8-chlororugulovasine A

CAS No.: 59787-45-0

Chemical Name:: 8-chlororugulovasine A

Synonyms: 8-chlororugulovasine A;Spiro[benz[cd]indole-5(1H),2'(5'H)-furan]-5'-one, 8-chloro-3,4-dihydro-4'-methyl-4-(methylamino)-, (2'R,4S)-rel-

CBNumber:: CB31329299

Molecular Formula:: C16H15ClN2O2

Molecular Weight:: 302.76

MOL File:: 59787-45-0.mol

Modify Date:: 2022/12/21 16:56:50

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8-chlororugulovasine A Properties

Melting point	Ci o . NHMe

8-chlororugulovasine A Chemical Properties,Uses,Production

Description

When Penicillium islandicum is grown on freshly dug green peanuts it elaborates two chlorine-containing alkaloids which are the first naturally occurring chlorinated ergot bases discovered. The bases have been separated by chromatography on silica gel and are stereoisomeric, being readily interconverted by refluxing in methanol. This alkaloid forms an amorphous white powder and has the structure shown above which is based upon spectroscopic data.

References

Cole et ai., Can. 1. Microbiol., 22, 741 (1976)

8-chlororugulovasine A Preparation Products And Raw materials

Raw materials

Preparation Products

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8-chlororugulovasine A Spiro[benz[cd]indole-5(1H),2'(5'H)-furan]-5'-one, 8-chloro-3,4-dihydro-4'-methyl-4-(methylamino)-, (2'R,4S)-rel- 59787-45-0