ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Borane >B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE

B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE

B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Structure
CAS No.
42371-63-1
Chemical Name:
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE
Synonyms
S-Alpine-Borane;S-ALPINE-BORANE(R);S-Alpine-Borane®s-alpine-borane tm solution;S-Alpine-Borane(R) solution;S-Alpine-Borane? solution ;isopinocampheylborane derivative;S-ALPINE-BORANE 97% NEAT LIQUID;S-alpine-borane (0.5M soln. in thf);B-3-PINANYL-9-BORABICYCLO[3.3.1]NONANE
CBNumber:
CB3297373
Molecular Formula:
C18H31B
Molecular Weight:
258.25
MOL File:
42371-63-1.mol
MSDS File:
SDS
Modify Date:
2022/8/15 17:41:17

B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Properties

Boiling point >55 °C(lit.)
Density 0.897 g/mL at 25 °C
Flash point 1 °F
optical activity [α]22/D +20°, c = 12 in THF

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02
Signal word  Danger
Hazard statements  H250
Precautionary statements  P222-P231-P422
Hazard Codes  F,Xn,Xi
Risk Statements  11-19-22-36/37/38-17-40-36/37
Safety Statements  16-26-27-36/37/39-24-6-36-36/37
RIDADR  UN 1993 3/PG 2
WGK Germany  3
HazardClass  4.3
PackingGroup  III

B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 237701 S-Alpine-Borane® solution 0.5?M in THF 42371-63-1 100ML ₹10944.08 2022-06-14 Buy
Sigma-Aldrich(India) 237701 S-Alpine-Borane® solution 0.5?M in THF 42371-63-1 800ML ₹40474.68 2022-06-14 Buy
Product number Packaging Price Buy
237701 100ML ₹10944.08 Buy
237701 800ML ₹40474.68 Buy

B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Chemical Properties,Uses,Production

Uses

R- and S-Alpine-Boranes are used for asymmetric reduction of aldehydes and prochiral ketones.

General Description

S-Alpine-Borane? is a chiral reducing agent, synthesized from (-)-α-pinene via hydroboration.

B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 19)Suppliers
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S-alpine-borane (0.5M soln. in thf) S-Alpine-Borane? S-2,6,6-trimethyl-4-(9-borabicyclo(3.3.1)nonane-9-yl)-bicyclo(3.1.1)heptane S-B-isopinocampheyl-9-borabicyclo(3.3.1)nonane S-ALPINE-BORANE 97% NEAT LIQUID (S)-(+)-1,2-Isopropylideneglycerol, 98% (99% ee/GLC) s-alpine-borane tm solution isopinocampheylborane derivative S-Alpine-Borane(R) solution 9-((2R,3S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)-9-borabicyclo[3.3.1]nonane 9-((2R,3S)-2,6,6-TRIMETHYLBICYCLO[3.1.1]HEPTAN-3-YL)-9-BORABICYCLO[3.3.1]NONANE;B-3-PINANYL-9-BORABICYCLO[3.3.1]NONANE B-3-PINANYL-9-BORABICYCLO[3.3.1]NONANE S-ALPINE-BORANE(R) 9-((2S,3R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)-9-borabicyclo[3.3.1]nonane 9-((2S,3R)-2,6,6-TRIMETHYLBICYCLO[3.1.1]HEPTAN-3-YL)-9-BORABICYCLO[3.3.1]NONANE;B-3-PINANYL-9-BORABICYCLO[3.3.1]NONANE S-Alpine-Borane S-Alpine-Borane solution,B-isopinocampheyl-9-borabicyclo[3.3.1]nonane S-Alpine-Borane(R) solution 0.5 M in THF S-Alpine-Borane? solution 9-Borabicyclo[3.3.1]nonane, 9-[(6,6-dimethylbicyclo[3.1.1]hept-2-yl)methyl]- 9-[(1S,3S,4R,5S)-4,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]-9-borabicyclo[3.3.1]nonane S-Alpine-Borane® 42371-63-1 173624-47-2 Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Reduction API intermediates