ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Silane >3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Structure
CAS No.
38002-45-8
Chemical Name:
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
Synonyms
(3-BroMoprop-1-yn-1-yl)triMethylsilane;)-1-propyne;(3-Bromo-1-pr;3-Bromo-1-(trimethyL;(3-BROMO-1-PROPYNYL)TRIMETHYLSILANE;3-(TRIMETHYLSILYL)PROPARGYL BROMIDE;3-(trimethylsilyl)-propagyl bromide;3-bromoprop-1-ynyl(trimethyl)silane;3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE;3-Bromo-1-(trimethulsilyl)-1-propyne
CBNumber:
CB1151699
Molecular Formula:
C6H11BrSi
Molecular Weight:
191.14
MOL File:
38002-45-8.mol
MSDS File:
SDS
Modify Date:
2024/6/12 17:09:27

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Properties

Melting point <0°C
Boiling point 44-45 °C2 mm Hg(lit.)
Density 1.17 g/mL at 25 °C(lit.)
refractive index n20/D 1.483(lit.)
Flash point 145 °F
storage temp. 2-8°C
solubility Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
form Oil
color Colourless to Pale Yellow
Specific Gravity 1.351
Water Solubility Immiscible with water.
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN 2037650
Stability Hygroscopic
InChIKey GAPRPFRDVCCCHR-UHFFFAOYSA-N
CAS DataBase Reference 38002-45-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-28-36/37/39
RIDADR  UN 3334
WGK Germany  3
8-9-19
TSCA  No
HS Code  29319090
NFPA 704
2
2 1

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 377775 3-Bromo-1-(trimethylsilyl)-1-propyne 98% 38002-45-8 1G ₹4308.35 2022-06-14 Buy
Sigma-Aldrich(India) 377775 3-Bromo-1-(trimethylsilyl)-1-propyne 98% 38002-45-8 10G ₹22570.13 2022-06-14 Buy
TCI Chemicals (India) B1654 3-Bromo-1-(trimethylsilyl)-1-propyne min. 97.0 % 38002-45-8 1G ₹3400 2022-05-26 Buy
ALFA India ALF-H53451-14 3-Bromo-1-trimethylsilyl-1-propyne, 98% 38002-45-8 25g ₹19477 2022-05-26 Buy
TCI Chemicals (India) B1654 3-Bromo-1-(trimethylsilyl)-1-propyne min. 97.0 % 38002-45-8 5G ₹6400 2022-05-26 Buy
Product number Packaging Price Buy
377775 1G ₹4308.35 Buy
377775 10G ₹22570.13 Buy
B1654 1G ₹3400 Buy
ALF-H53451-14 25g ₹19477 Buy
B1654 5G ₹6400 Buy

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Chemical Properties,Uses,Production

Chemical Properties

Clear colorless to pale yellow liquid

Uses

3-Bromo-1-(trimethylsilyl)-1-propyne may be used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It may be used as reagent for the alkylation of dianion of β-keto esters at γ-carbon. It may be employed in the preparation of terminal conjugated enynes and allenic alcohols.

General Description

3-Bromo-1-(trimethylsilyl)-1-propyne is reported as a propargylating agent. Selective reaction of 3-bromo-1-(trimethylsilyl)-1-propyne with α-keto ester using indium metal has been studied.

Global( 202)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
Reax Chemicals 08048372701Ext 416 Hyderabad, India 4223 58 Inquiry
Hebei Mojin Biotechnology Co., Ltd +86 13288715578 +8613288715578 China 12446 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 18632 58 Inquiry
Hangzhou FandaChem Co.,Ltd. 008657128800458; +8615858145714 China 9355 55 Inquiry
ATK CHEMICAL COMPANY LIMITED +undefined-21-51877795 China 32836 60 Inquiry
Accela ChemBio Inc. +1-858-6993322 United States 19479 58 Inquiry
3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE 98% 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE, 98 % 3-(TRIMETHYLSILYL)PROPARGYL BROMIDE 97+% 3-(Trimethylsilyl)propargyl bromide, 3-Bromo-1-(trimethylsilyl)-1-propyne (3-BROMO-1-PROPYNYL)TRIMETHYLSILANE 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE (3-Bromo-1-propyn-1-yl)trimethyl-silane 3-(TRIMETHYLSILYL)PROPARGYL BROMIDE 3-Bromo-1-(trimethyL 3-Bromo-1-(trimethylsilyl)-1-propyne > Silane, (3-bromo-1-propyn-1-yl)trimethyl- )-1-propyne (3-Bromo-1-pr 3-bromo-1-trimethylsilyl-1-propargyne 3-Bromo-1-(trimethulsilyl)-1-propyne 3-(trimethylsilyl)-propagyl bromide 3-bromoprop-1-ynyl(trimethyl)silane silane, (3-bromo-1-propynyl)trimethyl- 3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE, 97%3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE, 97%3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE, 97% (3-BroMoprop-1-yn-1-yl)triMethylsilane 3-Bromo-1-(Trimethylsilyl)-1-Propyne,95% 38002-45-8 BrCH2CCSiCH33 C6H11BrSi BrCH2C8801CSiCH33 Building Blocks Alkynes Organic Building Blocks Internal Acetylenes Si-(C)4 Compounds Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Functionalized Acetylenes Ethynylsilanes Acetylenes Ethynylsilanes Functionalized Acetylenes Si (Classes of Silicon Compounds) Si-(C)4 Compounds Silicon Compounds (for Synthesis) Synthetic Organic Chemistry