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Terephthalaldehyde

Terephthalaldehyde Structure
CAS No.
623-27-8
Chemical Name:
Terephthalaldehyde
Synonyms
1,4-PHTHALALDEHYDE;Terephthaldehyde;1,4-BENZENEDICARBOXALDEHYDE;TEREPHTHALDICARBOXALDEHYDE;P-benzaldehyde;P-PHTHALALDEHYDE;TPAL;Benzene-1,4-dialdehyde;4-Formylbenzaldehyde;Terephtaldehyde
CBNumber:
CB1425781
Molecular Formula:
C8H6O2
Molecular Weight:
134.13
MOL File:
623-27-8.mol
MSDS File:
SDS
Modify Date:
2024/8/6 16:32:36

Terephthalaldehyde Properties

Melting point 114-116 °C (lit.)
Boiling point 245-248 °C (lit.)
Density 1,06 g/cm3
vapor pressure 0.25-0.46Pa at 20-25℃
refractive index 1.4800 (estimate)
Flash point 76 °C
storage temp. Store below +30°C.
solubility 3g/l
form Crystalline Powder
color White to light yellow
Water Solubility 3 g/L (50 ºC)
Sensitive Air Sensitive
BRN 385863
InChIKey KUCOHFSKRZZVRO-UHFFFAOYSA-N
LogP 1 at 20.1℃ and pH6.6-6.8
CAS DataBase Reference 623-27-8(CAS DataBase Reference)
NIST Chemistry Reference 1,4-Benzenedicarboxaldehyde(623-27-8)
EPA Substance Registry System 1,4-Benzenedicarboxaldehyde (623-27-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38-36/37
Safety Statements  22-24/25-36-26-37/39
WGK Germany  1
RTECS  WZ0430000
Hazard Note  Irritant
TSCA  Yes
HS Code  29122900
NFPA 704
1
2 0

Terephthalaldehyde price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) T2207 Terephthalaldehyde ReagentPlus?, 99% 623-27-8 5G ₹2510 2022-06-14 Buy
Sigma-Aldrich(India) T2207 Terephthalaldehyde ReagentPlus?, 99% 623-27-8 100G ₹4040 2022-06-14 Buy
Sigma-Aldrich(India) T2207 Terephthalaldehyde ReagentPlus?, 99% 623-27-8 500G ₹14950 2022-06-14 Buy
Sigma-Aldrich(India) 8.08617 Terephthaldialdehyde for synthesis 623-27-8 100G ₹8380 2022-06-14 Buy
TCI Chemicals (India) T0010 Terephthalaldehyde min. 98.0 % 623-27-8 25G ₹2300 2022-05-26 Buy
Product number Packaging Price Buy
T2207 5G ₹2510 Buy
T2207 100G ₹4040 Buy
T2207 500G ₹14950 Buy
8.08617 100G ₹8380 Buy
T0010 25G ₹2300 Buy

Terephthalaldehyde Chemical Properties,Uses,Production

Description

Terephthalaldehyde is an aromatic dialdehyde. Theoretically, the two aldehydes of terephthalaldehyde (TPA) are equivalent, so the single or double Schiff base from TPA and d-glucosamine (Glc) may be formed at the same time. It is used as an intermediate for the preparation of dyes and fluorescent whitening agents and in the synthesis of polyimines by reacting with aliphatic diamines. It is also used as a precursor for the preparation of paramagnetic microporous polymeric organic frameworks (POFs) through copolymerization with pyrrole, indole, and carbazole. As a good crosslinking agent, it could used in crosslinked chitosan hydrogel for the selective removal of anionic dyes[1].

Chemical Properties

WHITE TO LIGHT YELLOW CRYSTALLINE POWDER

Uses

Terephthalaldehyde (cas# 623-27-8) is a compound useful in organic synthesis.

Purification Methods

Terephthalaldehyde [623-27-8] M 134.1, m 116o, b 245 -248o/771mm. Crystallise terephthalaldehyde from water. [Beilstein 7 IV 2140.]

References

[1] Weng Q, et al. Controllable Synthesis and Biological Application of Schiff Bases from d-Glucosamine and Terephthalaldehyde. ACS Omega, 2020; 5: 24864–24870.

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