2-Amino-3,6,8-naphthalenetrisulfonic acid
- CAS No.
- 118-03-6
- Chemical Name:
- 2-Amino-3,6,8-naphthalenetrisulfonic acid
- Synonyms
- K-ACID;AMINO K ACID;2-R amino acid;kyselinakochova;2-NAPHTHYLAMINE-3,6,8-TRISULFONIC ACID;6-naphthalenetrisulfonicacid,7-amino-3;7-Amino-1,3,6-naphthalenesulfonic Acid;kyselina2-naftylamin-3,6,8-trisulfonova;2-NAPTHYLAMINE-3,6,8 TRI SULPHONIC ACID;7-aminonaphthalene-1,3,6-trisulfonicaci
- CBNumber:
- CB1148862
- Molecular Formula:
- C10H9NO9S3
- Molecular Weight:
- 383.37
- MOL File:
- 118-03-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/11/6 14:04:18
Boiling point | 702.53℃[at 101 325 Pa] |
---|---|
Density | 1.7995 (rough estimate) |
refractive index | 1.6800 (estimate) |
storage temp. | 2-8°C |
pka | -1.27±0.40(Predicted) |
Water Solubility | 1000g/L at 25℃ |
LogP | -11.96 |
CAS DataBase Reference | 118-03-6(CAS DataBase Reference) |
EPA Substance Registry System | 1,3,6-Naphthalenetrisulfonic acid, 7-amino- (118-03-6) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H302-H315-H319-H335 |
Precautionary statements | P261-P305+P351+P338 |
Toxicity | rat,LD50,oral,13gm/kg (13000mg/kg),"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1058, 1986. |
2-Amino-3,6,8-naphthalenetrisulfonic acid Chemical Properties,Uses,Production
Chemical Properties
2-Aminonaphthalene-3,6,8-trisulfonic acid [118-03-6]. (7-aminonaphthalene-1,3,6- trisulfonic acid), C10H9NO9S3, Mr 383.36, and its disodium salts are soluble in water, but the dipotassium salt is much less soluble. Reduction with zinc dust and alkali results in 2-aminonaphthalene-3,6-disulfonic acid, and caustic fusion at 240℃ gives 2-amino-8-hydroxynaphthalene-3,6-disulfonic acid.
Production Methods
2-Aminonaphthalene-6,8-disulfonic acid is sulfonated with 65 % oleum at 125℃ for 12 h in the presence of anhydrous sodium sulfate. After quenching and liming out, the hot solution of calcium salt is basified with sodium carbonate and the resulting solution of the trisodium salt is used directly for caustic fusion to give 2-amino-8-hydroxynaphthalene-3,6-disulfonic acid.
2-Amino-3,6,8-naphthalenetrisulfonic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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