2,2-Bis(3-amino-4-hydroxyphenyl)propane
- CAS No.
- 1220-78-6
- Chemical Name:
- 2,2-Bis(3-amino-4-hydroxyphenyl)propane
- Synonyms
- BHAPP;Oxyindene;4,4''-(Propane;4,4'-Isopropylidenebis(2-aminophenol);2-Bis(3-amino-4-hydroxyphenyl)propane;2,2-Bis(3-amino-4-hydroxyphenyl)propan;2,2-BIS-(3-AMINO-4-HYDROXYPHENYL)PROPANE;2,2-Bis(3-amino-4-hydroxylphenyl)propane;4,4'-(Propane-2,2-diyl)bis(2-aMinophenol);4,4'-(Propane-2,2-diyl)bis(2-aminophenol)
- CBNumber:
- CB81090679
- Molecular Formula:
- C15H18N2O2
- Molecular Weight:
- 258.32
- MOL File:
- 1220-78-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/23 11:46:28
| Melting point | 248-250 °C |
|---|---|
| Boiling point | 471.1±45.0 °C(Predicted) |
| Density | 1.265±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | soluble in Dimethylformamide |
| form | powder to crystal |
| pka | 10.62±0.10(Predicted) |
| color | White to Yellow to Orange |
| CAS DataBase Reference | 1220-78-6(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319 |
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 |
| HS Code | 29222990 |
2,2-Bis(3-amino-4-hydroxyphenyl)propane price More Price(2)
2,2-Bis(3-amino-4-hydroxyphenyl)propane Chemical Properties,Uses,Production
Description
2,2-Bis(3-amino-4-hydroxyphenyl)propane (BAP) is a diamine organic compound that is used in the synthesis of polyimides.
Uses
2,2-bis(4-hydroxy-3-aminophenyl)propane is used as a polyimide intermediate and functional monomer.
Synthesis
Thedinitro compound (2) (10,000 g, 0.0314 mol) was heated to reflux inabsolute ethanol (100 mL) in the presence of wet 10% Pd/C catalyst(0.650 g). Hydrazine monohydrate (20 mL) was then added dropwiseover a period of 30 min, and the reaction was maintained at reflux for24 h. The hot solution was filtered through Celite to eliminate thecatalyst and partially concentrated under reduced pressure. Afterwards,the concentrate was poured into cold distilled water. The crude productwas filtered, washed with water, dried under vacuum and recrystallizedtwice from methanol to give (3). The diamino compound was obtainedas a white powder: yield: 88%; mp. 263 ??C (DSC); Analysis: Calculatedfor C15H18N2O2: C, 69.74%; H, 7.02%; N, 10.84%. Found: C, 69.35%;H, 7.15%; N, 11.02%. 1H NMR (400 MHz, DMSO-d6): |? (ppm); 8.57 (s,1H, OH), 6.43 (d, J=8.1 Hz, 1H, Har), 6.34 (d, J=1.8 Hz, 1H, Har),6.21 (dd, J=8.1 Hz, 1.8 Hz, 1H, Har), 4.23 (s, 2H, NH) 1.37 (s, 3H, CH3f). 13C NMR (100 MHz, DMSO-d6): |? (ppm) 142.4, 141.4, 135.4, 114.4,113.5, 113.4, 40.8, 30.9.
2,2-Bis(3-amino-4-hydroxyphenyl)propane Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Shanghai Daeyeon Chemicals Co., Ltd | 021-64478606 +8615900664856 | China | 2062 | 58 | Inquiry |
| CHINATECH(TIANJIN) CHEMICAL CO.,LTD. | +86-18222270857 +86-18222265956 | China | 64 | 58 | Inquiry |
| Heynova (Shanghai) New Material Technology CO., Ltd | +86-17821320848; +8617821320848 | China | 433 | 58 | Inquiry |
| Hangzhou ICH Biofarm Co., Ltd | +86-0571-28186870; +undefined8613073685410 | China | 985 | 58 | Inquiry |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | China | 20296 | 58 | Inquiry |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 16858 | 58 | Inquiry |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | China | 9337 | 55 | Inquiry |
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