sodium benzaldehyde-o-sulfonate

sodium benzaldehyde-o-sulfonate Structure
CAS No.
91-25-8
Chemical Name:
sodium benzaldehyde-o-sulfonate
Synonyms
o-Sulfobenzaldehyde;Benzaldehyde-o-sulfonic acid;Benzenesulfonic acid, 2-formyl-;sodium benzaldehyde-o-sulfonate;2-methanoylbenzenesulfonic acid
CBNumber:
CB3875791
Molecular Formula:
C7H6O4S
Molecular Weight:
186.19
MOL File:
91-25-8.mol
Modify Date:
2023/5/15 10:43:54

sodium benzaldehyde-o-sulfonate Properties

Density 1.503±0.06 g/cm3(Predicted)
solubility DMSO (Slightly), Water (Slightly)
form Solid
pka -0.97±0.18(Predicted)
color White to Off-White
Stability Hygroscopic
EPA Substance Registry System Benzenesulfonic acid, 2-formyl- (91-25-8)

sodium benzaldehyde-o-sulfonate Chemical Properties,Uses,Production

Chemical Properties

Acquires a deep reddish-violet color if Schiff' s reagent is added. In contrast to the poorly soluble barium salt, the sodium salt is freely soluble in water; it is also freely soluble in hot, but not in cold, ethyl alcohol.

Application

2-Formylbenzenesulfonic acid(sodium benzaldehyde-o-sulfonate) is an intermediate in the manufacture of optical brighteners, trade names including Uvitex NFW (for textiles) and Tinopal CBS (for detergents). Triphenylmethane dyes are produced by condensation of the acid with various N,N-dialkylani- lines, N,N-dialkyl-m-aminophenols, and their sulfonic acids.

Production Methods

The starting material is o-chlorobenzaldehyde, which is heated with sodium hydrogensulfite solution in an autoclave to 190 – 200 ℃,with the result that its chloro substituent is replaced by the sulfonic acid group. The batch is allowed to cool, sulfuric acid is added, and excess sulfur dioxide and unconverted chlorobenzaldehyde are driven off by boiling. The resulting solution is used directly in the manufacture of dyes. Sodium benzaldehyde-o-sulfonate can also be produced by oxidation of o-toluenesulfonic acid with oxygen in the presence of bromine and cobalt as catalysts.

sodium benzaldehyde-o-sulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 9)Suppliers
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91-25-8(sodium benzaldehyde-o-sulfonate)Related Search:

Benzaldehyde-o-sulfonic acid o-Sulfobenzaldehyde 2-methanoylbenzenesulfonic acid sodium benzaldehyde-o-sulfonate Benzenesulfonic acid, 2-formyl- 91-25-8