N-TERT-BUTYLTRIMETHYLSILYLAMINE

N-TERT-BUTYLTRIMETHYLSILYLAMINE Structure
CAS No.
5577-67-3
Chemical Name:
N-TERT-BUTYLTRIMETHYLSILYLAMINE
Synonyms
tert-C4H9NHSi(CH3)3;t-Butylamino Trimethylsilane;TERT-BUTYLAMINOTRIMETHYLSILANE;TERT-BUTYL TRIMETHYLSILYLAMINE;N-TERT-BUTYLTRIMETHYLSILYLAMINE;(Trimethylsilyl)(tert-butyl)amine;N-(TRIMETHYLSILYL)-TERT-BUTYLAMINE;N-(tert-Butyl)(trimethyl)silanamine;N-tert-Butyltrimethylsilylamine 98%;N-tert-butyl-1,1,1-trimethylsilanamine
CBNumber:
CB4185743
Molecular Formula:
C7H19NSi
Molecular Weight:
145.32
MOL File:
5577-67-3.mol
MSDS File:
SDS
Modify Date:
2025/1/27 9:38:02

N-TERT-BUTYLTRIMETHYLSILYLAMINE Properties

Boiling point 118-119 °C(lit.)
Density 0.762 g/mL at 25 °C(lit.)
refractive index n20/D 1.406(lit.)
Flash point 80 °F
form liquid
pka 13.25±0.70(Predicted)
color Clear, colourless
BRN 1734528

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS05
Signal word  Danger
Hazard statements  H226-H314
Precautionary statements  P280-P305+P351+P338-P310
Hazard Codes  C
Risk Statements  10-34
Safety Statements  16-26-36/37/39-45
RIDADR  UN 2733 3/PG 3
WGK Germany  3
10-21
HazardClass  3.2
PackingGroup  III
HS Code  2931900090

N-TERT-BUTYLTRIMETHYLSILYLAMINE price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 369330 N-tert-Butyltrimethylsilylamine 98% 5577-67-3 25G ₹9969.83 2022-06-14 Buy
Product number Packaging Price Buy
369330 25G ₹9969.83 Buy

N-TERT-BUTYLTRIMETHYLSILYLAMINE Chemical Properties,Uses,Production

Uses

N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates.

Preparation

N-tert-Butyltrimethylsilylamine is prepared by the reaction of the parent amines with n-Butyllithium in THF/hexane. The parent amines are prepared by the reaction of lithium t-butylamide and the corresponding chlorosilanes (eq 1).
N-TERT-BUTYLTRIMETHYLSILYLAMINE synthesis route

General Description

N-tert-Butyltrimethylsilylamine (Me3SiNH-t-Bu) reacts with [Cp*Rh(H2O)3](OTf)2 in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh3(μ-OH)3(μ3-OH)](OTf)3(t-BuNH3).

storage

N-tert-Butyltrimethylsilylamine reacts readily with protic solvents, especially water, and must be maintained in a dry environment. It is thermally stable. Use in a fume hood.

Purification Methods

Best purified by distillation.

N-TERT-BUTYLTRIMETHYLSILYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

N-TERT-BUTYLTRIMETHYLSILYLAMINE Suppliers

Global( 50)Suppliers
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Shanghai Daken Advanced Materials Co.,Ltd +86-371-+86-371-66670886 China 19805 58 Inquiry
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Suzhou Daolan Biomedical Technology Co., Ltd. 13771737464 China 2309 58 Inquiry
TERT-BUTYL TRIMETHYLSILYLAMINE N-TERT-BUTYLTRIMETHYLSILYLAMINE N-(TRIMETHYLSILYL)-TERT-BUTYLAMINE TERT-BUTYLAMINOTRIMETHYLSILANE N-tert-Butyltrimethylsilylamine 98% N-(tert-Butyl)(trimethyl)silanamine tert-C4H9NHSi(CH3)3 (Trimethylsilyl)(tert-butyl)amine N-(Trimethylsilyl)-2-methyl-2-propanamine 2-methyl-N-trimethylsilylpropan-2-amine Silanamine,N-(1,1-dimethylethyl)-1,1,1-trimethyl- N-(1,1-Dimethylethyl)-1,1,1-trimethylsilanamine t-Butylamino Trimethylsilane N-tert-butyl-1,1,1-trimethylsilanamine N-tert-Butyltrimethylsilylamine 5577-67-3 CH33SiNHCCH33 Protected Amines Organic Building Blocks Nitrogen Compounds Building Blocks Building Blocks Chemical Synthesis Nitrogen Compounds Organic Building Blocks Protected Amines