CERIUM(III) CHLORIDE
- CAS No.
- 7790-86-5
- Chemical Name:
- CERIUM(III) CHLORIDE
- Synonyms
- CeCl3;CERIUM CHLORIDE;cerium chloride anhydrous;Cerium trichloride heptahydrate;Cerium(III) trichloride;Anhydrous Cerium Chloride;CEROUS CHLORIDE;trichloroceriuM;Cerium(III) chL;ceriumtrichloride
- CBNumber:
- CB0120131
- Molecular Formula:
- CeCl3
- Molecular Weight:
- 246.48
- MOL File:
- 7790-86-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/8/4 16:55:17
Melting point | 848 °C(lit.) |
---|---|
Boiling point | 1727 °C |
Density | 3.97 g/mL at 25 °C(lit.) |
Flash point | 1727°C |
storage temp. | Inert atmosphere,Room Temperature |
solubility | soluble in H2O, ethanol |
form | beads |
color | White to Pale Gray |
Specific Gravity | 3.92 |
Water Solubility | Soluble in water, ethanol, acids and acetone. |
Sensitive | Hygroscopic |
Merck | 14,1997 |
Stability | Stable. Hygroscopic. Incompatible with strong acids, strong oxidizing agents. |
InChIKey | VYLVYHXQOHJDJL-UHFFFAOYSA-K |
CAS DataBase Reference | 7790-86-5(CAS DataBase Reference) |
EPA Substance Registry System | Cerium chloride (CeCl3) (7790-86-5) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05,GHS09 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H314-H410 | |||||||||
Precautionary statements | P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36 | |||||||||
RIDADR | UN 3260 8 / PGIII | |||||||||
WGK Germany | 2 | |||||||||
RTECS | FK5075000 | |||||||||
F | 3-10 | |||||||||
TSCA | Yes | |||||||||
HS Code | 28461090 | |||||||||
Toxicity | LD50 in mice, guinea pigs (mg/kg): 352, 110 i.p. (Graca) | |||||||||
NFPA 704 |
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CERIUM(III) CHLORIDE price More Price(18)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 429406 | Cerium(III) chloride AnhydroBeads?, ?10?mesh, ≥99.99% trace metals basis | 7790-86-5 | 5G | ₹13314.75 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 429406 | Cerium(III) chloride AnhydroBeads?, ?10?mesh, ≥99.99% trace metals basis | 7790-86-5 | 25G | ₹33882.25 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 298190 | Cerium(III) chloride AnhydroBeads?, ?10?mesh, 99.9% | 7790-86-5 | 50G | ₹29205.85 | 2022-06-14 | Buy |
ALFA India | ALF-035688-22 | Cerium(III) chloride, ultra dry, 99.9% (REO) | 7790-86-5 | 100g | ₹49094 | 2022-05-26 | Buy |
ALFA India | ALF-035688-14 | Cerium(III) chloride, ultra dry, 99.9% (REO) | 7790-86-5 | 25g | ₹28320 | 2022-05-26 | Buy |
CERIUM(III) CHLORIDE Chemical Properties,Uses,Production
Chemical Properties
Cerium(III) chloride is a white powder and is used for incandescent gas mantles, spectrography and polymerization of olefins.
Cerium(III) chloride is mainly used as catalyst for petroleum,automobile exhaust catalyst , also used as a raw material for the production of cerium metal and other cerium compounds.
Physical properties
White, very fine powder; hexagonal crystal system; heptahydrate is yellow orthogonal crystal and hygroscopic; density of anhydrous salt 3.97 g/cm3; melts at 817°C; vaporizes at 1,727°C; heptahydrate begins to lose water above 90°C and becomes anhydrous at about 230°C; soluble in water and alcohol; hexahydrate has greater solubility in these solvents.
Uses
Cerium(III) chloride is used in incandescent gas mantles, spectrography and polymerization of olefins. It acts as a Lewis acid and used in Friedel-Crafts alkylation and acylation reactions in organic synthesis. It is used as a precursor for the preparation of other cerium salts, such as cerium(III) trifluoromethanesulfonate.
Production Methods
Cerium(III) chloride is prepared by the reaction of hydrochloric acid with a cerium salt, such as cerium hydroxide or carbonate, followed by crystallization;
Ce(OH)3 + 3HCl → CeCl3 + 3H2O
Ce2(CO3)3 + 6HCl → 2CeCl3 + 3CO2 + 3H2O.
Safety Profile
Poison by intravenous, intraperitoneal, and subcutaneous routes. Moderately toxic by ingestion. See also CERIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of Cl-
CERIUM(III) CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
Vardhaman P Golechha | 9704422000 | Telangana, India | 294 | 58 | Inquiry |
JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
ALS INDIA LIFE SCIENCES | +91-8977036379 +91-8977036379 | Hyderabad, India | 1879 | 58 | Inquiry |
Star Earth Minerals Pvt Ltd | +91-9594153555 +91-9594775679 | Maharashtra, India | 45 | 58 | Inquiry |
Survival Technologies Pvt Ltd | +91 (22) 4212-8221 | New Delhi, India | 290 | 50 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
Supplier | Advantage |
---|---|
Vardhaman P Golechha | 58 |
JSK Chemicals | 58 |
ALS INDIA LIFE SCIENCES | 58 |
Star Earth Minerals Pvt Ltd | 58 |
Survival Technologies Pvt Ltd | 50 |
CLEARSYNTH LABS LTD. | 58 |
TCI Chemicals (India) Pvt. Ltd. | 58 |
Otto Chemie Pvt. Ltd. | 58 |
Alfa Aesar | 58 |
A.J Chemicals | 58 |
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