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Tetramethylammonium chloride

Tetramethylammonium chloride Structure
CAS No.
75-57-0
Chemical Name:
Tetramethylammonium chloride
Synonyms
TMA;TMAC;TMACL;50g;Tetramethylammoniumchlorid;N,N,N-trimethylmethanaminium chloride;usafan-8;USAF AN-8;N1,1,1,1Cl;tetraminechloride
CBNumber:
CB9118809
Molecular Formula:
C4H12ClN
Molecular Weight:
109.6
MOL File:
75-57-0.mol
MSDS File:
SDS
Modify Date:
2024/7/25 20:04:51

Tetramethylammonium chloride Properties

Melting point >300 °C (lit.)
Boiling point 165.26°C (rough estimate)
Density 1,17 g/cm3
refractive index 1.5320 (estimate)
storage temp. Store below +30°C.
solubility methanol: 0.1 g/mL, clear, colorless
form Hygroscopic Crystalline Powder
Specific Gravity 1.169
color White to ivory
PH 6-8 (100g/l, H2O, 20℃)
Odor Odorless
PH Range 6 - 8
Water Solubility >60 g/100 mL (20 ºC)
Sensitive Hygroscopic
λmax λ: 260 nm Amax: 0.02
λ: 280 nm Amax: 0.02
BRN 2496575
Stability Stable. Incompatible with strong oxidizing agents, water. Hygroscopic.
CAS DataBase Reference 75-57-0(CAS DataBase Reference)
NIST Chemistry Reference Tetramethylammonium chloride(75-57-0)
EPA Substance Registry System Tetramethylammonium chloride (75-57-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H300-H311-H315-H370-H411
Precautionary statements  P260-P264-P273-P280-P301+P310-P302+P352+P312
Hazard Codes  T,Xn
Risk Statements  21-25-36/37/38-20/21/22
Safety Statements  26-36/37-45-37/39-28A-28-36
RIDADR  UN 2811 6.1/PG 2
WGK Germany  1
RTECS  BS7700000
3-10
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29239000
Toxicity LD50 orally in Rabbit: 50 mg/kg LD50 dermal Rat 537 mg/kg
NFPA 704
1
2 0

Tetramethylammonium chloride price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) T3411 Tetramethylammonium chloride solution for molecular biology 75-57-0 500ML ₹6484.18 2022-06-14 Buy
Sigma-Aldrich(India) T3411 Tetramethylammonium chloride solution for molecular biology 75-57-0 1L ₹11604.4 2022-06-14 Buy
Sigma-Aldrich(India) T19526 Tetramethylammonium chloride reagent grade, ≥98% 75-57-0 5G ₹1136.63 2022-06-14 Buy
Sigma-Aldrich(India) T19526 Tetramethylammonium chloride reagent grade, ≥98% 75-57-0 100G ₹2316.55 2022-06-14 Buy
Sigma-Aldrich(India) T19526 Tetramethylammonium chloride reagent grade, ≥98% 75-57-0 500G ₹5997.05 2022-06-14 Buy
Product number Packaging Price Buy
T3411 500ML ₹6484.18 Buy
T3411 1L ₹11604.4 Buy
T19526 5G ₹1136.63 Buy
T19526 100G ₹2316.55 Buy
T19526 500G ₹5997.05 Buy

Tetramethylammonium chloride Chemical Properties,Uses,Production

Chemical Properties

white crystals

Uses

Tetramethylammonium chloride along with N-hydroxyphthalimide and xanthone may be used as an efficient chloride catalytic system for the aerobic oxidation of hydrocarbons to form the corresponding oxygenated compounds. It may also be used as a phase transfer catalyst for the synthesis of aryl fluorides via selective chloride/fluoride exchange reaction of activated aryl chlorides with potassium fluoride in solid-liquid phase.

Uses

Chemical intermediate, catalyst, inhibitor.
	Tetramethylammonium chloride

General Description

Tetramethylammonium chloride is a quaternary ammonium salt commonly used as a catalyst due to its thermal stability and also tolerance towards strong aqueous bases or nucleophiles.

Safety Profile

Poison by ingestion, intraperitoneal, and subcutaneous routes. When heated to decomposition it emits very toxic fumes of NOx, NH3, and Cl-. See also CHLORIDES.

Purification Methods

Crystallise the chloride from EtOH, EtOH/CHCl3, EtOH/diethyl ether, acetone/EtOH (1:1), isopropanol or water. Traces of the free amine can be removed by washing with CHCl3. [Beilstein 4 IV 145.]

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