4-Chloro-2-methylaniline

4-Chloro-2-methylaniline Properties

Melting point	24-27 °C (lit.)
Boiling point	241 °C (lit.)
Density	1.19 g/mL at 25 °C (lit.)
refractive index	n20/D 1.583(lit.)
Flash point	211 °F
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
Water Solubility	Practically insoluble in water
solubility	Chloroform (Slightly), Methanol (Slightly)
pka	pK1:3.385(+1) (25°C)
color	White or colorless to Brown
BRN	878505
Stability	Air Sensitive
CAS DataBase Reference	95-69-2(CAS DataBase Reference)
EWG's Food Scores	3
FDA UNII	95NB978426
Proposition 65 List	p-Chloro-o-toluidine
IARC	2A (Vol. 77, 99) 2010
NIST Chemistry Reference	Benzenamine, 4-chloro-2-methyl-(95-69-2)
EPA Substance Registry System	4-Chloro-2-methylaniline (95-69-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS06,GHS08,GHS09

Signal word

Danger

Hazard statements

H301+H311+H331-H341-H350-H410

Precautionary statements

P202-P273-P280-P301+P310-P302+P352+P312-P304+P340+P311

Hazard Codes

T,N

Risk Statements

45-23/24/25-50/53-68

Safety Statements

53-45-60-61

RIDADR

UN 2239 6.1/PG 3

WGK Germany

3

RTECS

XU5000000

F

8-10

HazardClass

6.1(b)

PackingGroup

III

HS Code

29214300

NFPA 704

	0
1		0

4-Chloro-2-methylaniline price More Price(29)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	590711	4-Chloro-2-methylaniline 98%	95-69-2	10g	$69.2	2024-03-01	Buy
Sigma-Aldrich	46282	4-Chloro-2-methylaniline analytical standard	95-69-2	250mg	$53.6	2022-05-15	Buy
TCI Chemical	A0704	4-Chloro-2-methylaniline >98.0%(GC)(T)	95-69-2	25g	$28	2024-03-01	Buy
TCI Chemical	A0704	4-Chloro-2-methylaniline >98.0%(GC)(T)	95-69-2	100g	$63	2024-03-01	Buy
TCI Chemical	A0704	4-Chloro-2-methylaniline >98.0%(GC)(T)	95-69-2	500g	$186	2024-03-01	Buy

Product number	Packaging	Price	Buy
590711	10g	$69.2	Buy
46282	250mg	$53.6	Buy
A0704	25g	$28	Buy
A0704	100g	$63	Buy
A0704	500g	$186	Buy

4-Chloro-2-methylaniline Chemical Properties,Uses,Production

Chemical Properties

The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.

Chemical Properties

clear brown liquid

Uses

Intermediate.

Uses

4-Chloro-2-methylaniline may be used in the synthesis of the following:

2,8-dichloro-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f]-diazocine via reaction with paraformaldehyde in toluene
N-allylated derivative via palladium-catalyzed selective monoallylation with allyl alcohol
N-(4-chloro-2-methylphenyl)benzamide via reaction with benzoyl chloride

Definition

ChEBI: 4-Chloro-ortho-toluidine is a member of monochlorobenzenes.

General Description

Gray to white solid with a weak fishy odor. Sinks in water. Freezing point is 77°F.

Air & Water Reactions

May be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

4-Chloro-2-methylaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. . A halogenated amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Hazard

Toxic by ingestion and inhalation. Probable carcinogen.

Health Hazard

Inhalation, ingestion, or skin contact causes bluish tint in fingernails, lips, and ears. Headache, drowsiness, and nausea also occur. Contact with eyes causes irritation.

Fire Hazard

Special Hazards of Combustion Products: Toxic oxides of nitrogen and hydrochloric acid fumes may form.

Safety Profile

Confirmed carcinogen. Poison by ingestion and subcutaneous routes. Human mutation data reported. In the presence of copperpI) chloride catalyst decomposition occurs above 239'C. When heated to decomposition it emits toxic fumes of Cland NOx. See also other chloro toluidme entries.

Potential Exposure

Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations.

Carcinogenicity

p-Chloro-o-toluidine and its hydrochloride salt are reasonably anticipated to be human carcinogens based on limited evidence of carcinogenicity from studies in humans and evidence of carcinogenicity from studies in experimental animals.

Shipping

UN2239 Chlorotoluidines, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3429 Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1- Poisonous materials

Incompatibilities

Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards.

4-Chloro-2-methylaniline synthesis

Synthesis of 4-Chloro-2-methylaniline from o-Toluidine

4-Chloro-2-methylaniline Preparation Products And Raw materials

Raw materials

Glycine o-Toluidine Benzoyl chloride 2-NITROSOTOLUENE 2-Methylphenyl azide

4-CHLORO-2-METHYLPHENYLBORONIC ACID 1-Bromo-4-chloro-2-methylbenzene 2-METHYLACETANILIDE 5-Chloro-2-nitrotoluene 4-Chloro-2-methylaniline

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Preparation Products

4-CHLORO-2-METHYLBENZOIC ACID CHLOROMETHIURON 4-CHLORO-2-METHYLPHENYL ISOTHIOCYANATE 2-Chloro-6-methylaniline CHLORDIMEFORM

4-Chloro-N-methylaniline 5-CHLORO-7-METHYLISATIN Disperse Red 220 4'-Chloro-3-hydroxy-2'-methyl-2-naphthanilide ANTHRA RED B

4-Chloro-2-methylaniline N-(4-Chloro-2-Methylphenyl)-4-fluorobenzaMide, 96%

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4-Chloro-2-methylaniline Suppliers

Global( 315)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5892	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20287	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29791	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32957	60
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28172	58
Shanghai Worldyang Chemical Co.,Ltd.	+86-021-56795779 +8613651600618	sales@worldyachem.com	China	1243	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49374	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29811	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co,.LTD	58
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
Hubei Jusheng Technology Co.,Ltd.	58
Shanghai Worldyang Chemical Co.,Ltd.	58
Chongqing Chemdad Co., Ltd	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58

View Lastest Price from 4-Chloro-2-methylaniline manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-10-11	4-Chloro-2-methylaniline 95-69-2	US $30.00-10.00 / kg	10kg	99%	100000kg	Hebei Chuanghai Biotechnology Co,.LTD
2024-01-02	4-Chloro-2-Methylaniline 95-69-2	US $200.00-1.00 / KG	1KG	99%, 99.5% Sublimated	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2022-02-19	4-Chloro-2-methylaniline 95-69-2	US $0.00 / KG	1KG	97.6%	100 tons	Honest Joy Holdings Limited

4-Chloro-2-methylaniline
95-69-2
US $30.00-10.00 / kg
99%
Hebei Chuanghai Biotechnology Co,.LTD

4-Chloro-2-Methylaniline
95-69-2
US $200.00-1.00 / KG
99%, 99.5% Sublimated
Henan Fengda Chemical Co., Ltd

4-Chloro-2-methylaniline
95-69-2
US $0.00 / KG
97.6%
Honest Joy Holdings Limited

4-Chloro-2-methylaniline Spectrum

4-Chloro-2-methylaniline(95-69-2)MS 4-Chloro-2-methylaniline(95-69-2)¹HNMR 4-Chloro-2-methylaniline(95-69-2)¹³CNMR 4-Chloro-2-methylaniline(95-69-2)IR1 4-Chloro-2-methylaniline(95-69-2)IR2 4-Chloro-2-methylaniline(95-69-2)IR3 4-Chloro-2-methylaniline(95-69-2)IR

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