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4-Chlorobenzotrichloride

4-Chlorobenzotrichloride  Structure
CAS No.
5216-25-1
Chemical Name:
4-Chlorobenzotrichloride
Synonyms
PCTC;orobenzotrichL;Tetrachlorotoluene;4-Chlorobenzotrichlo;4-Chlorbenzotrichlorid;p-Chlorbenzotrichlorid;4-chlorobenzotrichlorid;Clotrimazole Impurity 5;P-CHLOROBENZOTRICHLORIDE;p-Chlorotrichlorotoluene
CBNumber:
CB2146946
Molecular Formula:
C7H4Cl4
Molecular Weight:
229.92
MOL File:
5216-25-1.mol
Modify Date:
2024/3/14 15:18:26

4-Chlorobenzotrichloride Properties

Melting point 5.8 °C
Boiling point 245 °C(lit.)
Density 1.495 g/mL at 25 °C(lit.)
refractive index n20/D 1.572(lit.)
Flash point >230 °F
solubility Chloroform (Sparingly), DMSO (Sparingly)
form clear liquid
color Colorless to Light yellow
Water Solubility decomposes
Sensitive Moisture Sensitive
BRN 1866549
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference 5216-25-1(CAS DataBase Reference)
NIST Chemistry Reference Benzene, 1-chloro-4-(trichloromethyl)-(5216-25-1)
EPA Substance Registry System 4-Chlorobenzotrichloride (5216-25-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS08
Signal word  Danger
Hazard statements  H302+H312-H315-H319-H372-H412-H302-H312-H335-H350-H361
Precautionary statements  P260-P264-P270-P273-P280-P301+P312+P330-P302+P352+P312+P362+P364-P305+P351+P338+P337+P313-P314-P501-P201-P304+P340-P405-P501a
Hazard Codes  T
Risk Statements  45-21/22-37/38-48/23-62
Safety Statements  53-45
RIDADR  UN 1760 8/PG 2
WGK Germany  3
RTECS  XT8580000
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29039990
Toxicity LD50 orl-rat: 820 mg/kg EPASR* 8EHQ-0281-0360
NFPA 704
0
3 1

4-Chlorobenzotrichloride Chemical Properties,Uses,Production

Chemical Properties

p-Chlorobenzotrichloride, an organochloride, is a flammable, water-white liquid.

Uses

4-Chlorobenzotrichloride is a useful reactant in organic synthesis.

General Description

Clear colorless liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Simple aromatic halogenated organic compounds, such as 4-Chlorobenzotrichloride , are very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Health Hazard

ACUTE/CHRONIC HAZARDS: Corrosive; Lachrymator.

Fire Hazard

Flash point data for 4-Chlorobenzotrichloride are not available, however, 4-Chlorobenzotrichloride is probably combustible.

Safety Profile

Suspected carcinogen. A poison by inhalation. Moderately toxic by ingestion and skin contact. When heated to decomposition it emits toxic vapors of Cl-.

Potential Exposure

Used in agrochemicals manufacture as an intermediate; reaction with HF yields chlorobenzotrifluoride as a major intermediate for several pesticides; for making pharmaceuticals; UV absorbers, and dyestuffs. This chemical is manufactured in high volume (exceeds 1 million pounds per annum) in the United States.

Shipping

UN1760 Corrosive liquids, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.

Incompatibilities

A halogenated aromatic compound. Hydrolyzes to hydrochloric acid and benzoic acid in all forms of moisture. Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from reducing agents, alkaline materials, strong acids, strong bases, amines, nitrides, azo/ diazo compounds, alkali metals, and epoxides.

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P-CHLORO-A,A,A-TRICHLOROTOLUENE P-CHLOROBENZOTRICHLORIDE PCTC P-CHLORO(TRICHLOROMETHYL)BENZENE 1-chloro-4-(trichloromethyl)-benzen 1-Chloro-4-(trichloromethyl)benzene 1-chloro-4-trichloromethyl-benzene 4,alpha,alpha,alpha-Tetrachlorotoluene alpha,alpha,alpha,para-tetrachlorotoluene alpha,alpha,alpha,p-tetrachloro-toluen Benzene,1-chloro-4-(trichloromethyl)- p,alpha,alpha,alpha-Tetrachlorotoluene p-Chlorophenyltrichloromethane p-Chlorotrichlorotoluene p-Trichloromethylchlorobenzene Toluene, alpha,alpha,alpha,p-tetrachloro- Toluene, p,alpha,alpha,alpha-tetrachloro- 4-CHLOROBENZOTRICHLORIDE A,A,A,P-TETRACHLOROTOLUENE ALPHA,ALPHA,ALPHA,4-TETRACHLOROTOLUENE Tetrachlorotoluene 4-CHLOROBENZOTRICHLORIDE OEKANAL, 250 MG 4-Chloro-α,α,α-trichlorotoluene P-CHLORO BENOTRICHLORIDE 4-Chlorbenzotrichlorid 4-chlorobenzotrichlorid alpha,alpha,alpha-trichloro-4-chlorotoluene 4-CHLORO-ALPHA,ALPHA,ALPHA-TRICHLOROTOLUENE PARA,ALPHA,ALPHA,ALPHA-TETRACHLORO-TOLUENE p-Chlorbenzotrichlorid 4-CHLOROBENZOTRICHLORIDE, 98+% 44) PARA CHLORO BENZO TRICHLORIDE α,α,α,4-tetrachlorotoluene p-chlorobenzotrichloride 1-(Trichloromethyl)-4-chlorobenzene à,à,à,4-tetrachlorotoluene α,α,α,4-tetrachlorotoluene Alpha,alpha,alpha,p-tetrachlorotoluene 4-Chlorobenzotrichloride,99% 4-Chlorobenzotrichlo 4-Chlorobenzotrichloride, 99% 50GR a,a,a-4-Tetrachlorotoluene 4-Chloromethyl benzyl chloride 4-Chlorobenzotrichloride > orobenzotrichL Clotrimazole Impurity 5 2-Chloro-4-(Trichloromethyl) Benzene 5216-25-1 ClC6H4CCl3 C7H4CI4 Aryl C7 Building Blocks Organic Building Blocks Halogenated Hydrocarbons