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FLUOROLUBE GREASE, GR-362

FLUOROLUBE GREASE, GR-362 Structure
CAS No.
9002-83-9
Chemical Name:
FLUOROLUBE GREASE, GR-362
Synonyms
PCTFE;12f;HALOCARBON OIL;11f;4lf;f3m;12fd;13fm;tl340;PTFCE
CBNumber:
CB0174598
Molecular Formula:
C2ClF3
Molecular Weight:
116.4696096
MOL File:
9002-83-9.mol
Modify Date:
2023/5/25 18:00:55

FLUOROLUBE GREASE, GR-362 Properties

Melting point 210-212 °C
Boiling point 140-190 °C(Press: 1 Torr)
Density 1 g/mL at 25 °C
storage temp. Hygroscopic, Refrigerator, under inert atmosphere
solubility Acetone (Slightly), Chloroform (Slightly)
form powder
color Clear Colourless
LogP 1.419 (est)
CAS DataBase Reference 9002-83-9
EPA Substance Registry System Ethene, chlorotrifluoro-, homopolymer (9002-83-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P271-P261-P280
Hazard Codes  Xi
WGK Germany  3
RTECS  MG7104000
HS Code  3904698081
Toxicity LD50 oral in rat: > 9200mg/kg
NFPA 704
0
1 0

FLUOROLUBE GREASE, GR-362 price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) H8898 Halocarbon oil 700 9002-83-9 50ML ₹10789.2 2022-06-14 Buy
Sigma-Aldrich(India) H8898 Halocarbon oil 700 9002-83-9 100ML ₹19247.4 2022-06-14 Buy
Sigma-Aldrich(India) H8773 Halocarbon oil 27 9002-83-9 100ML ₹19247.4 2022-06-14 Buy
Sigma-Aldrich(India) 454710 Poly(chlorotrifluoroethylene) powder 9002-83-9 25G ₹3629.7 2022-06-14 Buy
Product number Packaging Price Buy
H8898 50ML ₹10789.2 Buy
H8898 100ML ₹19247.4 Buy
H8773 100ML ₹19247.4 Buy
454710 25G ₹3629.7 Buy

FLUOROLUBE GREASE, GR-362 Chemical Properties,Uses,Production

Chemical Properties

Polychlorotrifluoroethylene (PCTFE) is more expensive than poly tetrafluoroethylene and its use is comparatively limited. The preferred commercial method of preparation of polychlorotrifluoroethylene is by suspension polymerization using procedures similar to those used for polytetrafluoroethylene. In order to obtain polymer of high molecular weight, reaction temperatures are generally kept in the range 0-40°C. Initiation is commonly by means of a redox system activated by a metal salt, e.g. persulphate - bisulphite with a ferrous salt. Average molecular weights of commercial polymers are within the range 50000-500000. Polychlorotrifluoroethylene is a white solid. Compared to poly tetrafluoroethylene, it has greater tensile strength, hardness and resistance to creep. The presence of a chlorine atom, which is larger than a fluorine atom, in the polymer does not permit such close chain packing as is possible with polytetrafluoroethylene. Thus polychlorotrifluoroethylene has a lower softening point and can be processed in the melt. Because of the lower tendency to crystallize, it is possible to produce thin transparent films by rapid quenching. The presence of chlorine in the polymer results in greater interchain attraction and accounts for the better mechanical strength of polychlorotrifluoroethylene. On the other hand, the unsymmetrical structure leads to poorer electrical insulation properties.
The chemical resistance of polychlorotrifluoroethylene is very good but not as good as that of polytetrafluoroethylene. Molten alkali metals and molten caustic alkalis attack the polymer and a few halogenated solvents swell or dissolve the polymer at elevated temperatures. Polychlorotrifluoroethylene may be melt processed. Standard techniques of extrusion and injection moulding may be used but careful temperature control is required since degradation occurs at processing temperatures, which are normally in the range 230-290°C. Degradation is accompanied by development of unsaturation and may involve the following chain splitting rearrangement:
Reaction of Fluorolube grease, gr-362
The temperature range of useful performance is from about -loooe to 200°C.
Polychlorotrifluorethylene finds limited use for such items as diaphragms, gaskets, electrical components and transparent windows for chemical equipment. Dispersions are used for the preparation of films and coatings.

Uses

Valves, seals, packaging films, electroluminescent display panels, bearings where high wear is a problem.

Production Methods

PCTFE is a polymer of chlorotrifluoroethylene. It is prepared by free-radical polymerization in an aqueous emulsion using organic or water-soluble initiators or ionizing radiation. Examples of applications of PCTFE are plastic molded parts in chemical process equipment and electric parts.

General Description

Halocarbon oil 27 is?a polymer of chlorotrifluoroethylene (CTFE). It is used to lubricate pumps in hyperbaric chambers.

Industrial uses

The properties of FLUOROLUBE GREASE, GR-362 are generally similar tothose for polytetrafluoroethylene; however, thepresence of the chlorine atoms in the formercauses the polymer to be a little less resistant toheat and to chemicals. The polymonochlorotrifluoroethylenecan be shaped by use of conventionalmolding and extrusion equipment, and itis obtained in a transparent, noncrystalline conditionby quenching. Dispersions of the polymerin organic media may be used for coating.
The applications of FLUOROLUBE GREASE, GR-362 in general similar to those for polytetrafluoroethylene.Because of its stability andinertness, the polymer is useful in the manufactureof gaskets, linings, and valve seats thatmust withstand hot and corrosive conditions. Itis also used as a dielectric material, as a vaporand liquid barrier, and for microporous filters.

FLUOROLUBE GREASE, GR-362 Preparation Products And Raw materials

Raw materials

Preparation Products

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