ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >2-CHLOROPHENYLZINC IODIDE
2-CHLOROPHENYLZINC IODIDE
- CAS No.
- 148651-35-8
- Chemical Name:
- 2-CHLOROPHENYLZINC IODIDE
- Synonyms
- 2-CHLOROPHENYLZINC IODIDE;2-chlorophenylzinc iodide solution;2-Chlorophenylzinc iodide solution 0.5 in THF;2-Chlorophenylzinc iodide solution 0.5M in THF;2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran;2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles;2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
- CBNumber:
- CB1436675
- Molecular Formula:
- C6H4ClIZn
- Molecular Weight:
- 303.84
- MOL File:
- 148651-35-8.mol
- Modify Date:
- 2023/5/27 8:28:43
Density | 0.973 g/mL at 25 °C |
---|---|
Flash point | 1 °F |
storage temp. | 2-8°C |
Sensitive | Air & Light Sensitive |
Exposure limits |
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin) OSHA: TWA 200 ppm(590 mg/m3) NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
CAS DataBase Reference | 148651-35-8 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05,GHS02,GHS07,GHS08 |
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Signal word | Danger | |||||||||
Hazard statements | H261-H314-H318-H333-H225-H302-H319-H335-H351 | |||||||||
Precautionary statements | P223-P303+P361+P353-P405-P501a-P210-P280-P301+P312+P330-P305+P351+P338-P370+P378-P403+P235 | |||||||||
Hazard Codes | F,Xn | |||||||||
Risk Statements | 11-19-22-36/37/38-40-36/37 | |||||||||
Safety Statements | 16-26-33-36-36/37 | |||||||||
RIDADR | UN 2056 3/PG 2 | |||||||||
WGK Germany | 1 | |||||||||
HazardClass | 4.3 | |||||||||
NFPA 704 |
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2-CHLOROPHENYLZINC IODIDE Chemical Properties,Uses,Production
Uses
2-Chlorophenylzinc iodide is an organozinc compound, which can be used as a reactant in Negishi cross-coupling reaction to construct carbon-carbon bonds by reacting with organic halides using nickel or palladium catalysts.
It can also be utilized as a reactant to prepare:
- Arylmethanes via rhodium-catalyzed cross-coupling reaction with methyl halides.
- (2-chlorobenzyl)trimethylsilane by Rh-catalyzed cross-coupling reaction with (iodomethyl)trimethylsilane.
- Dichloro biphenyl by palladium catalyzed oxidative homocoupling reaction using N-chlorosuccinimide (NCS) or O2 as the oxidant.
2-CHLOROPHENYLZINC IODIDE Preparation Products And Raw materials
2-CHLOROPHENYLZINC IODIDE Suppliers
Global( 16)Suppliers
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
Sainor Laboratories Private Limited | 09666644167 | Hyderabad, India | 66 | 58 | Inquiry |
Guangdong Wengjiang Chemical Reagent Co., Ltd. | 0751-2886766 13927870850 | China | 9984 | 58 | Inquiry |
Huangshi Bo’Er Chemical Co., Ltd. | 0714-6401888 18671400300 | China | 530 | 58 | Inquiry |
Baoji Didu Pharmaceutical and Chemical Co., Ltd | 029-81148929 13186179623 | China | 10011 | 58 | Inquiry |
Infinity SCI | 400-400-1062016 17800804092 | China | 632 | 55 | Inquiry |
Riedel-de Haen AG | 800 558-9160 | United States | 6825 | 87 | Inquiry |
Rieke Metals, Inc. | 402 434 2775 | United States | 6509 | 69 | Inquiry |
3B Scientific Corporation | 847.281.9822 | United States | 6744 | 47 | Inquiry |
SIGMA-RBI | 800 736 3690 (Orders) | Switzerland | 6913 | 91 | Inquiry |
Alfa Aesar | 400-6106006 | China | 30132 | 84 | Inquiry |
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2-CHLOROPHENYLZINC IODIDE
2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
2-chlorophenylzinc iodide solution
2-Chlorophenylzinc iodide solution 0.5 in THF
2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles
2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
2-Chlorophenylzinc iodide solution 0.5M in THF
2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran
148651-35-8
ClC6H4ZnI
Aryl
Organozinc Halides
Organometallic Reagents
Reike and Organozinc Reagents
Aryl
Organozinc Halides
Reike and Organozinc Reagents