1,1,2,2-TETRAPHENYLDISILANE
- CAS No.
- 16343-18-3
- Chemical Name:
- 1,1,2,2-TETRAPHENYLDISILANE
- Synonyms
- TPDS;1,1,2,2-TETRAPHENYLDISILANE;Disilane, 1,1,2,2-tetraphenyl-
- CBNumber:
- CB2402468
- Molecular Formula:
- C24H22Si2
- Molecular Weight:
- 366.6
- MOL File:
- 16343-18-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/6/8 17:06:34
Melting point | 80 °C |
---|---|
Boiling point | 441.7±18.0 °C(Predicted) |
solubility | soluble in chloroform and most organic solvents, less soluble in ethanol. |
form | powder to crystal |
color | White to Light yellow to Light orange |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H315-H319 |
Precautionary statements | P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P |
Risk Statements | 36/37/38 |
Safety Statements | 26-36/37/39 |
HS Code | 2931.90.6000 |
1,1,2,2-TETRAPHENYLDISILANE price More Price(2)
1,1,2,2-TETRAPHENYLDISILANE Chemical Properties,Uses,Production
Physical properties
mp 79–80 °C
Uses
1,1,2,2-tetraphenyldisilane (TPDS) is more effective than pentamethyldisilane, since one phenyl group on the Si–H group probably reduces by 2 kcal/mol the Si–H bond dissociation energy. TPDS is used for radical reduction, intramolecular and intermolecular carbon–carbon bond formation, 1,2-elimination, etc., of halides, chalcogenides, and xanthates.
Preparation
generally, 1,1,2,2-tetraphenyldisilane is prepared by the coupling reaction of diphenylsilane in the presence of diphenyltitanocene without solvent under heating conditions at 110°Cfor 24 h.
1,1,2,2-TETRAPHENYLDISILANE Preparation Products And Raw materials
1,1,2,2-TETRAPHENYLDISILANE Suppliers
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16343-18-3(1,1,2,2-TETRAPHENYLDISILANE)Related Search:
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TPDS
1,1,2,2-TETRAPHENYLDISILANE
Disilane, 1,1,2,2-tetraphenyl-
16343-18-3
C24H22Si2
Si (Classes of Silicon Compounds)
Si-Si Compounds
Si-H Compounds
Reduction
Reduction
Si (Classes of Silicon Compounds)
Si-H Compounds
Si-Si Compounds
Synthetic Organic Chemistry