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1-METHOXY-1,3-CYCLOHEXADIENE

1-METHOXY-1,3-CYCLOHEXADIENE Structure
CAS No.
2161-90-2
Chemical Name:
1-METHOXY-1,3-CYCLOHEXADIENE
Synonyms
2,3-DIHYDROANISOLE;1-METHOXY-1,3-CYCLOHEXADIENE;1-methoxycyclohexa-1,3-diene;1,3-Cyclohexadiene, 1-methoxy-;1,3-Cyclohexadien-1-yl methyl ether;1-METHOXY-1,3-CYCLOHEXADIENE, TECH., 65%;1-Methoxy-1,3-cyclohexadiene,2,3-Dihydroanisole;1-Methoxy-1,3-cyclohexadiene technical grade, 65%
CBNumber:
CB1494725
Molecular Formula:
C7H10O
Molecular Weight:
110.15
MOL File:
2161-90-2.mol
MSDS File:
SDS
Modify Date:
2023/5/25 18:01:00
Request For Quotation

1-METHOXY-1,3-CYCLOHEXADIENE Properties

Melting point 96-97 °C
Boiling point 40 °C/15 mmHg (lit.)
Density 0.929 g/mL at 25 °C (lit.)
refractive index n20/D 1.488(lit.)
Flash point 80 °F
LogP 1.790 (est)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H302+H312+H332
Precautionary statements  P210-P233-P280-P301+P312-P303+P361+P353-P304+P340+P312
Hazard Codes  Xn
Risk Statements  10-20/21/22
Safety Statements  16-33-36/37/39
RIDADR  UN 1993 3/PG 3
WGK Germany  3
HazardClass  3.2
PackingGroup  III

1-METHOXY-1,3-CYCLOHEXADIENE Chemical Properties,Uses,Production

Uses

1-Methoxy-1,3-cyclohexadiene was used in the following studies:

  • Synthesis of tetracyclic polyhydroxyquinones via Diels-Alder reaction.
  • Synthesis of tetra-ortho-substituted biaryls via Diels-Alder reaction.
  • Synthesis of optically active form of dihydroisocoumarin fragment of the gastroprotective natural product AI-77-B, via regiospecific Diels-Alder reaction with an acetylenic ester derivative.

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 4195, 1972 DOI: 10.1016/S0040-4039(01)94273-X

General Description

1-Methoxy-1,3-cyclohexadiene is a useful Diels-Alder diene employed in Diels-Alder cycloadditions. It undergoes Diels-Alder reaction with alkyne to yield anisole derivative.

1-METHOXY-1,3-CYCLOHEXADIENE Preparation Products And Raw materials

Raw materials

Preparation Products

1-methoxycyclohexene 2-METHOXY-6-METHYLBENZOIC ACID ETHYL ESTER

1-METHOXY-1,3-CYCLOHEXADIENE Suppliers

Global( 14)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Dayang Chem (Hangzhou) Co.,Ltd. 571-88938639 +8617705817739 China 52861 58 Inquiry
GIHI CHEMICALS CO.,LIMITED +8618058761490 China 49999 58 Inquiry
Aladdin Scientific +1-+1(833)-552-7181 United States 52927 58 Inquiry
Shanghai Aladdin Biochemical Technology Co.,Ltd. +86-18521732826 China 48467 58 Inquiry
BOC Sciences USA 0 65 Inquiry
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd 15229059051 China 9971 58 Inquiry
MP Biomedicals, Inc. 949 833 2500 United States 6566 81 Inquiry
SIGMA-RBI 800 736 3690 (Orders) Switzerland 6913 91 Inquiry
3B Pharmachem (Wuhan) International Co.,Ltd. 821-50328103-801 18930552037 China 15848 69 Inquiry
Energy Chemical 021-021-58432009 400-005-6266 China 44700 61 Inquiry
Supplier Advantage
Dayang Chem (Hangzhou) Co.,Ltd. 58
GIHI CHEMICALS CO.,LIMITED 58
Aladdin Scientific 58
Shanghai Aladdin Biochemical Technology Co.,Ltd. 58
BOC Sciences 65
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd 58
MP Biomedicals, Inc. 81
SIGMA-RBI 91
3B Pharmachem (Wuhan) International Co.,Ltd. 69
Energy Chemical 61

1-METHOXY-1,3-CYCLOHEXADIENE Spectrum

1-METHOXY-1,3-CYCLOHEXADIENE(2161-90-2)1HNMR1-METHOXY-1,3-CYCLOHEXADIENE(2161-90-2)IR1-METHOXY-1,3-CYCLOHEXADIENE(2161-90-2)Raman1-METHOXY-1,3-CYCLOHEXADIENE(2161-90-2)FT-IR

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1-METHOXY-1,3-CYCLOHEXADIENE 2,3-DIHYDROANISOLE 1,3-Cyclohexadien-1-yl methyl ether 1,3-Cyclohexadiene, 1-methoxy- 1-methoxycyclohexa-1,3-diene 1-METHOXY-1,3-CYCLOHEXADIENE, TECH., 65% 1-Methoxy-1,3-cyclohexadiene,2,3-Dihydroanisole 1-Methoxy-1,3-cyclohexadiene technical grade, 65% 2161-90-2 Building Blocks Enol Ethers Oxygen Compounds Organic Building Blocks