerin by condensation, using Phosphoric acid as a catalyst, and making use of azeotropic distillation to remove reaction water. Also by heating Glycerol and Benzaldehyde in CO2 atmosphere to 150°C. The 1,3-isomer is crystallizable and may be separated.

FEMA 2129 Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 43)Suppliers
Supplier Tel Email Country ProdList Advantage
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Benzaldehyde,cyclicacetalwith1,2,3-propanetriol BENZAL GLYCERYL ACETAL BENZALDEHYDE GLYCERYL ACETAL FEMA 2129 Benzyl glyceryl acetal 5-Hydroxy-2-phenyl-1,3-dioxan Benzalglycerin Benzaldehyde glycrol acetal 2-PHENYL-1,3-DIOXOLANE-4-METHANOL Benzaldehyde glycerol cyclic acetal BGA* 1319-88-6