Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate
![Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Structure](CAS/GIF/147531-11-1.gif)
- CAS No.
- 147531-11-1
- Chemical Name:
- Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate
- Synonyms
- Diphenyl(trifluoromethyl);diphenyl(trifluoromethyl)sulfanium;sulfonium trifluoromethanesulfonate;diphenyl-(trifluoroMethyl)-sulfoniuM;(S)-(trifluoroMethyl)diphenylsulfoniuM triflate;Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfot;Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonat;diphenyl(trifluoromethyl)sulfanium trifluoromethanesulfonate;diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate;Diphenyl-(trifluoroMethyle)-sulfoniuM trifluoroMethancesulfonate
- CBNumber:
- CB22470708
- Molecular Formula:
- C13H10F3S.CF3O3S
- Molecular Weight:
- 404.35
- MOL File:
- 147531-11-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/5/4 15:15:31
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H302 |
Precautionary statements | P264-P270-P301+P312-P330-P501 |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
HS Code | 29339900 |
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Chemical Properties,Uses,Production
Uses
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate can be used as a raw material for organic synthesis with styrene derivatives to synthesise 2-arylazo pyridine at low temperature[1].
Synthesis
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate is synthesised using phenyl trifluoromethyl sulfoxide as a raw material by chemical reaction. The specific synthesis steps are as follows:
Trifluoromethyl sulfoxide (0.4 g, 2.1 mmol) and then benzene (4.9 g, 64 mmol) are introduced, under an inert atmosphere and at approximately 0° C. (lower limit below which benzene crystallizes), into a Schlenck tube purged beforehand with argon. Five equivalents of triflic anhydride (2.82 g, 10 mmol) are gradually added. The mixture is stirred for 1 h at 0° C. and then for 24 h at ambient temperature. The medium is evaporated and the residue is purified by chromatography with the CH3CN/CH2Cl2 (1/4) mixture as eluent. White crystals (Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate), having a melting point of 69-70° C., are obtained with a yield of 40%.
References
[1] J. MATSUO. A Convenient Method for the Synthesis of 2-Arylaziridines from Styrene Derivatives via 2-Arylethenyl(diphenyl)sulfonium Salts[J]. Chemistry Letters, 2003. DOI:10.1246/CL.2003.392.
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 16220 | 58 | Inquiry |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | China | 9338 | 55 | Inquiry |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49391 | 58 | Inquiry |
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | CHINA | 21149 | 58 | Inquiry |
Allfluoro pharmaceutical co. ltd. | 021-26137118 +8615821363818 | China | 5791 | 58 | Inquiry |
Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | China | 30253 | 58 | Inquiry |
ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | China | 23556 | 58 | Inquiry |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | China | 52861 | 58 | Inquiry |
147531-11-1(Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate)Related Search:
1of3
chevron_right