CADINENE

CADINENE Structure
CAS No.
29350-73-0
Chemical Name:
CADINENE
Synonyms
CADINENE;6alpha,8abeta)]-alphdidehydroderiv.;4-Isopropyl-1,6-dimethyl-decahydronaphthalene;1-Isopropyl-4,7-dimethyl-1,2,4a,5,8,8a-hexahydronaphthalene;naphthalene,decahydro-1,6-dimethyl-4-(1-methylethyl)-,[1s-(1alpha,4alpha,4a;(1S,4aβ,8aβ)-Decahydro-1β,6β-dimethyl-4β-(1-methylethyl)didehydronaphthalene;Naphthalene, decahydro-1,6-dimethyl-4-(1-methylethyl)-, (1S,4S,4aS,6S,8aS)-, didehydro deriv.;[1S-(1alpha,4.alpha,4aalpha,6alpha,8abeta)]-Decahydro-4-isopropyl-1,6-dimethylnaphthalin, Didehydroderivat;[1S-(1alpha,4alpha,4aalpha,6alpha,8abeta)]-decahydro-4-isopropyl-1,6-dimethylnaphthalene, didehydro derivative;Naphthalene,decahydro-1,6-dimethyl-4-(1-methylethyl)-,[1S-(1.alpha.,4.alpha.,4a.alpha.,6.alpha.,8a.beta.)]-,didehydroderiv.
CBNumber:
CB2495062
Molecular Formula:
C15H26
Molecular Weight:
206.37
MOL File:
Mol file
Modify Date:
2024/12/18 14:07:02

CADINENE Properties

Melting point 220 °C
Boiling point 277.87°C (rough estimate)
Density 0.9200 (rough estimate)
refractive index 1.5600 (estimate)
Odor at 100.00 %. fresh woody longifolone
Odor Type woody
Stability Stable. Combustible. Incompatible with strong oxidising agents. Light-sensitive.
LogP 6.800
EPA Substance Registry System Cadinene (29350-73-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS08
Signal word  Danger
Hazard statements  H304

CADINENE Chemical Properties,Uses,Production

Chemical Properties

Cadinene has usually bearing the aroma of the oil from which it is derived. The relative position of the two double bonds characterizes the stereoisomers of cadinene; these have been identified.

Physical properties

Colorless, slightly viscous liquid. B.P. 275°C. Sp.Gr. 0.92.
Insoluble in water, soluble in alcohol, miscible with most perfume and flavor oils.

Occurrence

The presence of cadinene has been confirmed in several essential oils: α- and β-cadinene in the oil of Dacrydium colensoi; γ-cadinene in the oils of Java citronella, ylang-ylang, and Populus balsamifera; γ1-cadinene in the oil of lemongrass Malabar; δ-cadinene in the oils of citronella, calamus, and ylang-ylang; ε-cadinene in the oil of ylang-ylang.

Application

CADINENE is occasionally used in flavor compositions, mostly as a fixative in candy flavors, where the stability to heat is an advantage. Concentrations of this chemical may then be as high as 4000 ppm in the finished candy.

Production Methods

CADINENE can be produced by isolation from Brazilian Cedrelawood oils or from the non-esterified portion of Amyris oil in the preparation of so-called "Amyris acetate".

General Description

Clear yellow to lime green oily liquid with a characteristic odor.

Reactivity Profile

CADINENE is sensitive to prolonged exposure to light. CADINENE is incompatible with strong oxidizers.

Health Hazard

ACUTE/CHRONIC HAZARDS: CADINENE is a possible eye irritant.

Fire Hazard

CADINENE is combustible.

CADINENE Preparation Products And Raw materials

Raw materials

Preparation Products

6alpha,8abeta)]-alphdidehydroderiv. Naphthalene,decahydro-1,6-dimethyl-4-(1-methylethyl)-,[1S-(1.alpha.,4.alpha.,4a.alpha.,6.alpha.,8a.beta.)]-,didehydroderiv. naphthalene,decahydro-1,6-dimethyl-4-(1-methylethyl)-,[1s-(1alpha,4alpha,4a [1S-(1alpha,4alpha,4aalpha,6alpha,8abeta)]-decahydro-4-isopropyl-1,6-dimethylnaphthalene, didehydro derivative Naphthalene, decahydro-1,6-dimethyl-4-(1-methylethyl)-, (1S,4S,4aS,6S,8aS)-, didehydro deriv. [1S-(1alpha,4.alpha,4aalpha,6alpha,8abeta)]-Decahydro-4-isopropyl-1,6-dimethylnaphthalin, Didehydroderivat (1S,4aβ,8aβ)-Decahydro-1β,6β-dimethyl-4β-(1-methylethyl)didehydronaphthalene 4-Isopropyl-1,6-dimethyl-decahydronaphthalene CADINENE 1-Isopropyl-4,7-dimethyl-1,2,4a,5,8,8a-hexahydronaphthalene 29350-73-0