PHENYLSELENYL BROMIDE

- CAS No.
- 34837-55-3
- Chemical Name:
- PHENYLSELENYL BROMIDE
- Synonyms
- bromoselenobenzene;Phenylbromoselenium;Phenylbromo selenide;Phenylseleno bromide;PHENYLSELENYL BROMIDE;BENZENESELENYL BROMIDE;Phenylselenium bromide;PHENYLSELENENYL BROMIDE;phenylselenohypobromite;BENZENESELENENYL BROMIDE
- CBNumber:
- CB1360840
- Molecular Formula:
- C6H5BrSe
- Molecular Weight:
- 235.97
- MOL File:
- 34837-55-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/1/27 9:38:02
Melting point | 58-62 °C (lit.) |
---|---|
Boiling point | 107-108 °C/15 mmHg (lit.) |
Flash point | 107-108°C/15mm |
storage temp. | 2-8°C |
solubility | Soluble in toluene, very faint turbidity. |
form | solid |
color | Orange to Brown to Dark purple |
Odor | unpleasant smell. |
Sensitive | Moisture Sensitive |
BRN | 2039772 |
Exposure limits |
ACGIH: TWA 0.2 mg/m3 NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3 |
InChIKey | LCEFEIBEOBPPSJ-UHFFFAOYSA-N |
CAS DataBase Reference | 34837-55-3(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() ![]() GHS05,GHS06,GHS08,GHS09 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H290-H301+H331-H373-H410 | |||||||||
Precautionary statements | P234-P260-P273-P301+P310-P304+P340+P311-P314 | |||||||||
Hazard Codes | T,N | |||||||||
Risk Statements | 23/25-33-50/53 | |||||||||
Safety Statements | 20/21-28-45-60-61 | |||||||||
RIDADR | UN 2928 6.1/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 10-21 | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29319090 | |||||||||
NFPA 704 |
|
PHENYLSELENYL BROMIDE price More Price(9)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 243965 | Phenylselenyl bromide 98% | 34837-55-3 | 5G | ₹4427.43 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 243965 | Phenylselenyl bromide 98% | 34837-55-3 | 25G | ₹24908.33 | 2022-06-14 | Buy |
ALFA India | ALF-A11906-14 | Phenylselenenyl bromide, 98% | 34837-55-3 | 25g | ₹19753 | 2022-05-26 | Buy |
ALFA India | ALF-A11906-06 | Phenylselenenyl bromide, 98% | 34837-55-3 | 5g | ₹4351 | 2022-05-26 | Buy |
ALFA India | ALF-A11906-03 | Phenylselenenyl bromide, 98% | 34837-55-3 | 1g | ₹1297 | 2022-05-26 | Buy |
PHENYLSELENYL BROMIDE Chemical Properties,Uses,Production
Chemical Properties
dark brownish to black crystals
Uses
Employed in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide. Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione.
Synthesis
Phenylselenyl Bromide can be quantitatively prepared in situ by treatment of Diphenyl Diselenide with an equimolar amount of Bromine.
Purification Methods
Distil it in a vacuum, recrystallise it from pet ether, CHCl3 (EtOH free), or Et2O (cooling mixture) to give dark red or orange crystals. These sublime at 25o/0.001mm [Behaghel et al. Chem Ber 65 815 1932, Pitteloud & Petrzilka Helv Chim Acta 62 1319 1979]. [Beilstein 6 III 1111.] HIGHLY TOXIC.
PHENYLSELENYL BROMIDE Preparation Products And Raw materials
PHENYLSELENYL BROMIDE Suppliers
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
BTC pharm India | +918790379245 | AndhraPradesh, India | 1262 | 58 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6257 | 58 | Inquiry |
Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5870 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6905 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
Accela ChemBio Inc. | +1-858-6993322 | United States | 19825 | 58 | Inquiry |
career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29808 | 58 | Inquiry |
Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | China | 52849 | 58 | Inquiry |
Henan Alfa Chemical Co., Ltd | +8615838112936 | China | 13194 | 58 | Inquiry |
Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | China | 8772 | 58 | Inquiry |