ChemicalBook > Product Catalog >Organic Chemistry >Organic fluorine compound >Fluorine propane series >2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Structure
CAS No.
69563-88-8
Chemical Name:
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
Synonyms
HFBAPP;4-BDAF;BAPOFP;6FBAPP;BIS-AF-A;GI 530159;isbenzenamine;leneoxy))bis-;leneoxy)]bis-;2,2-BIS[4-(4-AMINOPH
CBNumber:
CB3265411
Molecular Formula:
C27H20F6N2O2
Molecular Weight:
518.45
MOL File:
69563-88-8.mol
Modify Date:
2024/5/22 9:09:33

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Properties

Melting point 159-163 °C(lit.)
Boiling point 544.8±50.0 °C(Predicted)
Density 1.3455 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Soluble in DMSO
Water Solubility Insoluble in water
form powder to crystal
pka 4.80±0.10(Predicted)
color White to Almost white
InChIKey HHLMWQDRYZAENA-UHFFFAOYSA-N
CAS DataBase Reference 69563-88-8(CAS DataBase Reference)
EPA Substance Registry System Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis- (69563-88-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  22-36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  CY1213000
HazardClass  IRRITANT
HS Code  29222990
NFPA 704
0
2 0

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 386669 4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline 97% 69563-88-8 5G ₹5629 2022-06-14 Buy
TCI Chemicals (India) B1398 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane 69563-88-8 5G ₹3000 2022-05-26 Buy
TCI Chemicals (India) B1398 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane 69563-88-8 25G ₹5900 2022-05-26 Buy
Product number Packaging Price Buy
386669 5G ₹5629 Buy
B1398 5G ₹3000 Buy
B1398 25G ₹5900 Buy

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Chemical Properties,Uses,Production

Description

2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (4-BDAF) is composed of two phenoxyanilines linked by a hexafluoroisopropane. 4-BDAF is commonly used in the synthesis of polyimides, and the semicrystalline and amorphous fluorinated polyimides developed have high transition temperatures and good The developed semi-crystalline and amorphous fluorinated polyimides have high transition temperatures and good thermal stability. Polyimides derived from 4-BDAF and trimellitic anhydride (PMDA) are semi-crystalline and have a melting point of 472°C. Addition of 6F dianhydride (2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, 6FDA) as a copolymer monomer to the PMDA/4-BDAF polyimides lowers the melting point to 440°C. The melting point of the polyimides is reduced to 440°C by using 1,1-bis(4-aminophenyl)-1 Polyimides based on 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane (3F diamine, 3FDAM) are soluble and amorphous. The glass transition temperature of PMDA/3FDAM-based polyimides exceeds 420°C. These fluoropolyimide systems are currently being investigated as candidates for high-temperature applications[1].

Chemical Properties

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is white crystal or powder

Uses

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is used for the preparation of a polyimide material.

Hazard

Moderately toxic by ingestion and skin contact. An eye irritant.

References

[1] M.E. ROGERS. Semicrystalline and amorphous fluorine-containing polyimides[J]. Polymer, 1993. DOI:10.1016/0032-3861(93)90373-I.

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 256)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
Chengdu Yuanda Chemical Co., Ltd 28-85356300 +8618980937689 CHINA 94 58 Inquiry
Shanghai Daeyeon Chemicals Co., Ltd 021-64478606 +8615900664856 China 2062 58 Inquiry
Heynova (Shanghai) New Material Technology CO., Ltd +86-17821320848; +8617821320848 China 431 58 Inquiry
CHINATECH(TIANJIN) CHEMICAL CO.,LTD. +86-18222270857 +86-18222265956 China 64 58 Inquiry
Hebei Mojin Biotechnology Co., Ltd +86 13288715578 +8613288715578 China 12459 58 Inquiry
Henan Fengda Chemical Co., Ltd +86-371-86557731 +86-13613820652 China 20361 58 Inquiry
Capot Chemical Co.,Ltd. 571-85586718 +8613336195806 China 29798 60 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 16220 58 Inquiry
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]-HEXAFLUOROPROPANANE 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane, 4,4μ-(Hexafluoroisopropylidene)bis(p-phenylenoxy)dianiline HFBAPP 2,2-Bis[4-(4-aminophenoxyphenyl)]hexafluoropropane 98% 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]-1,1,1,3,3,3-HEXAFLUOROPROPANE 2,2-Bis[4-(4-aminophenoxyphenyl])hexafluoropropane98% 2,2''-BIS[4-(4-AMINOPHENOXY)PHENY]HEXAFLUOROPROPANE 4,4'-[HEXAFLUOROISOPROPYLIDENEBIS(P-PHENYLENEOXY)]DIANILINE 4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS(P-PHE NYLENOXY)DIANILINE 4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS[(4-AMINOPHENOXY)BENZENE] 4'',4'''-(HEXAFLUOROISOPROPYLIDENE)BIS(4-PHENOXYANILINE) 4',4'''-(HEXAFLUOROISOPROPYLIDENE)-BIS-(4-PHENOXYANILINE) 4-BDAF isbenzenamine leneoxy))bis- leneoxy)]bis- 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane [4-[4-[1-[4-(4-aminophenoxy)phenyl]-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]phenoxy]phenyl]amine 4-[4-[2-[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropan-2-yl]phenoxy]aniline 4-[4-[2-[4-(4-azanylphenoxy)phenyl]-1,1,1,3,3,3-hexafluoro-propan-2-yl]phenoxy]aniline 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane ,99% 2,2-BIS[4-(4-AMINOPH BAPOFP 2,2-Bis[4-(-aMinophenoxy)phenyl]hexafluoropropane(HFBAPP) 4,4'-{(1,1,1,3,3,3-Hexafluoropropane-2,2-diyl)bis[(benzene-4,1-diyl)oxy]}dianiline, BIS-AF-A, 4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline 2,2- double[4-(4- aMinophenoxy)]six fluorinepropane 2,2-Bis[4-(-aminophenoxy)phenyl]hexafluoropropane 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (HFBAPP) 4,4'-(((Perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(oxy))dianiline 2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane 4′ 4′′′-(Hexafluoroisopropylidene)bis(4-phenoxyaniline) 2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane(HFBAPP) BIS-AF-A 4,4’-((2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis(4,1-phenyleneoxy))b benzenamine,4,4’-((2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis(4,1-pheny benzenamine,4,4’-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-pheny 4-(4-aminophenoxy)phenyl 6FBAPP 2,2'-Bis[4-(4- aminophenoxy)-1,1,1,3,3,3-sixfluoropropane(HFBAPP) 4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline 97% GI 530159 4,4'-[[2,2,2-Trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis[benzenamine] 4-[2-(4-amino-2-phenoxyphenyl)-1,1,1,3,3,3-hexafluoropropan-2-yl]-3-phenoxyaniline 2,2-Bis[4-(p-aminophenoxy)phenyl]hexafluoropropane 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane > Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis- 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE ISO 9001:2015 REACH 2,2-Bis[4-(4-aminophenoxy) 2,2-bi [4-(4-aminophenoxy)benzeneHexafluoropropane 2,2-double [4-4-aminophenoxy)phenyl]Hexafluoropropane 2,2-Bis[4-(4-aminophenoxybenzene)]hexafluoropropane, 97% 4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline 69563-88-8 C27H20F6N2O2 CF32CC6H4OC6H4NH22 Reagent for High-Performance Polymer Research Bisphenol AF type Compounds (for High-Performance Polymer Research) fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis