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1,2-Bis(bromomethyl)benzene

1,2-Bis(bromomethyl)benzene Structure
CAS No.
91-13-4
Chemical Name:
1,2-Bis(bromomethyl)benzene
Synonyms
O-XYLENE DIBROMIDE;O-XYLYLENE DIBROMIDE;α,α’-dibromo-o-xylene;O-XYLYLENE BROMIDE;O-Xylyene dibromide;O-XYLIDENE DIBROMIDE;1,2-dibenzyl bromide;a,a'-Dibromo-o-xylol;1,2-Bis(bromomethyl);à,à'-dibromo-o-xylene
CBNumber:
CB4129349
Molecular Formula:
C8H8Br2
Molecular Weight:
263.96
MOL File:
91-13-4.mol
Modify Date:
2024/4/15 15:30:59

1,2-Bis(bromomethyl)benzene Properties

Melting point 91-94 °C(lit.)
Boiling point 140 °C / 20mmHg
Density 1.96 g/mL at 25 °C(lit.)
refractive index 1.6113 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Crystals or Crystalline Powder
color White to light cream
Water Solubility soluble, hydrolyses
BRN 637159
InChIKey KGKAYWMGPDWLQZ-UHFFFAOYSA-N
CAS DataBase Reference 91-13-4(CAS DataBase Reference)
NIST Chemistry Reference Benzene, 1,2-bis(bromomethyl)-(91-13-4)
EPA Substance Registry System Benzene, 1,2-bis(bromomethyl)- (91-13-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P302+P352-P305+P351+P338
Hazard Codes  C
Risk Statements  22-34
Safety Statements  26-36/37/39-45
RIDADR  UN 3448 6.1/PG 2
WGK Germany  2
8-19-21
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29036990
NFPA 704
0
2 0

1,2-Bis(bromomethyl)benzene price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) D44405 α,α′-Dibromo-o-xylene 97% 91-13-4 25G ₹4884.65 2022-06-14 Buy
Sigma-Aldrich(India) D44405 α,α′-Dibromo-o-xylene 97% 91-13-4 100G ₹12501.75 2022-06-14 Buy
TCI Chemicals (India) D0214 α,α'-Dibromo-o-xylene min. 98.0 % 91-13-4 25G ₹3700 2022-05-26 Buy
TCI Chemicals (India) D0214 α,α'-Dibromo-o-xylene min. 98.0 % 91-13-4 100G ₹10900 2022-05-26 Buy
Product number Packaging Price Buy
D44405 25G ₹4884.65 Buy
D44405 100G ₹12501.75 Buy
D0214 25G ₹3700 Buy
D0214 100G ₹10900 Buy

1,2-Bis(bromomethyl)benzene Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

1,2-Bis(bromomethyl)benzene is used in the synthesis of isothioureas involved in the inhibition of human nitric oxide synthases. Also used in the synthesis of tridentate carbene ligands.

Purification Methods

Crystallise it from CHCl3 or pet ether, and/or distil it under vacuum. [Wenner Org Chem 17 527 1952, Beilstein 5 H 366, 5 I 180, 5 II 285, 5 III 819, 5 IV 929.]

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1,2-bis(bromomethyl)-benzen alpha,alpha '-Dibromo-ortho-xylene alpha,alpha'-Dibromo-o-xylol benzene,1,2-bis(bromomethyl)- o-(Bromomethyl)benzyl bromide o-Bis(bromomethyl)benzene o-Xylene, alpha,alpha'-dibromo- 1,2-Bis(bromomethyl)benzene~alpha,alpha-Dibromo-o-xylene O-XYLIDENE DIBROMIDE O-XYLYLENE DIBROMIDE 97% o-Xylylenedibromide,97% à,à'-dibromo-o-xylene 1,2-dibenzyl bromide 1,2-Bis(bromomethyl)benzene, o-Xylylene dibromide -(Bromomethyl)benzyl bromide 2-(Bromomethyl)benzyl bromide a,a'-Dibromo-o-xylol 1,2-Bis(bromomethyl)benzene 1,2-Bis(bromomethyl)benzene ,97% 1,2-Phenylenebis(bromomethane) alpha,alpha'-Dibromo-o-xylene,96% 1,2-Bis(bromomethyl)benzene ,97% 1,2-Bis(bromomethyl) alpha'-DibroMo-o-xylene o-Xylylene Bromide o-Xylylene Dibromide 1,2-Bis(bromomethyl)benzene alpha,alpha'-DibroMo-o-xylene 97% α,α'-Dibromo-o-xylene O-Xylyene dibromide 1,2-Bis(bromomethyl)-benzene for synthesis O-XYLYLENE BROMIDE A,A'-DIBROMO-O-XYLENE ALPHA,ALPHA'-DIBROMO-2-XYLENE ALPHA,ALPHA'-DIBROMO-O-XYLENE ALPHA,ALPHA-DIBROMO-O-XYLENE 1,2-BIS(BROMOMETHYL)BENZENE α,α'-Dibromo-o-xylene α,α'-Dibromo-o-xylene > 1,2-Bis(bromomethyl)benzene USP/EP/BP O-XYLYLENE DIBROMIDE O-XYLENE DIBROMIDE α,α’-dibromo-o-xylene Alpha,Alpha'-Dibromo-o-xylene 91-13-4 HALOGEN Aryl C8 Building Blocks Organic Building Blocks Halogenated Hydrocarbons Aryl Building Blocks C8 Chemical Synthesis Halogenated Hydrocarbons Organic Building Blocks Aromatic Halides (substituted)