DIETHOXYPHOSPHINYL ISOCYANATE
![DIETHOXYPHOSPHINYL ISOCYANATE Structure](CAS/GIF/20039-33-2.gif)
- CAS No.
- 20039-33-2
- Chemical Name:
- DIETHOXYPHOSPHINYL ISOCYANATE
- Synonyms
- DIETHYL ISOCYANATOPHOSPHATE;diethoxyphosphorylisocyanate;Diethyl isocyanatidophosphate;DIETHOXYPHOSPHINYL ISOCYANATE;DIETHYL PHOSPHORISOCYANATIDATE;diethoxyphosphorylimino-keto-methane;phosphorisocyanatidicacid,diethylester;1-(ethoxy-isocyanatophosphoryl)oxyethane;1-(ethoxy-isocyanato-phosphoryl)oxyethane
- CBNumber:
- CB0294508
- Molecular Formula:
- C5H10NO4P
- Molecular Weight:
- 179.11
- MOL File:
- 20039-33-2.mol
- Modify Date:
- 2023/4/23 13:52:06
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS02,GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H226-H312-H315-H319-H332-H335 |
Precautionary statements | P261-P280-P305+P351+P338 |
Hazard Codes | Xn |
Risk Statements | 10-20/21/22-36/37/38 |
Safety Statements | 16-23-26-28-36/37/39 |
RIDADR | UN 3080 6.1/PG 2 |
WGK Germany | 3 |
RTECS | TD1250000 |
HazardClass | 3.2 |
PackingGroup | III |
HS Code | 2931499090 |
Toxicity | mouse,LD50,oral,4080mg/kg (4080mg/kg),Ecotoxicology and Environmental Safety. Vol. 17, Pg. 258, 1989. |
DIETHOXYPHOSPHINYL ISOCYANATE Chemical Properties,Uses,Production
Uses
Diethoxyphosphinyl Isocyanate is an intermediate for organic synthesis. Diethoxyphosphinyl Isocyanate is toxic, cytogenetic and embryotoxic to different mice strains.
Preparation
A solution of diethyl phosphoramidate (30.6 g, 0.2 mol) in tetrachloromethane (50 mL) was slowly added dropwise with stirring and efficient external cooling to a solution of oxalyl chloride (27.9 g, 0.22 mol) in the same solvent (150 mL). The reaction temperature was kept at -5 to 0 °C. After completion of the addition, the temperature of the mixture was slowly increased to 50 °C and this was maintained for 1 h. The mixture was then cooled to room temperature, filtered, and concentrated in vacuo. The residual liquid product was distilled in vacuo (bp 85–87 °C/10 Torr); yield 22.9 g (64%).
General Description
Diethoxyphosphinyl isocyanate is an isocyanate derivative. It has been investigated for its performance as film forming electrolyte additive in propylene carbonate (PC) and EC/EMC-based electrolytes.
DIETHOXYPHOSPHINYL ISOCYANATE Preparation Products And Raw materials
Raw materials
Preparation Products
DIETHOXYPHOSPHINYL ISOCYANATE Suppliers
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
Atomax Chemicals Co., Ltd | 0755- 33239182 | China | 6498 | 43 | Inquiry |
Ryan Scientific, Inc. | 843-884-4911 x 319 | United States | 6446 | 60 | Inquiry |
SIGMA-RBI | 800 736 3690 (Orders) | Switzerland | 6913 | 91 | Inquiry |
Energy Chemical | 021-021-58432009 400-005-6266 | China | 44700 | 61 | Inquiry |
Matrix Scientific | 803 788-9494 All other calls | United States | 6655 | 80 | Inquiry |
Apollo Scientific Ltd. | 44 161 406 0505 | United Kingdom | 6097 | 88 | Inquiry |
Riedel-de Haen AG | 800 558-9160 | United States | 6825 | 87 | Inquiry |
Carbosynth | +86 512 6260 5585 | United Kingdom | 6018 | 58 | Inquiry |
Sigma-Aldrich | 021-61415566 800-8193336 | China | 51471 | 80 | Inquiry |
Shanghai Xingui Biotechnology Co., Ltd. | 17501653715 | China | 10014 | 58 | Inquiry |
Supplier | Advantage |
---|---|
Atomax Chemicals Co., Ltd | 43 |
Ryan Scientific, Inc. | 60 |
SIGMA-RBI | 91 |
Energy Chemical | 61 |
Matrix Scientific | 80 |
Apollo Scientific Ltd. | 88 |
Riedel-de Haen AG | 87 |
Carbosynth | 58 |
Sigma-Aldrich | 80 |
Shanghai Xingui Biotechnology Co., Ltd. | 58 |