(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03
![(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 Structure](CAS/GIF/72952-73-9.gif)
- CAS No.
- 72952-73-9
- Chemical Name:
- (2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03
- Synonyms
- Pentadienyltrimethylsilane;5-(Trimethylsilyl)-1,3-pentadiene;trimethyl(penta-2,4-dienyl)silane;Silane, trimethyl(2E)-2,4-pentadien-1-yl-;(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03
- CBNumber:
- CB2502210
- Molecular Formula:
- C8H16Si
- Molecular Weight:
- 140.3
- MOL File:
- 72952-73-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/6/26 8:28:19
SAFETY
Risk and Safety Statements
Risk Statements | 11-36/37/38 |
---|---|
Safety Statements | 16-26-36 |
RIDADR | 1993 |
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 Chemical Properties,Uses,Production
Physical properties
bp 41 °C/36 mmHg or 105 °C/760 mmHg; n20/ D 1.4570.
Uses
5-Trimethylsilyl-1,3-pentadiene is a useful pentadienylation reagent; an allyl silane; a precursor for 1-trimethylsilyldienes and intramolecular Diels–Alder substrates).
Preparation
5-Trimethylsilyl-1,3-pentadiene may be prepared in 85% yield by the reaction of pentadienyllithium with chlorotrimethylsilane in THF at room temperature.1–3 Generally the product is ≈95% (E) isomer as judged by IR (strong band at 1000 cm?1) or NMR(trans coupling constant of 15.2 Hz for proton at C-3, 5.92 ppm).
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 Preparation Products And Raw materials
Raw materials
Preparation Products
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72952-73-9((2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03)Related Search:
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03
Pentadienyltrimethylsilane
5-(Trimethylsilyl)-1,3-pentadiene
Silane, trimethyl(2E)-2,4-pentadien-1-yl-
trimethyl(penta-2,4-dienyl)silane
72952-73-9