ChemicalBook > Product Catalog >Pharmaceutical intermediates >Heterocyclic compound >Pyridine compound >Pyridine derivatives >2,2':6',2''-TERPYRIDINE
2,2':6',2''-TERPYRIDINE
- CAS No.
- 1148-79-4
- Chemical Name:
- 2,2':6',2''-TERPYRIDINE
- Synonyms
- Terpyridine;TERPY;´SKL085;Ba 2799;Nsc3905;TRIPYRIDYL;Terpyridyl;Trypyridyl;TRIPYRIDINE
- CBNumber:
- CB1407532
- Molecular Formula:
- C15H11N3
- Molecular Weight:
- 233.27
- MOL File:
- 1148-79-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/9 21:58:15
| Melting point | 90-93 °C |
|---|---|
| Boiling point | 370 °C |
| Density | 1.1901 (rough estimate) |
| refractive index | 1.5610 (estimate) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | dioxane: 0.1 g/mL, clear |
| pka | 4.60±0.10(Predicted) |
| form | Crystalline powder |
| color | Cream to yellow to brown |
| Water Solubility | 1.472g/L(24.99 ºC) |
| BRN | 11199 |
| InChIKey | DRGAZIDRYFYHIJ-UHFFFAOYSA-N |
| CAS DataBase Reference | 1148-79-4(CAS DataBase Reference) |
| EPA Substance Registry System | 2,2':6',2''-Terpyridine (1148-79-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H300+H310-H315-H318-H335 | |||||||||
| Precautionary statements | P261-P262-P280-P301+P310-P302+P352+P310-P305+P351+P338 | |||||||||
| Hazard Codes | T+,T | |||||||||
| Risk Statements | 27/28-37/38-41 | |||||||||
| Safety Statements | 26-28-36/37/39-45 | |||||||||
| RIDADR | UN 2811 6.1/PG 1 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | I | |||||||||
| HS Code | 29333990 | |||||||||
| NFPA 704 |
|
2,2':6',2''-TERPYRIDINE price More Price(8)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 234672 | 2,2′:6′,2′′-Terpyridine 98% | 1148-79-4 | 250MG | ₹3821.23 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 234672 | 2,2′:6′,2′′-Terpyridine 98% | 1148-79-4 | 1G | ₹11571.93 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 234672 | 2,2′:6′,2′′-Terpyridine 98% | 1148-79-4 | 5G | ₹36934.9 | 2022-06-14 | Buy |
| ALFA India | ALF-A17750-06 | 2,2':6',2''-Terpyridine, 97% | 1148-79-4 | 5g | ₹27876 | 2022-05-26 | Buy |
| TCI Chemicals (India) | T0024 | 2,2':6',2''-Terpyridine min. 98.0 % | 1148-79-4 | 200MG | ₹2300 | 2022-05-26 | Buy |
2,2':6',2''-TERPYRIDINE Chemical Properties,Uses,Production
Description
A case of occupational dermatitis was reported in a chemical technician, with no cross reactivity to pyridine derivatives.
Chemical Properties
Off-white crystal
Uses
2,2';6',2"-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture the racks, ladders and grids, helicates, catenanes and dendrimers. It plays an important role as a ligand in coordination chemistry. Its complexes are employed in the oxidation of alcohols, the carbonylation of aromatic compounds and as oxygen-binding molecules. Functionalized terpyridine ligands were used in semiconductors and solar panels. It forms chealate complexes with europium(III) and terbium(III), which is used in protein labelling.
Definition
ChEBI: A tridentate heterocyclic ligand that binds metals at three meridional sites giving two adjacent 5-membered MN2C2 chelate rings.
General Description
2,2′:6′,2′′;-Terpyridine is a tridentate ligand that can be prepared in two steps starting from 2-acetylpyridine.
Contact allergens
This molecule is a terpyridine with a 4-methyl substitution. A case of occupational dermatitis was reported in a chemical technician with no cross-reactivity to pyridine derivatives.
Purification Methods
Crystallise it from diethyl ether, toluene or from pet ether, then aqueous MeOH, followed by sublimation in a vacuum at 90o. It is used for estimating Ag and Ru. [Kamra et al. Anal Chim Acta 81 177 1976, Beilstein 26 III/IV 258.]
2,2':6',2''-TERPYRIDINE Preparation Products And Raw materials
Raw materials
3,3-bis(methylsulfanyl)-1-pyridin-2-ylprop-2-en-1-one
TRIMETHYL(2-PYRIDYL)TIN
2,6-Diiodopyridine
4'-(METHYLTHIO)-2,2':6',2''-TERPYRIDINE
4-Bromo-2,2''-bipyridine
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Global( 241)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
| Sapala Organics Private Limited | +91-4027170174 +91-9963110948 | Telangana, India | 89 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Gagri Global IT Services Pvt. Ltd. | +91-40-27170174, | Telangana, India | 1321 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Sapala Organics Private Limited | 08048372577Ext 676 | Mallapur, India | 50 | 58 | Inquiry |
| TSK Lifesciences | 91-9397306789 | Hyderabad, India | 246 | 58 | Inquiry |
| OCEAN TRADING CORPORATION | +91(22) 24921669 | New Delhi, India | 6211 | 58 | Inquiry |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | China | 6938 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| GLR Innovations | 58 |
| Sapala Organics Private Limited | 58 |
| A.J Chemicals | 58 |
| Gagri Global IT Services Pvt. Ltd. | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Sapala Organics Private Limited | 58 |
| TSK Lifesciences | 58 |
| OCEAN TRADING CORPORATION | 58 |
| Shanghai UCHEM Inc. | 58 |
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2,2':6',2''-Terpyridine,97%
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2,2':6',2''-Terpyridine >
α,α',α''-Tripyridyl
2,2':6',2''-TERPYRIDINE ISO 9001：2015 REACH
SKL085
TERPY
Terpyridine
2,2':6',2''-Terpyridine (6CI, 7CI, 8CI, 9CI, ACI)
2,2':6',2''-Terpyridine,98% TERPY
2,2':6',2''-TERPYRIDINE
2,2':6',2"-Terpyridine
2,2',2''-Terpyridine
2,2':6,2''-terpyridine
1148-79-4
11448-79-4
C5H4NC5H3NC5H4N
C15H11N3
C15H13Cl2N3O8
Analytical Chromatography Product Catalog
Analytical Reagents
IR/UV/ VIS
Spectroscopy Reagents
Pyrimidines
Achiral Nitrogen
Py-N