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BISPHENOL A DIGLYCIDYL ETHER RESIN

BISPHENOL A DIGLYCIDYL ETHER RESIN Structure
CAS No.
1675-54-3
Chemical Name:
BISPHENOL A DIGLYCIDYL ETHER RESIN
Synonyms
DGEBA;der332;dgebpa;Epon 828;EPON(R) RESIN 828;bpdge;EP 274;gy6010;epoxidea;ERL-2774
CBNumber:
CB3749115
Molecular Formula:
C21H24O4
Molecular Weight:
340.41
MOL File:
1675-54-3.mol
MSDS File:
SDS
Modify Date:
2024/6/18 13:26:42

BISPHENOL A DIGLYCIDYL ETHER RESIN Properties

Melting point 40-44 °C
Boiling point 210 °C / 1mmHg
Density 1,17 g/cm3
vapor pressure 0Pa at 25℃
refractive index 1.5735
storage temp. Inert atmosphere,2-8°C
solubility Soluble in DMSO (up to 30 mg/ml) or in Ethanol (up to 15 mg/ml)
form viscous liquid
color White
Water Solubility Soluble in 100% ethanol, dimethyl sulfoxide (100 mM), dimethyl formamide, chloroform, methanol, and ethanol (50 mM). Insoluble in water.
BRN 299026
Stability Stable for 1 year from date of purchase as supplied. Solutions in DMSO or ethanol may be stored at -20°C for up to 1 month.
LogP 3.242 at 25℃
CAS DataBase Reference 1675-54-3(CAS DataBase Reference)
IARC 3 (Vol. 47, 71) 1999
EPA Substance Registry System Bisphenol A diglycidyl ether (1675-54-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H317-H319
Precautionary statements  P261-P264-P272-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/38-43
Safety Statements  28-37/39
WGK Germany  1
RTECS  TX3800000
TSCA  Yes
HS Code  2910900090
Toxicity LD50 oral in rabbit: 1980mg/kg
NFPA 704
1
3 0

BISPHENOL A DIGLYCIDYL ETHER RESIN price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) D3415 Bisphenol A diglycidyl ether 1675-54-3 250G ₹4362.48 2022-06-14 Buy
Sigma-Aldrich(India) 31185 D.E.R.™ 332 used as embedding medium 1675-54-3 250G ₹5704.78 2022-06-14 Buy
Sigma-Aldrich(India) 31185 D.E.R.™ 332 used as embedding medium 1675-54-3 1KG ₹16010.18 2022-06-14 Buy
Sigma-Aldrich(India) 15138 Bisphenol A diglycidyl ether analytical standard 1675-54-3 500MG ₹11626.05 2022-06-14 Buy
ALFA India ALF-L14817-36 Bisphenol A diglycidyl ether resin 1675-54-3 500g ₹29391 2022-05-26 Buy
Product number Packaging Price Buy
D3415 250G ₹4362.48 Buy
31185 250G ₹5704.78 Buy
31185 1KG ₹16010.18 Buy
15138 500MG ₹11626.05 Buy
ALF-L14817-36 500g ₹29391 Buy

BISPHENOL A DIGLYCIDYL ETHER RESIN Chemical Properties,Uses,Production

Description

Most epoxy resins result from polymerization of bisphenol A diglycidyl ether (BADGE). Delayed hypersensitivity is caused by the low-molecular-weight monomer BADGE (MW 340 g/mol), the dimer having a much lower sensitization power. This allergen caused contact dermatitis in six workers in a plant producing printed circuits boards made of copper sheets and fiberglass fabric impregnated with a brominated epoxy resin. It can also be contained in adhesives.

Chemical Properties

Diglycidyl ether of bisphenol A is a colorless to light amber liquid. Slight epoxy odor.

Uses

Bisphenol A derivative. A PPARγ antagonist; exhibits estrogenic activity; An inhibitor of PPARγ and suppressor of TNFα.

Production Methods

The synthesis of the basic epoxy resin molecule involves the reaction of epichlorohydrin with bisphenol A, the latter requiring two basic intermediates for synthesis, acetone and phenol. Theoretically, the production of the bisphenol A diglycidyl ether requires 2 mol of epichlorohydrin for each mole of the phenol. Epoxy resins of higher molecular weight are obtained by reducing the epichlorohydrin/bisphenol A ratio. This reaction involves consumption of the initial epoxy groups in the epichlorohydrin and of some of the groups formed by dehydrohalogenation.

General Description

Odorless yellowish brown liquid. Sinks in water.

Air & Water Reactions

Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979 p.151-154, 164]. Insoluble in water.

Reactivity Profile

Epoxides, such as BISPHENOL A DIGLYCIDYL ETHER RESIN, are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Health Hazard

Contact with liquid irritates eyes. Prolonged or repeated contact with skin causes irritation and dermatitis.

Fire Hazard

BISPHENOL A DIGLYCIDYL ETHER RESIN is probably combustible.

Biological Activity

PPAR γ pure antagonist with micromolar affinity in 3T3-L1 and 3T3-F442A preadipocyte cells; selective over PPAR δ and PPAR α . Antagonizes the ability of rosiglitazone to stimulate transcriptional activity of PPAR γ . Acts as a PPAR γ agonist in an ECV304 cell line. Also produces PPARg-independent apoptosis of tumor cells via several mechanisms. Active in vivo .

Contact allergens

Most epoxy resins result from polymerization of bisphenol A diglycidyl ether (BADGE). Delayed hypersensitivity is caused by the low-molecular-weight monomer BADGE (Molecular Weight 340 g/mol), the dimer having much a lower sensitization power. This allergen caused contact dermatitis in six workers in a plant producing printed circuits boards made of copper sheets and fiber glass fabric impregnated with a brominated epoxy resin. It can be contained in adhesives.

Potential Exposure

Diglycidyl ether of bisphenol A is used as a basic active ingredient of epoxy resins.

Carcinogenicity

In summary, a number of carcinogenicity studies involving the topical application of pure BADGE as well as EPON Resin 828 and other commercial BADGE-based resins have been carried out in experimental animals.Viewing the studies as a whole, the weight of evidence does not show that BADGE or BADGE-based epoxy resins are carcinogenic.

Incompatibilities

Easily oxidized in air; presumed to form unstable and explosive peroxides in storage. Incompatible with strong acids; strong oxidizers.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

BISPHENOL A DIGLYCIDYL ETHER RESIN Preparation Products And Raw materials

Global( 205)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
Pharmaffiliates Analytics and Synthetics P. Ltd +91-172-5066494 Haryana, India 6773 58 Inquiry
Pharma Affiliates 172-5066494 Haryana, India 6761 58 Inquiry
Clearsynth Labs 91-22-45045900 Maharashtra, India 3889 58 Inquiry
Shandong Deshang Chemical Co., Ltd. +86-0531-8875-2665 +8613153039501 China 487 58 Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21675 55 Inquiry
SHANDONG ZHI SHANG CHEMICAL CO.LTD +86 18953170293 China 2931 58 Inquiry

BISPHENOL A DIGLYCIDYL ETHER RESIN Spectrum

p,p'-Dihydroxydiphenyldimethylmethane diglycidyl ether Propane, 2,2-bis(4-(2,3-epoxypropoxy)phenyl)- Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]- propane,2,2-bis(p-(2,3-epoxypropoxy)phenyl) BISPHENOL A DIGLYCIDYL ETHER RESIN DER 332 RESIN 2,2’-((1-methylethylidene)bis(4,1-phenyleneoxymethylene))bis-oxiran 2,2’-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-oxiran Bisphenol-A diglycidyl ether E42 Bisphenol-A epoxy resin E42 Bisphenol-A epoxy resin,solid Bisphenol-A diglycidyl ether E39-D Bisphenol-A epoxy resin E39-D Bisphenol-A diglycidyl ether E51 Bisphenol-A epoxy resin E51 Bisphenol-A diglycidyl ether E14 Bisphenol-A epoxy resin E14 Bisphenol-A diglycidyl ether E35 Bisphenol-A epoxy resin E35 Bisphenol-A diglycidyl ether E31 Bisphenol-A epoxy resin E31 Bisphenol-A diglycidyl ether E44 Bisphenol-A epoxy resin E44 2,2'-[(1-Methylethylidene)bis(4,1-phenylene)bis(oxymethylene)]bisoxirane 2,2-Bis[4-(oxiranylmethyloxy)phenyl]propane 4,4’-isopropylidenebis(1-(2,3-epoxypropoxy)benzene) 4,4'-Bis(2,3-epoxypropoxy)diphenyldimethylmethane 4,4'-Dihydroxydiphenyldimethylmethane diglycidyl ether 4,4'-Isopropylidenebis[1-(2,3-epoxypropoxy)benzene] Bis(4-glycidyloxyphenyl)dimethyamethane Bis(4-glycidyloxyphenyl)dimethylmethane Bis(4-hydroxyphenyl)dimethylmethane diglycidyl ether bis(4-hydroxyphenyl)dimethylmethanediglycidylether Bis[4-(2,3-epoxypropoxy)phenyl]propane bisphenoladiglycidylether(dgebpa) bpdge D.E.R. 332 d.e.r.332 Dian Diglycidyl ether Dian-bis-glycidylether diandiglycidylether Diglycidyl bisphenol A Diglycidyl bisphenol A ether Diglycidyl diphenylolpropane ether Diglycidyl ether of 2,2-bis(4-hydroxyphenyl)propane Diglycidyl ether of 2,2-bis(p-hydroxyphenyl)propane Diglycidyl ether of 4,4'-isopropylidenediphenol diglycidylbisphenola diglycidylbisphenolaether diglycidyldiphenylolpropaneether diglycidyletherof2,2-bis(4-hydroxyphenyl)propane diglycidyletherof2,2-bis(p-hydroxyphenyl)propane diglycidyletherof4,4’-isopropylidenediphenol Diomethane diglycidyl ether diomethanediglycidylether diphenylol diphenylolpropanediglycidylether EP 274