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4,4'-Methylenebis(2,6-di-tert-butylphenol)

CAS No.: 118-82-1

Chemical Name:: 4,4'-Methylenebis(2,6-di-tert-butylphenol)

Synonyms: e702;E 702;l3mb1;bimoxm;binoxm;L 3MB1;lz-mb1;binox-m;Binox M;Bimox M

CBNumber:: CB0206363

Molecular Formula:: C29H44O2

Molecular Weight:: 424.66

MOL File:: 118-82-1.mol

MSDS File:: SDS

Modify Date:: 2024/8/19 17:35:41

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4,4'-Methylenebis(2,6-di-tert-butylphenol) Properties

Melting point	155-159 °C(lit.)
Boiling point	289 °C40 mm Hg(lit.)
Density	0.99 g/cm3 (20℃)
vapor pressure	0Pa at 25℃
refractive index	1.4875 (estimate)
Flash point	289°C/40mm
storage temp.	Store below +30°C.
solubility	<0.0001g/l
pka	12.03±0.40(Predicted)
form	solid
color	White
Water Solubility	31.9ng/L at 20℃
BRN	1916919
Stability	Stable for 2 years from date of purchase as supplied. Solutions are not stable. Solutions must be made fresh and used within 1 working day.
InChIKey	MDWVSAYEQPLWMX-UHFFFAOYSA-N
LogP	8.9 at 25℃
CAS DataBase Reference	118-82-1(CAS DataBase Reference)
NIST Chemistry Reference	Phenol, 4,4'-methylenebis[2,6-bis(1,1-dimethylethyl)-(118-82-1)
EPA Substance Registry System	Phenol, 4,4'-methylenebis[2,6-bis(1,1-dimethylethyl)- (118-82-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38-38-37-36

Safety Statements

26-36

WGK Germany

RTECS

SL9650000

TSCA

Yes

HS Code

29072990

Toxicity

LD50 oral in rat: > 24gm/kg

NFPA 704

	1
1		0

4,4'-Methylenebis(2,6-di-tert-butylphenol) price More Price(4)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	8.42857	4,4′-Methylenebis(2,6-di-tert-butylphenol) for synthesis	118-82-1	10G	₹2040	2022-06-14	Buy
Sigma-Aldrich(India)	8.42857	4,4′-Methylenebis(2,6-di-tert-butylphenol) for synthesis	118-82-1	100G	₹3080.01	2022-06-14	Buy
TCI Chemicals (India)	M0214	4,4'-Methylenebis(2,6-di-tert-butylphenol) min. 98.0 %	118-82-1	25G	₹1800	2022-05-26	Buy
TCI Chemicals (India)	M0214	4,4'-Methylenebis(2,6-di-tert-butylphenol) min. 98.0 %	118-82-1	500G	₹5200	2022-05-26	Buy

Product number	Packaging	Price	Buy
8.42857	10G	₹2040	Buy
8.42857	100G	₹3080.01	Buy
M0214	25G	₹1800	Buy
M0214	500G	₹5200	Buy

4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical Properties,Uses,Production

Chemical Properties

light yellow crystalline

Uses

Antioxidant.

Application

4,4'-Methylenebis(2,6-di-tert-butylphenol), also known as H2-4DBP, could be used as a ligand to react with sets of M(OR)x and MRx. The ligand possesses more flexibility than OBzP or catecholate derivatives, and the para-OH makes it of interest for controlled alcoholysis. This compound has several characteristics, including (i) the ortho position possesses the sterically hindering t-butyl group which will assist in minimizing oligomerization, (ii) the para linkage prevents chelation of the 4DBP ligand to the metal upon coordination, and (iii) may act as a valuable model for complexation behavior of the plastic precursor bisphenol-A [BPA; 4,4' -(propane-2,2-diyl)diphenol] that has become of recent concern[2].

References

1) Amorati et al. (2003), Antioxidant activity of 0-bisphenols: the role of intramolecular hydrogen bonding; J. Org. Chem. 68 5198.
[2] T. Boyle, Daniel T Yonemoto, L. Steele. “Synthesis and characterization of 4,4′-methylenebis (2,6-di-tert-butylphenol) derivatives of a series of metal alkoxides and alkyls.” Journal of Coordination Chemistry 65.1(2012): 487–505.

4,4'-Methylenebis(2,6-di-tert-butylphenol) Preparation Products And Raw materials

Raw materials

2,6-Di-tert-butylphenol 3,5-DI-TERT-BUTYL-4-HYDROXYBENZYL ETHER 3,5-di-tert-butyl-4-hydroxybenzyl acetate 3,5-Di-tert-butyl-4-hydroxybenzyl alcohol 4,4'-[2,4,6-Trimethyl-1,3-phenylenebis(methylene)]bis[2,6-di(tert-butyl)phenol]

Antioxidant 1330 2,6-Di-tert-butyl-4-(dimethylaminomethyl)phenol Mesitylene Formaldehyde

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Preparation Products

3,5-di-tert-butyl-4-hydroxybenzyl acetate 4,4'-Ethylenebis(2,6-ditert-butylphenol)

4,4'-Methylenebis(2,6-di-tert-butylphenol) Suppliers

Global( 240)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
CHEMSWORTH	+91-261-2397244	New Delhi, India	6707	30	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
NANJING PASTEUR ChEMICAL CO.,LTD	+86-18066069912 +86-18066069912	China	18	58	Inquiry
Qingdao Scienoc Chemical CO Ltd	+86-0532-68076095 +8618661673503	China	113	58	Inquiry
Hebei Mojin Biotechnology Co., Ltd	+86 13288715578 +8613288715578	China	12558	58	Inquiry
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	China	20290	58	Inquiry
Hebei Zhuanglai Chemical Trading Co.,Ltd	+8613343047651	China	3002	58	Inquiry
Hebei Shengyang Water Conservancy Engineering Co., Ltd.	+8615373025980	China	874	58	Inquiry
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	China	21663	55	Inquiry
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	China	9262	55	Inquiry

Supplier	Advantage
CHEMSWORTH	30
TCI Chemicals (India) Pvt. Ltd.	58
NANJING PASTEUR ChEMICAL CO.,LTD	58
Qingdao Scienoc Chemical CO Ltd	58
Hebei Mojin Biotechnology Co., Ltd	58
Henan Fengda Chemical Co., Ltd	58
Hebei Zhuanglai Chemical Trading Co.,Ltd	58
Hebei Shengyang Water Conservancy Engineering Co., Ltd.	58
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55

4,4'-Methylenebis(2,6-di-tert-butylphenol) Spectrum

4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)MS 4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)¹HNMR 4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)¹³CNMR 4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)IR1 4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)IR2 4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)ESR

118-82-1(4,4'-Methylenebis(2,6-di-tert-butylphenol))Related Search:

Butyl acetate Antioxidant 1098 3-tert-Butylphenol 4-tert-Butylphenol tert-Butanol

p-Cresol tert-Butyl peroxyacetate Butyl acrylate Antioxidant 1010 2-sec-Butylphenol

2,4-Di-tert-butylphenol 4-Butylphenol 4,4'-Thiobis(6-tert-butyl-m-cresol) Antioxidant 1520 2,6-Di-tert-butylphenol

2,2'-Methylenebis(4-methyl-6-tert-butylphenol) tert-Butyldimethylsilyl chloride Butylated Hydroxytoluene

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antioxidante702 Bimox M bimoxm Binox M binoxm binox-m bis(4-Hydroxy-3,5-ditertbutyl)phenylmathane Di(4-hydroxy-3,5-di-tert-butylphenyl)methane E 702 e702 mb1(antioxidant) nsc30551 Phenol, 4,4'-methylenebis*2,6-bis(1,1-dimethylethyl)- Phenol, 4,4'-methylenebis*2,6-di-tert-butyl- Phenol, 4,4'-methylenebis[2,6-di-tert-butyl- Antioxidant 702 BIS(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)METHANE GALVINOXYL PRECURSOR IONOX(R) 220 IONOX(R) 220 AH ETHANOX(R) 702 ANTIOXIDANT 4,4'-DIHYDROXY-3,3',5,5'-TETRA-TERT-BUTYLDIPHENYLMETHANE 4,4'-METHYLENEBIS(2,6-DI-TERT-BUTYLPHENOL) 3,3',5,5'-TETRA-TERT-BUTYL-4,4'-DIHYDROXYDIPHENYLMETHANE 4,4´ -Methylenebis(2,6-di-tert-butylphenol) 4,4'-Methylenebis(2,6-di-tert-butylphenol) TIMTEC-BB SBB007948 RARECHEM AQ BD 0024 RALOX(R) 02 S Antioxidant 728 Tetra-tert-butylbisphenol F 2,6-ditert-butyl-4-(3,5-ditert-butyl-4-hydroxy-benzyl)phenol 2,6-ditert-butyl-4-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]phenol 2,6-ditert-butyl-4-[(3,5-ditert-butyl-4-hydroxy-phenyl)methyl]phenol 4.4'-Methylene bis-(2.6-di-tert-butylphenol) 3g [118-82-1] 4,4zzhlxy-Methylenebis(2,6-di-tert-butylphenol) 4,4-METHYLENEBIS(2,6-DITERTIARYBUTYLPHENOL) 4, 4'-Methylen-bis(2,6-di-tert.-butylphenol) 4,4''-DIHYDROXY-3,3,5,5''-TETRA-TERT-BUTYLDIPHENYLMETHANE 98+% 2,2’,6,6’-tetra-tert-butyl-4,4’-methylenediphenol 4,4’-methylenebis(2,6-bis(1,1-dimethylethyl)-pheno 4,4’-methylenebis(2,6-bis(1,1-dimethylethyl)phenol) 4,4’-methylenebis(2,6-di-t-butylphenol) 4,4’-methylenebis(2,6-di-tert-butyl-pheno 4,4’-methylenebis[2,6-bis(1,1-dimethylethyl)-pheno 4,4’-methylenebis[2,6-bis(1,1-dimethylethyl)-Phenol Ethyl 702 ethyl702 Etil 702 etil702 Ionox 220 Ionox 220 Antioxidant ionox220 ionox220antioxidant L 3MB1 l3mb1 LZ-MB 1