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Ammonium carbonate

Ammonium carbonate Structure
CAS No.
506-87-6
Chemical Name:
Ammonium carbonate
Synonyms
Glucitol;crystalammonia;hartshorn;HARTSHORN SALT;BROMOCRESOL GRE;ammoniumcarbonat;SALT OF HARTSHORN;AMMONIUM CARBONATE;diammoniumcarbonate;AMMONIU BICARBONATE
CBNumber:
CB9393644
Molecular Formula:
CH8N2O3
Molecular Weight:
96.09
MOL File:
506-87-6.mol
MSDS File:
SDS
Modify Date:
2023/5/25 18:01:23

Ammonium carbonate Properties

Melting point 58 °C
Boiling point 179.58°C (rough estimate)
Density 1.5
vapor density 2.7 (vs air)
vapor pressure 760 mm Hg @ 600C
refractive index 1.4616 (estimate)
storage temp. Store at RT.
solubility H2O: 0.1 g/mL at 25 °C, clear, colorless
form Solid
color White to yellow
Odor strong odor of NH3
PH Range 9
Water Solubility SOLUBLE
Sensitive Hygroscopic
Merck 14,508
BRN 3627235
LogP -0.809 (est)
CAS DataBase Reference 506-87-6(CAS DataBase Reference)
EPA Substance Registry System Ammonium carbonate (506-87-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P301+P312+P330
Hazard Codes  Xn
Risk Statements  22-52/53
Safety Statements  24/25
RIDADR  UN 9084
WGK Germany  1
RTECS  BP1925000
13
TSCA  Yes
HS Code  28369940
Toxicity LD50 ivn-mus: 96 mg/kg AJVRAH 29,897,68
NFPA 704
0
2 1

Ammonium carbonate price More Price(23)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 207861 Ammonium carbonate ACS reagent, ≥30.0% NH3 basis 506-87-6 25G ₹2662.95 2022-06-14 Buy
Sigma-Aldrich(India) 207861 Ammonium carbonate ACS reagent, ≥30.0% NH3 basis 506-87-6 25G ₹2662.95 2022-06-14 Buy
Sigma-Aldrich 207861 Ammonium carbonate ACS reagent, ≥30.0% NH3 basis 506-87-6 100G ₹5423.33 2022-06-14 Buy
Sigma-Aldrich(India) 207861 Ammonium carbonate ACS reagent, ≥30.0% NH3 basis 506-87-6 100G ₹5423.33 2022-06-14 Buy
Sigma-Aldrich(India) 379999 Ammonium carbonate 99.999% trace metals basis 506-87-6 10G ₹5564.05 2022-06-14 Buy
Product number Packaging Price Buy
207861 25G ₹2662.95 Buy
207861 25G ₹2662.95 Buy
207861 100G ₹5423.33 Buy
207861 100G ₹5423.33 Buy
379999 10G ₹5564.05 Buy

Ammonium carbonate Chemical Properties,Uses,Production

Chemical Properties

Anunonium carbonate is a white water-soluble, volatile solid prepared by reaction of NH4OH and CO2 and crystallizing from dilute alcohol. Ammonium carbonate loses NH3,CO2, and H20 at ordinary temperatures, and rapidly at 58°C.

Physical properties

Colorless or translucent hard crystalline mass or white cubic crystals or powder; sharp taste; odor of ammonia; decomposes at 58°C; slow decomposition at ambient temperatures; readily dissolves in cold water; decomposes in hot water; insoluble in liquid ammonia, alcohol and carbon disulfide.

Uses

Ammonium Carbonate is a dough strengthener, a leavening agent, a ph control agent, and a texturizer. it is prepared by the sublima- tion of a mixture of ammonium sulfate and calcium carbonate, and occurs as a white powder or a hard, white translucent mass.

Preparation

Ammonium carbonate is obtained by passing carbon dioxide into aqueous ammonia solution in a column or tower. Ammonia, carbon dioxide and water vapor are distilled and the vapors condensed into a solid crystalline mass. It also may be prepared by subliming a mixture of ammonium sulfate and calcium carbonate.

Definition

ammonium carbonate: A colourlessor white crystalline solid,(NH4)2CO3, usually encountered asthe monohydrate. It is very soluble incold water. The compound decomposesslowly to give ammonia, water,and carbon dioxide. Commercial ‘ammoniumcarbonate’ is a double saltof ammonium hydrogencarbonateand ammonium aminomethanoate(carbamate), NH4HCO3.NH2COONH4.This material is manufactured byheating a mixture of ammoniumchloride and calcium carbonate andrecovering the product as a sublimedsolid. It readily releases ammoniaand is the basis of sal volatile. It isalso used in dyeing and wool preparationand in baking powders.

General Description

A colorless crystalline solid or a white powder with a strong odor of ammonia. Noncombustible. The primary hazard is the threat to the environment. Immediate steps should be taken to limit spread to the environment. Used to make other ammonium compounds, in pharmaceuticals, in food processing.

Air & Water Reactions

Water soluble.

Reactivity Profile

Ammonium carbonate decomposes when heated to give gaseous ammonia and gaseous carbon dioxide. Reaction is non-explosvie. Causes decomposition of sodium hypochlorite within a few seconds [Mellor 2 Supp. 1:550 1956].

Hazard

Evolves irritating fumes when heated.

Health Hazard

Inhalation causes irritation of nose and throat. Ingestion may cause gastric irritation. Contact with eyes or skin causes irritation.

Agricultural Uses

Ammonium carbonate, (NH4)2CO3, is an intermediate product formed during the synthesis of urea. Ammonium carbonate on decomposition yields urea and water.

Safety Profile

Poison by subcutaneous and intravenous routes. When heated to decomposition it emits toxic fumes of NO, and NH3.

Potential Exposure

It is used in dyeing, tanning, medicines, fire extinguishers; to make casein glue; ammonia salts; and baking powders. A laboratory reagent.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Acids, acid salts; salts of iron and zinc, alkaloids, calomel and tartar emetic. Keep cool, below 38 C. Contact with inorganic acids may form CO2, heat, and dangerous spattering.

Waste Disposal

Slowly deposit in a large container of water. Add excess amounts of soda ash and let stand for 24 hours. Decant to another container, neutralize with hydrochloric acid, and drain with an excess of water. Ship to landfill.

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