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Poly(ethyl vinyl ether)

Poly(ethyl vinyl ether)  Structure
CAS No.
25104-37-4
Chemical Name:
Poly(ethyl vinyl ether)
Synonyms
POLY(VINYL ETHYL ETHER);ebdc;Vinyl Ethyl Ether Resin (Low M.Wt.);edbc;ehbc;ehb-m;lutonala25;lutonala50;luthonala20;bakeliteehbm
CBNumber:
CB0365101
Molecular Formula:
C4H8O
Molecular Weight:
72.11
MOL File:
25104-37-4.mol
MSDS File:
SDS
Modify Date:
2024/7/2 17:04:22

Poly(ethyl vinyl ether) Properties

Density 0.968 g/mL at 25 °C (lit.)
Tg -60
vapor pressure 22.5 mm Hg ( 20 °C)
refractive index n20/D 1.454(lit.)
Flash point 140
form Viscous liquid
InChI InChI=1S/C4H8O/c1-3-5-4-2/h3H,1,4H2,2H3
InChIKey FJKIXWOMBXYWOQ-UHFFFAOYSA-N
SMILES O(C=C)CC
CAS DataBase Reference 25104-37-4
EPA Substance Registry System Poly(vinyl ethyl ether) (25104-37-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02
Signal word  Warning
Hazard statements  H226
Safety Statements  24/25
WGK Germany  3
RTECS  CQ6693000
Autoignition Temperature 446 °F
TSCA  TSCA listed
Toxicity LD50 intraperitoneal in mouse: 2590mg/kg
NFPA 704
0
0 0

Poly(ethyl vinyl ether) price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 182656 Poly(ethyl vinyl ether) average Mw ~3,800 by GPC 25104-37-4 100G ₹11496.15 2022-06-14 Buy
Product number Packaging Price Buy
182656 100G ₹11496.15 Buy

Poly(ethyl vinyl ether) Chemical Properties,Uses,Production

Chemical Properties

Poly(ethyl vinyl ether) is a opaque amber viscous liquid, It is a hydrophobic material that is insoluble in water or other polar solvents.

Uses

Poly(ethyl vinyl ether) can used as a plasticiser for cellulose nitrate and cellulose resin lacquers, as a base for pressure-sensitive adhesives in films and tapes, especially in surgical applications. Also used for non-irritating surgical casts requiring moisture permeability and to impart dry-film flexibility and increased viscosity of photochemical resist-coating compositions.

Preparation

To a flask containing 200 gm of benzene is added 1.0 gm of aluminum chloride. The mixture is stirred vigorously to suspend the catalyst and then the gradual addition of 200 gm (2.78 moles) of vinyl ether is begun. The reaction is exothermic, and when the temperature rises to 60°-80°C the addition is slowed so that only 1-2 gm of vinyl ethyl ether is added at one time. Polymerization is detected by the onset of turbidity and a slight brown color. When the brown color disappears, the next increment of vinyl ethyl ether is added. After the complete addition the reaction mixture is heated to 80°C. The benzene and volatiles are steam-distilled off, and the residue amounts to about 144 gm (72%) of a yellow balsamlike product.
25104-37-4 synthesis
Preparation of Poly(vinyl ethyl ether) Using Aluminum Chloride Catalyst

Hazard

Moderately toxic.

Safety Profile

Moderately toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors.

Poly(ethyl vinyl ether) Preparation Products And Raw materials

Raw materials

Preparation Products

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Poly(ethyl vinyl ether) Spectrum

VinylethylethereesinHighMWt Poly(vinyl ethyl ether), low molecular weight 5-ethyl-5-(6-oxo-1-cyclohexen-1-yl)-barbituric acid POLY(ETHYL VINYL ETHER) VINYL ETHYL ETHER RESIN 5-(3or6-oxo-1-cyclohexen-1-yl)-5-ethylbarbituricacid 5-ethyl-5-(3or6-oxo-1-cyclohexen-1-yl)-barbituricaci 5-ethyl-5-(3or6-oxo-1-cyclohexen-1-yl)barbituricacid bakeliteehbc bakeliteehbm edbc ehbc ehb-m Poly(ethyl vinyl ether) average Mw ~3,800 by GPC Poly(vinyl ethyleether) Ethene,ethoxy-,homopolymer ether,ethylvinyl,polymers ethoxy-ethenhomopolymer ethoxy-ethenpolymers ethylvinyletherhomopolymer ethylvinyletherpolymer luthonala20 lutonala25 lutonala50 vinylethyletherhomopolymer vinylethyletherpolymer POLY(VINYL ETHYL ETHER) ISO 9001:2015 REACH Vinyl Ethyl Ether Resin (Low M.Wt.) POLY(VINYL ETHYL ETHER) ebdc Poly(vinyl ethyl ether),Approx Mw 120,000 [GPC Polyethylene based ether Poly(ethyl vinyl ether) (LUT-A25) Poly(ethyl vinyl ether) 50% in ethanol (LUT-A5050E) 25104-37-4 -CH2CHOC2H5n C4H8Ox Vinyl Ethers and Ketones Hydrophobic Polymers Materials Science Polymer Science Polymers Hydrophobic Polymers Polymer Science Vinyl Ethers and Ketones